ChemicalBook > CAS DataBase List > Z-TRP-OBZL

Z-TRP-OBZL

Product Name: Z-TRP-OBZL
CAS No.: 69876-37-5
Chemical Name: Z-TRP-OBZL
Synonyms: Z-TRP-OBZL;Cbz-Trp-OBzl;Z-L-Trp-OBzl;Z-L-TRYPTOPHAN BENZYL ESTER;N-a-Z-L-tryptophanbenzylester;Nα-Z-L-tryptophan benzyl ester;N-α-Z-L-tryptophan benzyl ester;N-cbz-L-tryptophan benzyl ester;N-.ALPHA.-CBZ-L-TRYPTOPHAN BENZYL ESTER;N-Carbobenzyloxy-L-tryptphan benzyl ester
CBNumber: CB3358438
Molecular Formula: C26H24N2O4
Formula Weight: 428.48
MOL File: 69876-37-5.mol

Less

Z-TRP-OBZL Property

Melting point:: 105-108℃
Boiling point:: 656.7±55.0 °C(Predicted)
Density: 1.266±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,2-8°C
form: Powder
pka: 10.93±0.46(Predicted)
color: White to off-white
optical activity: 7.70°(C=0.01g/mL, CHCL3, 20°C, 589nm)

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Less

N-Bromosuccinimide Price

AK Scientific

Product number: V0756
Product name: Z-Trp-OBzl
Packaging: 1g
Price: $14
Updated: 2021/12/16

Chem-Impex

Product number: 06627
Product name: Z-L-tryptophan benzyl ester
Purity: ≥ 99% (HPLC)
Packaging: 1G
Price: $25.9
Updated: 2021/12/16

AK Scientific

Product number: V0756
Product name: Z-Trp-OBzl
Packaging: 5g
Price: $54
Updated: 2021/12/16

Activate Scientific

Product number: AS91250
Product name: Nalpha-Cbz-L-tryptophan Benzyl Ester
Purity: 97+% ee
Packaging: 5G
Price: $86
Updated: 2021/12/16

ChemPep

Product number: 411802
Product name: Z-Trp-OBzl
Purity: ≥98%
Packaging: 1g
Price: $98
Updated: 2021/12/16

Less

Z-TRP-OBZL Chemical Properties,Usage,Production

Chemical Properties

White to off-white powder

Synthesis

100-51-6

7432-21-5

69876-37-5

GENERAL STEPS: To a stirred suspension of (S)-2-(((benzyloxy)carbonyl)amino)-3-(1H-indol-3-yl)propanoic acid (2.45 g, 7.2 mmol) in 10 mL of anhydrous dichloromethane, 4-dimethylaminopyridine (DMAP, 88 mg, 0.72 mmol) and benzyl alcohol (1.28 g, 11.8 mmol) were added. A 5 mL solution of N,N'-dicyclohexylcarbodiimide (DCC, 1.48 g, 7.2 mmol) in dichloromethane was slowly added at 0 °C. The reaction was carried out at 0 °C with the addition of N,N'-dicyclohexylcarbodiimide (DCC, 1.48 g, 7.2 mmol). The reaction mixture was slowly warmed to room temperature and stirred overnight. The white precipitate was removed by filtration and the solvent was subsequently removed by distillation under reduced pressure to afford the colorless oily product Cbz-L-tryptophan benzyl ester (3 g, 98%). The product had a rotativity of [α]D20 = +50 (c = 1.0, CHCl3, 365 nm). Thin layer chromatography (TLC) showed Rf = 0.29 (ethyl acetate:hexane = 1:2).1H NMR (400 MHz, CDCl3) δ: 8.26 (br, 1H), 7.56 (d, J = 8.0 Hz, 1H), 7.41-7.33 (m, 9H), 7.26-7.20 (m, 3H), 7.12 (t, J = 8.0 Hz , 1H), 6.76 (d, J = 2.0 Hz, 1H), 5.47 (d, J = 8.0 Hz, 1H), 5.18-5.10 (m, 4H), 4.82 (q, J = 8.0 Hz, 1H), 3.34 (d, J = 5.1 Hz, 2H).13C NMR (100 MHz, CDCl3) δ: 171.8, 155.8 , 136.1, 136.0, 135.1, 128.5, 128.4, 128.3, 128.0, 127.5, 127.4, 126.9, 122.9, 122.0, 119.5, 118.5, 111.2, 109.4, 67.1, 66.8, 54.6, 27.8.Fourier transform infrared (FTIR) spectroscopy ( FTIR, pure sample) showed absorption peaks located at 3395, 3343, 1742, 1458, 1377, 721 cm-1. High resolution mass spectrometry (HRMS, ESI) calculated value of C20H20O4N2 [M + H]+ was 429.1814 and measured value was 429.1821.

