DI-TERT-BUTYLSILYL BIS(TRIFLUOROMETHANESULFONATE)

Product Name: DI-TERT-BUTYLSILYL BIS(TRIFLUOROMETHANESULFONATE)
CAS No.: 85272-31-7
Chemical Name: DI-TERT-BUTYLSILYL BIS(TRIFLUOROMETHANESULFONATE)
Synonyms: DI-TERT-BUTYLBIS(TRIFLUOROMETHANESULFONYLOXY)SILANE;Di-tert-butylsilanediyl bis(trifluoroMethanesulfonate);DTBS DITRIFLATE;Di-T-Butylsilylbis;DI-T-BUTYLSILYL DITRIFLATE;DI-TERT-BUTYLSILYL DITRIFLATE;BIS(TRIFLUOROMETHANESULFONATE);85272-31-7 DI-TERT-BUTYLSILYL DITRIFLATE;Di-tert-butylsilylbis(trifluoromethanesul;Di-t-butylsilybis(trifluoromethanesulfonate
CBNumber: CB3337556
Molecular Formula: C10H18F6O6S2Si
Formula Weight: 440.45
MOL File: 85272-31-7.mol

More

Less

DI-TERT-BUTYLSILYL BIS(TRIFLUOROMETHANESULFONATE) Property

Boiling point:: 73-75 °C/0.35 mmHg (lit.)
Density: 1.352 g/mL at 25 °C (lit.)
refractive index: n20/D 1.398(lit.)
Flash point:: 195 °F
storage temp.: Inert atmosphere,Room Temperature
solubility: sol most common organic solvents.
form: Oil
color: Clear Pale Yellow
Specific Gravity: 1.358
Hydrolytic Sensitivity: 8: reacts rapidly with moisture, water, protic solvents
BRN: 3569211
Stability:: Moisture Sensitive
InChIKey: HUHKPYLEVGCJTG-UHFFFAOYSA-N
CAS DataBase Reference: 85272-31-7(CAS DataBase Reference)

More

Less

Safety

Hazard Codes: C
Risk Statements: 34
Safety Statements: 26-36/37/39-45
RIDADR: UN 3265 8/PG 2
WGK Germany: 3
F: 10-21
Hazard Note: Corrosive
TSCA: No
HazardClass: 8
PackingGroup: III
HS Code: 29319090

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 262021
Product name: Di-tert-butylsilyl bis(trifluoromethanesulfonate)
Purity: 97%
Packaging: 5g
Price: $134
Updated: 2024/03/01

Sigma-Aldrich

Product number: 262021
Product name: Di-tert-butylsilyl bis(trifluoromethanesulfonate)
Purity: 97%
Packaging: 25g
Price: $445
Updated: 2024/03/01

TCI Chemical

Product number: D3135
Product name: Di-tert-butylsilyl Bis(trifluoromethanesulfonate)
Purity: >97.0%(T)
Packaging: 1g
Price: $47
Updated: 2024/03/01

TCI Chemical

Product number: D3135
Product name: Di-tert-butylsilyl Bis(trifluoromethanesulfonate)
Purity: >97.0%(T)
Packaging: 5g
Price: $141
Updated: 2024/03/01

Sigma-Aldrich

Product number: 262021
Product name: Di-tert-butylsilyl bis(trifluoromethanesulfonate)
Purity: 97%
Packaging: 250g
Price: $1616
Updated: 2024/03/01

More

Less

DI-TERT-BUTYLSILYL BIS(TRIFLUOROMETHANESULFONATE) Chemical Properties,Usage,Production

Chemical Properties

Colorless to yellow liquid

Physical properties

bp 73–75°C/0.35 mmHg; d 1.208 g cm?3.

Uses

Protecting group reagent for 1,3-diols used recently in a synthesis of N-homoceramides. Also used for selective α-galactosylation in the synthesis of α-galactosyl ceramides.

