Chemical Properties Uses Preparation
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Lithium sulfate

Chemical Properties Uses Preparation
Product Name
Lithium sulfate
CAS No.
10377-48-7
Chemical Name
Lithium sulfate
Synonyms
Li2SO4;LITHIUM SULPHATE;Lithium sulphat;Lithiophor;ithium suL;Lithiumsulfat;Lithium-Duriles;LITHIUM SULFATE;Dilthium sulfate;Dilithium sulfate
CBNumber
CB3408669
Molecular Formula
Li2O4S
Formula Weight
109.9446
MOL File
10377-48-7.mol
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Lithium sulfate Property

Melting point:
845 °C (lit.)
Density 
2.22 g/mL at 25 °C (lit.)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
absolute ethanol: insoluble(lit.)
form 
Powder
pka
2.08[at 20 ℃]
color 
White
PH
6.0-9.0 (25℃, 2M in H2O)
Water Solubility 
25.7 g/100 mL (25 ºC)
Sensitive 
Hygroscopic
λmax
λ: 260 nm Amax: 0.08
λ: 280 nm Amax: 0.04
Merck 
14,5541
Stability:
Hygroscopic
CAS DataBase Reference
10377-48-7(CAS DataBase Reference)
NIST Chemistry Reference
Lithium sulfate(10377-48-7)
EPA Substance Registry System
Sulfuric acid, dilithium salt (10377-48-7)
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Safety

Hazard Codes 
Xn
Risk Statements 
22-36/37/38
Safety Statements 
26-36/37-24/25
WGK Germany 
1
RTECS 
OJ6419000
TSCA 
Yes
HS Code 
28332990
Toxicity
mammal (species unspecified),LD50,intramuscular,560mg/kg (560mg/kg),Farmakologiya i Toksikologiya Vol. 9, Pg. 113, 1974.
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
62613
Product name
Lithium sulfate
Purity
purum p.a., ≥98.0% (T)
Packaging
1kg
Price
$308
Updated
2024/03/01
Sigma-Aldrich
Product number
203653
Product name
Lithium sulfate
Purity
≥99.99% trace metals basis
Packaging
10g
Price
$68.4
Updated
2024/03/01
Sigma-Aldrich
Product number
82348
Product name
Lithium sulfate solution
Purity
BioUltra, 2?M in H2O
Packaging
100mL
Price
$101
Updated
2023/06/20
Alfa Aesar
Product number
012983
Product name
Lithium sulfate hydrate, Puratronic?, 99.996% (metals basis)
Packaging
25g
Price
$132.65
Updated
2024/03/01
Alfa Aesar
Product number
012983
Product name
Lithium sulfate hydrate, Puratronic?, 99.996% (metals basis)
Packaging
5g
Price
$37.7
Updated
2023/06/20
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Lithium sulfate Chemical Properties,Usage,Production

Chemical Properties

Lithium sulfate is a colorless monoclinic or hexagonal crystalline solid. It is the lithium salt of sulfuric acid. Although lithium sulfate solution is prepared in a large quantity as an intermediate in the spodumene-sulfuric acid process, the pure compound has only limited industrial use. It is used in small quantities in molten salt baths for the chemical strengthening of glass.

The dissolved lithium sulfate is converted into lithium carbonate by adding sodium carbonate (NaCO3).The sodium replaces the lithium in the sulfate compound.This reaction works this way because sodium is more reactive than lithium.

Uses

Lithium sulfate is used in making a special type of high strength glass. It also is used in medicine as an antidepressant.

Preparation

Lithium sulfate is prepared by neutralization of lithium hydroxide or lithium carbonate with sulfuric acid followed by crystallization:
2LiOH + H2SO4 → Li2SO4 + H2O
Li2CO3 + H2SO4 → Li2SO4 + CO2 + H2O
The product obtained from crystallization in a concentrated solution is the monohydrate, Li2SO4•H2O. Anhydrous salt is obtained by heating the monohydrate in a vacuum.

Chemical Properties

White crystalline powder

Uses

Lithium sulfate, anhydrous is used to treat bipolar disorder, solar panels and the potential for a new class of battery, and used as a catalyst for the elimination reaction.

Definition

ChEBI: Lithium sulfate is a metal sulfate in which the counterion is lithium and the ratio of lithium to sulfate is 2:1. It has a role as an antidepressant. It contains a lithium(1+).

Preparation

Industrially lithium sulfate and its monohydrate are prepared by the same basic procedure. Lithium sulfate monohydrate is isolated by evaporation of a solution of lithium sulfate made by the reaction of sulfuric acid with either lithium hydroxide or lithium carbonate. The lithium sulfate monohydrate may be converted to anhydrous lithium sulfate by drying at slightly over 100°C.

Flammability and Explosibility

Non flammable

Purification Methods

Crystallise it from H2O (4mL/g) by partial evaporation, and dry it above 130o in vacuo.

Lithium sulfate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Lithium sulfate manufacturers

Henan Fengda Chemical Co., Ltd
Product
Lithium sulfate 10377-48-7
Price
US $8.00-1.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-04-03
Hebei Yanxi Chemical Co., Ltd.
Product
Lithium sulfate 10377-48-7
Price
US $30.00-10.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
20 tons
Release date
2023-10-25
Hebei Guanlang Biotechnology Co., Ltd.
Product
Lithium sulfate 10377-48-7
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2023-01-07

10377-48-7, Lithium sulfateRelated Search:


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