References

[1] Patent: US2011/269972, 2011, A1. Location in patent: Page/Page column 20

Z-TRP-OBZL Preparation Products And Raw materials

Raw materials

Preparation Products

Less

Z-TRP-OBZL Suppliers

China 80 Germany 2 India 2 Japan 1 Switzerland 1 United Kingdom 3 United States 8 Global 97

GL Biochem (Shanghai) Ltd

Tel: 21-61263452 13641803416
Fax: 86-21-61263399
Email: ymbetter@glbiochem.com
Country: China
ProdList: 9981
Advantage: 64

Accela ChemBio Co.,Ltd.

Tel: 021-50795510 4000665055
Fax: 021-50795055
Email: sales@accelachem.com
Country: China
ProdList: 11035
Advantage: 64

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696
Email: info@hanhongsci.com
Country: China
ProdList: 42934
Advantage: 64

Beijing HuaMeiHuLiBiological Chemical

Tel: 010-56205725
Fax: 010-65763397
Email: waley188@sohu.com
Country: China
ProdList: 12335
Advantage: 58

Shanghai T&W Pharmaceutical Co., Ltd.

Tel: +86 21 61551611
Fax: +86 21 50676805
Country: China
ProdList: 9891
Advantage: 58

Bide Pharmatech Ltd.

Tel: 400-164-7117 13681763483
Fax: +86-21-61629029
Email: product02@bidepharm.com
Country: China
ProdList: 39966
Advantage: 60

Wuxi Zhongkun Biochemical Technology Co., Ltd.

Tel: 0510-85629785 18013409632
Fax: 051085625359
Email: sales@reading-chemicals.com
Country: China
ProdList: 15178
Advantage: 58

Finetech Industry Limited

Tel: 027-87465837 19945049750
Fax: 027-8777-2287
Email: sales@finetechnology-ind.com
Country: China
ProdList: 9637
Advantage: 58

NINGBO INNO PHARMCHEM CO.,LTD.

Tel: 86-574-27787657
Fax: 86-574-27912196
Email: info@dearchem.com
Country: China
ProdList: 4613
Advantage: 58

Tianjin Anhao Biological Technology Co., Ltd.

Tel
Email: sales@ahpharmatech.com
Country: China
ProdList: 5734
Advantage: 55

Codow Chemical Co.,Ltd.

Tel: 18620099427
Fax: +86-20-62619665
Email: amy@howeipharm.com
Country: China
ProdList: 6687
Advantage: 55

Shanghai GL Peptide Ltd.

Tel: +86-21-61263340; 17609490614 13764994101
Fax: 021-61263399
Email: fisherwang@glschina.com
Country: China
ProdList: 8258
Advantage: 55

Wuxi Asia Peptide Biotechnology Limited Company

Tel: 0510-83583050 13771062561
Fax: 0510-83583039
Email: willsun@peptide-search.com
Country: China
ProdList: 6716
Advantage: 58

Amadis Chemical Company Limited

Tel: 571-89925085
Fax: 0086-571-89925065
Email: sales@amadischem.com
Country: China
ProdList: 131957
Advantage: 58

Nanjing Peptide Biotech Ltd.

Tel: 025-58361106-805 15951641583
Fax: 025-58361106-806
Email: zhao.xu@njpeptide.com
Country: China
ProdList: 9979
Advantage: 55

Sichuan jiayinglai technology CO.,LTD

Tel: 028-028-88457210 18190964009
Fax: QQ3213375147
Email: 3054240163@qq.com
Country: China
ProdList: 2293
Advantage: 55

Shanghai Yongzhi chemical-Technology Co., Ltd.

Tel: 021-60944093 18516153908 13917602471
Fax: 021-60944093
Email: mianyanghaodao@aliyun.com
Country: China
ProdList: 411
Advantage: 58

Shanghai Zhen Li Biological Technology Co., Ltd

Tel: 021-16621358918; 18516310516
Fax: 13045646768
Email: zhenlipharma888@163.com
Country: China
ProdList: 19035
Advantage: 58

Aikon International Limited

Tel: 025-58859352 18068836627
Fax: (5)02557626880
Email: dt3@aikonchem.com
Country: China
ProdList: 15493
Advantage: 58

Shanghai Haohong Pharmaceutical Co., Ltd.

