ChemicalBook > CAS DataBase List > METHYL 1-METHYLPYRROLE-2-CARBOXYLATE

METHYL 1-METHYLPYRROLE-2-CARBOXYLATE

Product Name: METHYL 1-METHYLPYRROLE-2-CARBOXYLATE
CAS No.: 37619-24-2
Chemical Name: METHYL 1-METHYLPYRROLE-2-CARBOXYLATE
Synonyms: RARECHEM AL BF 0084;2-Methoxycarbonyl-1-methylpyrrole;Methyl 1-Methyl-2-pyrrolecarboxylate;methyl N-methylpyrrole-2-carboxylate;Methyl-4-methylpyrrole-2-carboxylate;METHYL 1-METHYLPYRROLE-2-CARBOXYLATE;Methyl1-methylpyrrole-2-carboxylate,98%;METHYL 1-METHYL-1H-PYRROLE-2-CARBOXYLATE;1-METHYLPYRROLE-2-CARBOXYLIC ACID METHYL ESTER;1-Methyl-1H-pyrrole-2-carboxylic acid methyl ester
CBNumber: CB3407697
Molecular Formula: C7H9NO2
Formula Weight: 139.15
MOL File: 37619-24-2.mol

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METHYL 1-METHYLPYRROLE-2-CARBOXYLATE Property

Melting point:: 80 °C (sublm)(Press: 0.2 Torr)
Boiling point:: 96-98°C 15mm
Density: 1.07±0.1 g/cm3(Predicted)
refractive index: 1.5220
Flash point:: 96-98°C/15mm
storage temp.: Sealed in dry,Room Temperature
pka: -7.04±0.70(Predicted)
Appearance: Light yellow to brown Liquid
Water Solubility: Slightly soluble in water.
BRN: 116477
CAS DataBase Reference: 37619-24-2(CAS DataBase Reference)

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Safety

HazardClass: IRRITANT
HS Code: 2933998090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: B451520
Product name: Methyl1-Methylpyrrole-2-carboxylate
Packaging: 100mg
Price: $75
Updated: 2021/12/16

Matrix Scientific

Product number: 045456
Product name: Methyl 1-methyl-1H-pyrrole-2-carboxylate
Purity: >95%
Packaging: 5g
Price: $59
Updated: 2021/12/16

SynQuest Laboratories

Product number: 4H23-1-4S
Product name: Methyl 1-methyl-1H-pyrrole-2-carboxylate
Packaging: 1g
Price: $96
Updated: 2021/12/16

Matrix Scientific

Product number: 045456
Product name: Methyl 1-methyl-1H-pyrrole-2-carboxylate
Purity: >95%
Packaging: 500mg
Price: $10
Updated: 2021/12/16

Matrix Scientific

Product number: 045456
Product name: Methyl 1-methyl-1H-pyrrole-2-carboxylate
Purity: >95%
Packaging: 1g
Price: $14
Updated: 2021/12/16

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METHYL 1-METHYLPYRROLE-2-CARBOXYLATE Chemical Properties,Usage,Production

Uses

Methyl 1-methylpyrrole-2-carboxylate is used as chemical and organic Intermediates.

Synthesis

1193-62-0

74-88-4

37619-24-2

Methyl-1H-pyrrole-2-carboxylate (10 g, 79.9 mmol) was dissolved in anhydrous THF (200 mL) at 0 °C and NaH (3.52 g, 60% w/w, 87.9 mmol) was slowly added. The reaction mixture was stirred at 20 °C for 30 min before CH3I (13.62 g, 95.9 mmol) was added dropwise. The reaction was continued to be stirred at 20 °C for 17 hours. After completion of the reaction, the reaction was quenched by slowly pouring the mixture into aqueous NH4Cl (200 mL). The aqueous phase was extracted with EtOAc (200 mL x 2), the organic layers were combined and washed with brine (150 mL), dried over anhydrous Na2SO4, filtered and concentrated under reduced pressure. The crude product was purified by silica gel column chromatography (eluent: EtOAc/petroleum ether=1/20) to afford methyl 1-methyl-1H-pyrrole-2-carboxylate (9.88 g, 71 mmol, 89% yield) as a yellow oil. Mass spectrum (EI+, m/z): 140.1 [M+H]+.