Uses

Di-t-butylsilyl bis(trifluoromethanesulfonate) is a reagent for the selective protection of polyhydroxy compounds. This reagent reacts with 1,2-, 1,3-, and 1,4-diols under mild conditions to give the corresponding dialkylsilylene derivatives in high yield (0–50°C, 79–96%). Deprotection is conveniently achieved by using aqueous hydrofluoric acid in acetonitrile (eq 1).
Unlike di-t-butyldichlorosilane, this reagent reacts with hindered alcohols. Even pinacol reacts to give the silylene derivative (100°C, 24 h, 70%). Di-t-butylsilylene derivatives of 1,2-diols are more reactive than those of 1,3- and 1,4-diols and undergo rapid hydrolysis (5 min) in THF/H2O at pH 10, while the 1,3- and 1,4- derivatives are unaffected at pH 4–10 (22°C) for several hours. This protecting group is stable under the conditions of PDC oxidation of alcohols (CH2Cl2, 25?C, 27 h) and tosylation of alcohols (pyridine, 25°C, 27 h).
The reagent has seen limited use for the protection of alcohols but has been used to protect nucleosides (eq 2).The procedure consists of sequential addition of the ditriflate and triethylamine to the nucleoside in DMF. The choice of solvent is critical.

Preparation

by the treatment of di-t-butylchlorosilane with trifluoromethanesulfonic acid, followed by distillation (71% yield).

DI-TERT-BUTYLSILYL BIS(TRIFLUOROMETHANESULFONATE) Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

DI-TERT-BUTYLSILYL BIS(TRIFLUOROMETHANESULFONATE) Suppliers

Americas 1 Canada 2 China 149 Europe 1 Germany 3 India 3 Italy 1 Japan 1 Singapore 1 Switzerland 1 United Kingdom 10 United States 24 Global 197

Wuhu Nuowei Chemical Technology Co., Ltd

Tel: 0553-2911116 18055326116
Email: sales@nuowei-chem.com
Country: China
ProdList: 309
Advantage: 58

Aikon International Limited

Tel: 025-66113011 18112977050
Fax: (5)02557626880
Email: cb6@aikonchem.com
Country: China
ProdList: 15494
Advantage: 58

Manac (SHANGHAI) TRADING CO., LTD

Tel: 021-32503616
Fax: 021-32503616
Email: sales@manac-inc.com.cn
Country: China
ProdList: 160
Advantage: 60

Shanghai Boyle Chemical Co., Ltd.

Tel: 021-50182298 021-50180596
Fax: +86-21-57758967
Email: sales@boylechem.com
Country: China
ProdList: 2208
Advantage: 55

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 94657
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

Chembest Research Laboratories Limited

Tel: +86-21-20908456
Fax: 021-58180499
Email: sales@BioChemBest.com
Country: China
ProdList: 6005
Advantage: 61

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24529
Advantage: 81

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44689
Advantage: 61

Wuhan Chemwish Technology Co., Ltd

Tel: 86-027-67849912
Fax: 86-027-87531808
Email: sales@chemwish.com
Country: China
ProdList: 35896
Advantage: 56

More

Less

View Lastest Price from DI-TERT-BUTYLSILYL BIS(TRIFLUOROMETHANESULFONATE) manufacturers

Hebei Mojin Biotechnology Co.,Ltd

Product: DI-TERT-BUTYLSILYL BIS(TRIFLUOROMETHANESULFONATE) 85272-31-7
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2024-08-12

R&D Scientific Inc.

Product: Bis(tert-butyl)silyl bis(trifluoromethanesulphonate) 85272-31-7
Price: US $700.00/g
Min. Order: 1g
Purity: 98
Supply Ability: 500 Kg
Release date: 2024-02-11

Henan Aochuang Chemical Co.,Ltd.