Tel: 400-8210725 400821072
Fax: 021-58955996
Email: malulu@leyan.com
Country: China
ProdList: 25000
Advantage: 58

Shanghai Jizhi Biochemical Technology Co. Ltd.

Tel: 4009004166/18616739031 18616739031
Email: 3007523370@qq.com
Country: China
ProdList: 52687
Advantage: 58

Cool Pharm, Ltd

Tel: 021-58581007 18019463053
Fax: 021-50966098
Email: sales@coolpharm.com
Country: China
ProdList: 12878
Advantage: 58

Kanghua (Shanghai) New Drug Development Co., Ltd.

Tel: 021-61263370 18901917034
Email: xingli@glbiochem.com
Country: China
ProdList: 5637
Advantage: 58

Shanghai Jifeng Biotechnology Co., Ltd.

Tel: 021-61263377 15023907684
Fax: 021-61263399
Email: 15800684150@163.com
Country: China
ProdList: 8131
Advantage: 58

Finetech Industry Limited

Tel: +86-27-8746-5837 +8619945049750
Fax: 86 27 87772287
Email: info@finetechnology-ind.com
Country: China
ProdList: 9629
Advantage: 58

GL Biochem (Shanghai) Ltd.

Tel: +86-021-61263370 +86-18901917034
Country: CHINA
ProdList: 3904
Advantage: 58

Hefei TNJ Chemical Industry Co.,Ltd.

Tel: +86-0551-65418684 +8618949823763
Fax: 0086-551-65418684
Email: sales@tnjchem.com
Country: China
ProdList: 25356
Advantage: 58

Nextpeptide Inc

Tel: +86-0571-81612335 +8613336028439
Email: sales@nextpeptide.com
Country: China
ProdList: 19908
Advantage: 58

Dayang Chem (Hangzhou) Co.,Ltd.

Tel: +86-0571-88938639 +8617705817739
Fax: +86-571-88938652，+86-571- 88492614
Email: info@dycnchem.com
Country: China
ProdList: 52846
Advantage: 58

AFINE CHEMICALS LIMITED

Tel: +86-0571-85134551
Fax: 008657185134895
Email: sales@afinechem.com
Country: China
ProdList: 15107
Advantage: 58

GL Biochem(Binhai) Ltd.

Tel: +86-021-61263370 +8615301650015
Email: wuqiuyan@glschina.com
Country: China
ProdList: 2975
Advantage: 58

Henan Weituxi Chemical Technology Co., Ltd.

Tel: 0371-63284658 18135795563
Fax: QQ:2885349392
Email: 2885349392@qq.com
Country: China
ProdList: 9989
Advantage: 58

Chemwill Asia Co.,Ltd.

Tel: 86-21-51086038
Fax: 86-21-51861608
Email: chemwill_asia@126.com
Country: CHINA
ProdList: 23912
Advantage: 58

Binhai gill polypeptide co. LTD

Tel: 021-61263389 13524856427
Fax: WeChat630417570
Email: Joetang@glschina.com
Country: China
ProdList: 10000
Advantage: 58

Shanghai Anhua Biotechnology Co., Ltd.

Tel: 021-61263375 18168859245
Country: China
ProdList: 5958
Advantage: 58

Chongqing Chemdad Co., Ltd

Tel: +86-023-6139-8061 +86-86-13650506873
Email: sales@chemdad.com
Country: China
ProdList: 39927
Advantage: 58

Wuxi maimo topp biotechnology co., LTD

Tel: 13771048682 13771048682
Email: linda-fu@mimotopes.cn
Country: China
ProdList: 5796
Advantage: 58

Jiangsu Hongmin Pharmaceutical Co., Ltd.

Tel: 18221292452
Email: fannieliu@glschina.com
Country: China
ProdList: 6798
Advantage: 58

Jiangsu Shengkang Meixiang Technology Co., Ltd.

Tel: 18217475093
Email: 1615396342@qq.com
Country: China
ProdList: 4309
Advantage: 58

Gill polypeptide biopharmaceutical (dalian) co., LTD

Tel: 021-61263455 13167021076
Email: amy@glschina.com
Country: China
ProdList: 9736
Advantage: 58

Changzhou Kechem Bio-Scientific Co., LTD.