References

[1] Organic Letters, 2015, vol. 17, # 11, p. 2652 - 2655
[2] Patent: WO2018/89493, 2018, A1. Location in patent: Paragraph 00214
[3] Bioorganic and Medicinal Chemistry Letters, 2008, vol. 18, # 11, p. 3219 - 3223

METHYL 1-METHYLPYRROLE-2-CARBOXYLATE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from METHYL 1-METHYLPYRROLE-2-CARBOXYLATE manufacturers

Career Henan Chemical Co

Product: METHYL 1-METHYLPYRROLE-2-CARBOXYLATE 37619-24-2
Price: US $9.80/KG
Min. Order: 1g
Purity: ≥99%
Supply Ability: 100kg
Release date: 2019-12-25

37619-24-2, METHYL 1-METHYLPYRROLE-2-CARBOXYLATERelated Search:

TERT-BUTYL 1-METHYL-4-NITRO-1H-PYRROLE-2-CARBOXYLATE METHYL 1-METHYLPYRROLE-2-CARBOXYLATE methyl 1-methyl-1H-indole-2-carboxylate METHYL 2,5-DIMETHYLPYRROLE-3-CARBOXYLATE Methyl 2-pyrrolecarboxylate ETHYL 1-(4-CHLOROBENZYL)-3-(1H-PYRROL-1-YL)-1H-INDOLE-2-CARBOXYLATE ETHYL 1-[3-CHLORO-5-(TRIFLUOROMETHYL)-2-PYRIDINYL]-1H-PYRROLE-2-CARBOXYLATE ETHYL 4-CHLORO-5-METHYL-7-PHENYL-7H-PYRROLO[2,3-D]PYRIMIDINE-6-CARBOXYLATE METHYL 4-(2,4-DICHLOROBENZOYL)-1-METHYL-1H-PYRROLE-2-CARBOXYLATE METHYL 4-ACETYL-1-METHYL-1H-PYRROLE-2-CARBOXYLATE ETHYL 1-(4-METHYLBENZYL)-3-(1H-PYRROL-1-YL)-1H-INDOLE-2-CARBOXYLATE METHYL 4-(2,3-DICHLOROBENZOYL)-1-METHYL-1H-PYRROLE-2-CARBOXYLATE ETHYL 1-[3-CHLORO-5-(TRIFLUOROMETHYL)-2-PYRIDINYL]-3-(1H-PYRROL-1-YL)-1H-INDOLE-2-CARBOXYLATE 3-OXO-1-CYCLOHEXENYL 1-[3-CHLORO-5-(TRIFLUOROMETHYL)-2-PYRIDINYL]-1H-PYRROLE-2-CARBOXYLATE ETHYL 1-(2-CHLOROBENZYL)-3-(1H-PYRROL-1-YL)-1H-INDOLE-2-CARBOXYLATE 4H,6H-BENZO[E]PYRROLO[2,1-C][1,4]OXAZEPINE-4,6-DIONE METHYL 5-[2-(4-CHLOROPHENYL)-1-CYANOVINYL]-1-METHYL-1H-PYRROLE-2-CARBOXYLATE ETHYL 1-BENZYL-3-(1H-PYRROL-1-YL)-1H-INDOLE-2-CARBOXYLATE

RARECHEM AL BF 0084

1-METHYLPYRROLE-2-CARBOXYLIC ACID METHYL ESTER

METHYL 1-METHYL-1H-PYRROLE-2-CARBOXYLATE

METHYL 1-METHYLPYRROLE-2-CARBOXYLATE

Methyl-4-methylpyrrole-2-carboxylate

1-Methyl-1H-pyrrole-2-carboxylic acid methyl ester

methyl N-methylpyrrole-2-carboxylate

1H-Pyrrole-2-carboxylicacid, 1-methyl-, methyl ester

Methyl 1-Methyl-2-pyrrolecarboxylate

Methyl1-methylpyrrole-2-carboxylate,98%

2-Methoxycarbonyl-1-methylpyrrole

37619-24-2