ChemicalBook > CAS DataBase List > TRIS(4-CHLOROPHENYL)PHOSPHINE
TRIS(4-CHLOROPHENYL)PHOSPHINE
- Product Name
- TRIS(4-CHLOROPHENYL)PHOSPHINE
- CAS No.
- 1159-54-2
- Chemical Name
- TRIS(4-CHLOROPHENYL)PHOSPHINE
- Synonyms
- tris(4-chlorophenyl)phosphane;NSC 136459;Tri(p-chlorophen;Tris(4-chlorophenyl);TRI(4-CHLOROPHENYL)PHOSPHINE;TRI(P-CHLOROPHENYL)PHOSPHINE;RIS(4-CHLOROPHENYL)PHOSPHINE;TRIS(4-CHLOROPHENYL)PHOSPHINE;TRIS(P-CHLOROPHENYL)PHOSPHINE;Tri(p-chlorophenyl)phosphine,99%
- CBNumber
- CB3372856
- Molecular Formula
- C18H12Cl3P
- Formula Weight
- 365.62
- MOL File
- 1159-54-2.mol
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TRIS(4-CHLOROPHENYL)PHOSPHINE Property
- Melting point:
- 100-103 °C (lit.)
- Boiling point:
- 427.6±40.0 °C(Predicted)
- storage temp.
- Inert atmosphere,Room Temperature
- form
- crystal
- color
- white
- Sensitive
- Air Sensitive
- BRN
- 751458
- CAS DataBase Reference
- 1159-54-2(CAS DataBase Reference)
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 249491
- Product name
- Tris(4-chlorophenyl)phosphine
- Purity
- 95%
- Packaging
- 1g
- Price
- $75.48
- Updated
- 2025/07/31
TCI Chemical
- Product number
- T2933
- Product name
- Tris(4-chlorophenyl)phosphine
- Purity
- min. 97.0 %
- Packaging
- 5G
- Price
- $71
- Updated
- 2025/07/31
TCI Chemical
- Product number
- T2933
- Product name
- Tris(4-chlorophenyl)phosphine
- Purity
- min. 97.0 %
- Packaging
- 25G
- Price
- $213
- Updated
- 2025/07/31
Strem Chemicals
- Product number
- 15-6050
- Product name
- Tri(p-chlorophenyl)phosphine, 99%
- Packaging
- 1g
- Price
- $88
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-6050
- Product name
- Tri(p-chlorophenyl)phosphine, 99%
- Packaging
- 5g
- Price
- $347
- Updated
- 2024/03/01
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TRIS(4-CHLOROPHENYL)PHOSPHINE Chemical Properties,Usage,Production
Chemical Properties
white to light yellow crystal powde
Uses
Catalyst for:
- Preparation of chromans and (E,E)-1,3-dienes via reaction of γ-substituted allenoates with aldehydes
- Solvent-free Heck reactions
Cocatalyst in:
- Regioselective carbomagnesiation of terminal alkynes and enynes with alkyl Grignard reagents
- Rhodium-catalyzed coordination-assisted regioselective alkenylation of aromatic C-H bonds with terminal silylacetylenes
- Rhodium-catalyzed hydrogenation reactions
- Platinum-catalyzed allylation reactions
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Cross Couplings
Synthesis
4576-56-1
1159-54-2
The general procedure for the synthesis of tris(4-chlorophenyl)phosphine oxide from tris(4-chlorophenyl)phosphine oxide was as follows: 5100 mg (0.262 mmol) of tris(4-chlorophenyl)phosphine oxide was reacted with 6 mg of I? (26 μmol) and 130 μL (0.52 mmol) of tributylphosphine in 1 mL of mixed solvent of acetonitrile/THF (1:1, v/v) under nitrogen protection The reaction was carried out at room temperature for 10 min. After stirring for 10 min at room temperature, the reaction was quenched with 100 μL H?O. The reaction mixture was diluted with 10 mL of ethyl acetate and washed three times (5 mL each) with saturated aqueous NaHCO?solution. The organic phase was dried with Na?SO?, filtered and concentrated under reduced pressure. The residue was recrystallized with 2 mL of methanol, the crystals were collected by filtration, washed and dried under vacuum to give 95 mg (0.260 mmol, 99%) of tris(4-chlorophenyl)phosphine.
References
[1] Patent: WO2011/123037, 2011, A1. Location in patent: Page/Page column 23-24
[2] Journal of Organic Chemistry, 2008, vol. 73, # 4, p. 1524 - 1531
[3] Chinese Chemical Letters, 2014, vol. 25, # 1, p. 176 - 178
[4] Russian Journal of General Chemistry, 2015, vol. 85, # 5, p. 1156 - 1160
[5] Zh. Obshch. Khim.,
TRIS(4-CHLOROPHENYL)PHOSPHINE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from TRIS(4-CHLOROPHENYL)PHOSPHINE manufacturers
WUHAN FORTUNA CHEMICAL CO., LTD
- Product
- Tris(4-chlorophenyl)phosphine 1159-54-2
- Price
- US $0.00/G
- Min. Order
- 100G
- Purity
- 98%min
- Supply Ability
- 30kg/month
- Release date
- 2023-02-03
Hebei Chuanghai Biotechnology Co., Ltd
- Product
- TRIS(4-CHLOROPHENYL)PHOSPHINE 1159-54-2
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20 mt
- Release date
- 2024-11-14
Shaanxi Dideu Medichem Co. Ltd
- Product
- TRIS(4-CHLOROPHENYL)PHOSPHINE 1159-54-2
- Price
- US $0.10/KG
- Min. Order
- 1KG
- Purity
- 99.0%
- Supply Ability
- 1000 tons
- Release date
- 2024-08-23
1159-54-2, TRIS(4-CHLOROPHENYL)PHOSPHINERelated Search:
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4,4',4''-TRICHLOROTRITYL ALCOHOL
TRIS(4-HYDROXYPHENYL)PHOSPHINE OXIDE
Tris(4-fluorophenyl)phosphine
Tris(4-bromophenyl)amine
Tris(4-isocyanatophenyl) thiophosphate
TRIS(4-TRIFLUOROMETHYLPHENYL)PHOSPHINE
TRIS(4-FORMYLPHENYL)AMINE
Tris(4-fluorophenyl)phosphine
Phosphine
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TRIS(4-CHLOROPHENYL)PHOSPHINE
Tri(4-chlorophenyl)phosphine oxide
TRIS(4-CHLOROPHENYL)(METHYL)PHOSPHONIUM IODIDE
Bis(tris(p-chlorophenyl)phosphine)mercuric chloride complex
TRIS(4-CHLOROPHENYL)(2,3,4,5,6-PENTAMETHYLBENZYL)PHOSPHONIUM CHLORIDE
TRIS(4-CHLOROPHENYL)PHOSPHINE OXIDE