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3-ETHYNYL-BENZOIC ACID

Product Name
3-ETHYNYL-BENZOIC ACID
CAS No.
10601-99-7
Chemical Name
3-ETHYNYL-BENZOIC ACID
Synonyms
3-ETHYNYL-BENZOIC ACID;3-Eethynylbenzoic acid;Benzoic acid, 3-ethynyl-;3-Ethynylbenzoic acid 95%;Benzoic acid, 3-ethynyl- (9CI);3-Ethynylbenzoic acid - [E50962];3-ethynylbenzoic acid(SALTDATA: FREE)
CBNumber
CB3374577
Molecular Formula
C9H6O2
Formula Weight
146.14
MOL File
10601-99-7.mol
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3-ETHYNYL-BENZOIC ACID Property

Melting point:
164-171°C
Boiling point:
300.2±25.0 °C(Predicted)
Density 
1.23±0.1 g/cm3(Predicted)
storage temp. 
2-8°C
pka
3.99±0.10(Predicted)
form 
powder
Appearance
White to off-white Solid
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Safety

Hazard Codes 
Xn
Risk Statements 
22-36-43
Safety Statements 
26-36/37/39
WGK Germany 
nwg
HS Code 
2916399090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H317May cause an allergic skin reaction

H319Causes serious eye irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
724645
Product name
3-Ethynylbenzoic acid
Purity
95%
Packaging
1g
Price
$128
Updated
2025/07/31
TRC
Product number
E937168
Product name
3-Ethynylbenzoic acid
Packaging
100mg
Price
$75
Updated
2021/12/16
AK Scientific
Product number
5335AH
Product name
3-Ethynylbenzoic acid
Packaging
1g
Price
$83
Updated
2021/12/16
Activate Scientific
Product number
AS85698
Product name
3-Ethynyl-benzoic acid
Purity
97+%
Packaging
1g
Price
$88
Updated
2021/12/16
Synthonix
Product number
E50962
Product name
3-Ethynylbenzoic acid
Purity
97%
Packaging
250mg
Price
$20
Updated
2021/12/16
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3-ETHYNYL-BENZOIC ACID Chemical Properties,Usage,Production

Synthesis

77123-59-2

10601-99-7

Step 2: Methyl 3-((trimethylsilyl)ethynyl)benzoate (105) (2.42 g) was dissolved in methanol (30 mL), and 2N aqueous sodium hydroxide solution (10.4 mL) was slowly added under cooling in an ice bath, and the reaction was stirred at room temperature for 7 hours. After completion of the reaction, the pH of the reaction mixture was adjusted to 3~4 with 2N hydrochloric acid, followed by concentration under reduced pressure. Water (100 mL) was added to the residue and extracted with ethyl acetate (100 mL). The organic layer was washed with saturated brine (100 mL), dried over anhydrous sodium sulfate and filtered. The filtrate was concentrated under reduced pressure to give 3-ethynylbenzoic acid (106) as a white solid (1.50 g, 99% yield).

References

[1] Journal of Medicinal Chemistry, 2012, vol. 55, # 22, p. 9562 - 9575
[2] Patent: JP5725475, 2015, B2. Location in patent: Paragraph 0028; 0031
[3] Patent: WO2014/168824, 2014, A1. Location in patent: Page/Page column 19

3-ETHYNYL-BENZOIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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3-ETHYNYL-BENZOIC ACID Suppliers

CHEMSTEP
Tel
--
Fax
--
Email
info@chemstep.com
Country
Europe
ProdList
6143
Advantage
51
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View Lastest Price from 3-ETHYNYL-BENZOIC ACID manufacturers

Career Henan Chemical Co
Product
3-ETHYNYL-BENZOIC ACID 10601-99-7
Price
US $6.60/KG
Min. Order
1KG
Purity
97%-99%
Supply Ability
1kg-1000kg
Release date
2019-12-26