Product: Bis(trifluoromethanesulfonic acid)di-tert-butylsilanediyl ester 85272-31-7
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-09-23

85272-31-7, DI-TERT-BUTYLSILYL BIS(TRIFLUOROMETHANESULFONATE)Related Search:

Isobutylamine 2,4,6-Triisopropylbenzenesulfonyl chloride Trifluoromethane Trifluoromethanesulfonic acid DIISOPROPYLSILANE DI-TERT-BUTYLSILYL BIS(TRIFLUOROMETHANESULFONATE) DIISOPROPYLSILYL BIS(TRIFLUOROMETHANESULFONATE) DIMETHYLBIS(TRIFLUOROMETHYLSULFONYLOXY)SILANE DI-TERT-BUTYLSILANE

TRIFLUOROMETHANESULFONIC ACID DI-TERT-BUTYLSILYLENE ESTER

DI-T-BUTYLSILYLBIS(TRIFLUOROMETHANESULFONATE)

DI(T-BUTYL)SILYL BIS(TRIFLUOROMETHANESULPHONATE)

DI-T-BUTYLSILYL DITRIFLATE

DI-TERT-BUTYLBIS(TRIFLUOROMETHANESULFONYLOXY)SILANE

DI-TERT-BUTYLSILYL BIS(TRIFLUOROMETHANESULFONATE)

DI-TERT-BUTYLSILYL BIS(TRIFLUOROMETHANESULPHONATE)

DI-TERT-BUTYLSILYL DITRIFLATE

DTBS DITRIFLATE

Di-t-butylsilybis(trifluoromethanesulfonate

Bis(trifluoromethanesulfonic acid)[di(1,1-dimethylethyl)silanediyl] ester

Bis(trifluoromethanesulfonic acid)di-tert-butylsilanediyl ester

Di-tert-butylbis(trifluoromethylsulfonyloxy)silane

Methanesulfonic acid, trifluoro-, bis(1,1-dimethylethyl)silylene ester

BIS(TRIFLUOROMETHANESULFONATE)

Di-tert-butylsilyl ditriflate, DTBS ditriflate, Trifluoromethanesulfonic acid di-tert-butylsilylene ester

Di-tert-butylsilybis(trifluoromethanesulfonate

Di-tert-butylsilanediyl bis(trifluoroMethanesulfonate)

Di-tert-butylbis(trifluoromethanesulfonyloxy)silane Di-tert-butylsilyl Ditriflate

Methanesulfonic acid, 1,1,1-trifluoro-, bis(1,1-diMethylethyl)[[(trifluoroMethyl)sulfonyl]oxy]silyl ester

Di-T-Butylsilylbis

Bis(tert-butyl)silyl bis(trifluoromethanesulphonate)

Bis(tert-butyl)silyl ditriflate, DTBS ditriflate, DTBSDT

Di-tert-butylsilylBis(trifluoromethanesulfonate)&gt

Di-tert-butylsilyl bis(trifluoromethanesulfonate), 97%, for synthesis

85272-31-7 DI-TERT-BUTYLSILYL DITRIFLATE

Bis(1,1-dimethylethyl)[[(trifluoromethyl)sulfonyl]oxy]silyl 1,1,1-trifluoromethanesulfonate

Di-tert-butylsilylbis(trifluoromethanesul

Bis(tert-butyl)[[(trifluoromethyl)sulfonyl]oxy]silyl triflate

85272-31-7

C10H18F6O6S2Si

CF3SO32SiCCH332

C10H18O6F6S2Si

Silicon Compounds (for Synthesis)

Si (Classes of Silicon Compounds)

Si-O Compounds

Silyl Esters

Silicon-Based

Sulfur Compounds

Synthetic Reagents

Organic Triflates

Protecting and Derivatizing Reagents

Protection and Derivatization

Organic Building Blocks

Building Blocks

Si (Classes of Silicon Compounds)

Silicon Compounds (for Synthesis)

Silyl Esters

Si-O Compounds

Synthetic Organic Chemistry