Tel: 0519-68985668 13685222090
Fax: qq735434464
Email: sales@kechem.cn
Country: China
ProdList: 26028
Advantage: 58

Ontores Biotech

Tel: 0571-88760729 18072970094
Email: supports@ontorespeptide.com
Country: China
ProdList: 2696
Advantage: 58

DONBOO AMINO ACID COMPANY

Tel: +8618051385538
Email: donboo@donboo.com
Country: China
ProdList: 9363
Advantage: 58

Shanghai Sunway Pharmaceutical Technology Co.,Ltd.

Tel: 021-51816796-820 13611835272
Fax: 021-5161 3951
Email: sales2@sunwaypharm.com
Country: China
ProdList: 44119
Advantage: 58

Shanghai kadel chemical technology co., LTD

Tel: 021-4007787-550 400-7787-550
Email: 2850202386@qq.com
Country: China
ProdList: 10582
Advantage: 58

TCI (Shanghai) Chemical Trading Co., Ltd.

Tel: 021-61109150
Fax: 021-61105897
Email: sales@tcisct.com
Country: China
ProdList: 29668
Advantage: 58

Bide Pharmatech Ltd.

Tel: 400-6005915
Email: sales@picasso-e.com
Country: China
ProdList: 39665
Advantage: 58

Zhengzhou Deyuankai Chemical Co., LTD

Tel: 17837139533
Email: 1165412154@qq.com
Country: China
ProdList: 7740
Advantage: 58

Beijing Solarbio Science & Tecnology Co., Ltd.

Tel: 010-50973130 17801761073
Email: Gsiyu@solarbio.com
Country: China
ProdList: 50464
Advantage: 58

Shanghai Inchman Chemical Technology Co., LTD

Tel: 18299177127
Email: info@richmanchem.com
Country: China
ProdList: 3000
Advantage: 58

Less

View Lastest Price from Z-TRP-OBZL manufacturers

Career Henan Chemical Co

Product: Z-TRP-OBZL 69876-37-5
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 1ton
Release date: 2018-08-09

Career Henan Chemical Co

Product: Z-TRP-OBZL 69876-37-5
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20kg
Release date: 2018-08-15

69876-37-5, Z-TRP-OBZLRelated Search:

N-Cbz-L-Tryptophan Z-TRP-NH2 Z-TRP-OME Z-VAL-TRP-OH Z-TRP-OSU Z-TRP(BOC)-OH DCHA Z-PHE-ALA-OH Z-TRP-TRP-OH Z-PHE-TRP-OH Z-SER-NHNH2 Z-TRP-ONP Z-TRP(FOR)-OH Z-Trp(For)-OH.DCHA Z-Trp-Lys(Boc)-NH2 tert-butyl N-[(5S)-6-amino-5-[[(2S)-3-(1H-indol-3-yl)-2-(phenylmethoxycarbonylamino)propanoyl]amino]-6-oxohexyl]carbamate N-Cbz-O-tert-butyl-L-serine Z-TYR(TBU)-OH Z-LYS-SBZL HCL

N-.ALPHA.-CBZ-L-TRYPTOPHAN BENZYL ESTER

N-Carbobenzyloxy-L-tryptphan benzyl ester

(S)-benzyl 2-(benzyloxycarbonylamino)-3-(1H-indol-3-yl)propanoate

Benzyl (S)-2-(benzyloxycarbonylamino)-3-(1H-indol-3-yl)propanoate

N-[(Phenylmethoxy)carbonyl]-L-tryptophan phenylmethyl ester

N-ALPHA-CARBOBENZOXY-L-TRYPTOPHAN ALPHA-BENZYL ESTER

Z-L-TRYPTOPHAN BENZYL ESTER

Z-TRP-OBZL

Cbz-Trp-OBzl

N-α-Z-L-tryptophan benzyl ester

N-a-Z-L-tryptophanbenzylester

Nα-Z-L-tryptophan benzyl ester≥ 99% (HPLC)

Z-L-Trp-OBzl

N-Benzyloxycarbonyl-L-tryptophan benzyl ester

benzyl (2S)-2-{[(benzyloxy)carbonyl]amino}-3-(1H-indol-3-yl)propanoate

L-Tryptophan, N-[(phenylmethoxy)carbonyl]-, phenylmethyl ester

Nα-Z-L-tryptophan benzyl ester

benzyl (2S)-2-(benzyloxycarbonylamino)-3-(1H-indol-3-yl)prop...

N-cbz-L-tryptophan benzyl ester

Benzyl N-[(benzyloxy)carbonyl]-L-tryptophanate

69876-37-5

C26H24N2O4

Tryptophan [Trp, W]

Z-Amino Acids and Derivatives

Z-Amino acid series