1-(4-BROMOPHENYL)CYCLOPROPANECARBOXYLIC ACID

Product Name: 1-(4-BROMOPHENYL)CYCLOPROPANECARBOXYLIC ACID
CAS No.: 345965-52-8
Chemical Name: 1-(4-BROMOPHENYL)CYCLOPROPANECARBOXYLIC ACID
Synonyms: EOS-60374;CAS:345965-52-8;345965-52-8, MFCD07374439;1-(4-BROMOPHENYL)CYCLOPROPANECARBOXYLIC ACID;1-(4-broMophenyl)cyclopropane-1-carboxylic acid;Cyclopropanecarboxylic acid, 1-(4-broMophenyl)-;1-(4-BroMophenyl)-1-cyclopropanecarboxylic acid
CBNumber: CB3398980
Molecular Formula: C10H9BrO2
Formula Weight: 241.08
MOL File: 345965-52-8.mol

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1-(4-BROMOPHENYL)CYCLOPROPANECARBOXYLIC ACID Property

Melting point:: 160-165°
Boiling point:: 354.3±35.0 °C(Predicted)
Density: 1.670±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
form: solid
pka: 4.14±0.20(Predicted)
Appearance: White to light yellow Solid
InChI: InChI=1S/C10H9BrO2/c11-8-3-1-7(2-4-8)10(5-6-10)9(12)13/h1-4H,5-6H2,(H,12,13)
InChIKey: BYJIXWOWTNEVFO-UHFFFAOYSA-N
SMILES: C1(C2=CC=C(Br)C=C2)(C(O)=O)CC1

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Safety

HS Code: 2917399590

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P321Specific treatment (see … on this label).

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: BBO000686
Product name: 1-(4-Bromophenyl)cyclopropanecarboxylic acid
Packaging: 1 g
Price: $179
Updated: 2025/07/31

TRC

Product number: B698173
Product name: 1-(4-Bromophenyl)cyclopropanecarboxylicAcid
Packaging: 2.5g
Price: $90
Updated: 2021/12/16

SynQuest Laboratories

Product number: 2621-9-26
Product name: 1-(4-Bromophenyl)cyclopropanecarboxylic acid
Packaging: 1g
Price: $100
Updated: 2021/12/16

Oakwood

Product number: 044121
Product name: 1-(4-Bromophenyl)-cyclopropanecarboxylicacid
Purity: 97%
Packaging: 250mg
Price: $15
Updated: 2021/12/16

Matrix Scientific

Product number: 082869
Product name: 1-(4-Bromophenyl)cyclopropanecarboxylic acid
Purity: 97%
Packaging: 1g
Price: $24
Updated: 2021/12/16

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1-(4-BROMOPHENYL)CYCLOPROPANECARBOXYLIC ACID Chemical Properties,Usage,Production

Synthesis

124276-67-1

345965-52-8

General procedure for the synthesis of 1-(4-bromophenyl)cyclopropanecarboxylic acid from 1-(4-bromophenyl)cyclopropanecarbonitrile: A mixture of 1-(4-bromophenyl)cyclopropanecarbonitrile (7.5 g, 33.78 mmol), potassium hydroxide (7.6 g, 135 mmol), and ethylene glycol (50 mL) was heated to 160 °C for 6 hours. Upon completion of the reaction, the mixture was cooled to room temperature, water (200 mL) was added and the pH was adjusted to 3~4 with dilute hydrochloric acid to acidify the reaction mixture. Subsequently, the product was precipitated with 2N hydrochloric acid. The precipitate was collected by filtration to afford 1-(4-bromophenyl)cyclopropanecarboxylic acid (5.6 g, 69% yield). Mass spectrum (ESI) m/z (M+H)+ 240.

References

[1] Patent: US6359135, 2002, B1. Location in patent: Page column 113
[2] Patent: US6369225, 2002, B1. Location in patent: Page column 42, 112
[3] Journal of Medicinal Chemistry, 2010, vol. 53, # 16, p. 6003 - 6017
[4] Bioorganic and Medicinal Chemistry Letters, 2010, vol. 20, # 3, p. 887 - 892
[5] Patent: WO2013/25733, 2013, A1. Location in patent: Paragraph 0490

1-(4-BROMOPHENYL)CYCLOPROPANECARBOXYLIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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1-(4-BROMOPHENYL)CYCLOPROPANECARBOXYLIC ACID Suppliers

China 163 India 2 Ukraine 2 United Kingdom 2 United States 13 Global 182

Suzhou Sino Rare Chemical Co., Ltd.

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View Lastest Price from 1-(4-BROMOPHENYL)CYCLOPROPANECARBOXYLIC ACID manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: 1-(4-Bromophenyl)cyclopropanecarboxylic acid 345965-52-8
Price: US $2.20-8.80/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100kg
Release date: 2025-06-17

Henan Aochuang Chemical Co.,Ltd.

Product: 1-(4-BROMOPHENYL)CYCLOPROPANECARBOXYLIC ACID 345965-52-8
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-10-13

Career Henan Chemical Co

Product: 1-(4-BROMOPHENYL)CYCLOPROPANECARBOXYLIC ACID 345965-52-8
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 150KG
Release date: 2019-07-01

345965-52-8, 1-(4-BROMOPHENYL)CYCLOPROPANECARBOXYLIC ACIDRelated Search:

1-(4-nitrophenyl)propan-2-one t-Butyl 1-(4-bromophenyl)cyclopropylcarbamate 3-(4-BROMOPHENYL)PROPIONITRILE Cyclopropanecarboxylic acid 2-(4-BROMOPHENYL)CYCLOPROPANECARBOXYLIC ACID 1-(3-BROMOPHENYL)CYCLOPROPANECARBOXYLIC ACID 1-(3,4-DIBROMOPHENYL)CYCLOPROPANECARBOXYLIC ACID 1-Phenyl-1-cyclopropanecarboxylic acid 1-(4-BROMOPHENYL)CYCLOPROPANECARBOXYLIC ACID 1-phenylcyclopropanemethanol 2-(4-Bromophenyl)-2-methylpropionic acid 1-Bromo-4-cyclopropylbenzene

1-(4-BROMOPHENYL)CYCLOPROPANECARBOXYLIC ACID

1-(4-BroMophenyl)-1-cyclopropanecarboxylic acid

Cyclopropanecarboxylic acid, 1-(4-broMophenyl)-

1-(4-broMophenyl)cyclopropane-1-carboxylic acid

EOS-60374

345965-52-8, MFCD07374439

CAS:345965-52-8

345965-52-8

pharmacetical

Carboxylic Acids

Ring Systems