[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride

Reaction

Product Name: [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride
CAS No.: 15629-92-2
Chemical Name: [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride
Synonyms: NiCl2(dppp);Ni(dppp)Cl2;(1,3-dppp)NiCl2;[1,3-BIS(DIPHENYLPHOSPHINO)PROPANE]DICHLORONICKEL(II);1,3-BIS(DIPHENYLPHOSPHINO)PROPANE NICKEL (II) CHLORIDE;1,3-Bis(diphenyl phosphine)propane nickel(II)dichloride;1,3-B;NiCl2(DPPP)NiCl2(DPPP);phosphino)propane]dichL;1,3-Bis(diphenylphosphino
CBNumber: CB3416370
Molecular Formula: C27H26Cl2NiP2
Formula Weight: 542.04
MOL File: 15629-92-2.mol

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[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride Property

Melting point:: 213 °C (dec.)(lit.)
storage temp.: Inert atmosphere,Room Temperature
form: crystal
color: red
Water Solubility: insoluble
Hydrolytic Sensitivity: 4: no reaction with water under neutral conditions
Exposure limits: NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
InChIKey: ZBQUMMFUJLOTQC-UHFFFAOYSA-L
CAS DataBase Reference: 15629-92-2(CAS DataBase Reference)

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Safety

Hazard Codes: T,Xn
Risk Statements: 49-36/37/38-42/43-40
Safety Statements: 53-26-36/37/39-45-24-22
RIDADR: 3282
WGK Germany: 3
F: 10-21
TSCA: No
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H334May cause allergy or asthma symptoms or breathing difficulties if inhaled

H335May cause respiratory irritation

H350May cause cancer

Precautionary statements

P201Obtain special instructions before use.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 335363
Product name: [1,3-Bis(diphenylphosphino)propane]dichloronickel(II)
Packaging: 5g
Price: $82.1
Updated: 2024/03/01

Sigma-Aldrich

Product number: 335363
Product name: [1,3-Bis(diphenylphosphino)propane]dichloronickel(II)
Packaging: 25g
Price: $152
Updated: 2024/03/01

TCI Chemical

Product number: B1313
Product name: [1,3-Bis(diphenylphosphino)propane]nickel(II) Dichloride
Purity: >98.0%(T)
Packaging: 5g
Price: $32
Updated: 2024/03/01

TCI Chemical

Product number: B1313
Product name: [1,3-Bis(diphenylphosphino)propane]nickel(II) Dichloride
Purity: >98.0%(T)
Packaging: 25g
Price: $109
Updated: 2024/03/01

Alfa Aesar

Product number: 030167
Product name: Dichloro[bis(1,3-diphenylphosphino)propane]nickel(II)
Packaging: 2g
Price: $60.7
Updated: 2024/03/01

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[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride Chemical Properties,Usage,Production

Reaction

Nickel catalyst used in the N-heterocycle-directed cross-coupling of fluorinated arenes with organozinc reagents.
Nickel catalyst used in the (E)-selective semihydrogenation of internal alkynes.
Nickel catalyst used in the borylation of halides and pseudohalides.

Chemical Properties

red to red-brown powder or crystals

Uses

suzuki reaction.
Dichloro[bis(1,3-diphenylphosphino)propane]nickel(II) is used as an effective catalyst for Kumada coupling and Suzuki reactions. It also catalyzes other reactions to convert enol ethers, dithioacetals and vinyl sulfides to olefins. Further, it is used as a catalyst for preparation of block-copolythiophenes and solid state metathesis polycondensation.

Application

Catalyst for:
Synthesis of block-copolythiophenes
Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acids
Solid state metathesis polycondensation
Polymerization of poly(3-alkoxythiophene)s
Diastereoselective Nozaki-Hiyama-Kishi coupling reactions of C1-C19 fragment of macrolide antibiotic aplyronine A
Transfer condensation polymerization of conjugated polymers
[1,3-Bis(diphenylphosphino)propane]dichloronickel(II) can be used as a precursor to synthesize metal-fullerene coordination complexes by reduction method.

reaction suitability

core: nickel
reaction type: Cross Couplings
reagent type: catalyst

[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride Preparation Products And Raw materials

Raw materials

Nickel(II) chloride hexahydrate Diphenylphosphine Ethanol 1,3-Dichloropropane 1,3-Bis(diphenylphosphino)propane 1,3-Dibromopropane Tetrahydrofuran Ethyl acetate Hydrochloric acid Dichloromethane Sodium hydroxide Triphenylphosphine PETROLEUM ETHER Lithium

Preparation Products

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[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride Suppliers

Americas 1 Australia 1 Belgium 2 Canada 1 China 314 Europe 3 France 1 Germany 7 India 7 Japan 8 Russia 1 Singapore 1 Switzerland 3 United Kingdom 9 United States 47 Global 406

Puyang Huicheng Electronic Material Co. Ltd.

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Alfa Aesar

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TAIYUAN RHF CO.,LTD.

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TCI (Shanghai) Development Co., Ltd.

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View Lastest Price from [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride manufacturers

Xinxiang Hongqi District Houyuan Trading Co.,Ltd

Product: [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride 15629-92-2
Price: US $30.00-28.00/Kg
Min. Order: 1Kg
Purity: 99.0% up
Supply Ability: 50 tons per month
Release date: 2022-11-10

henan kanbei chemical co.,ltd

Product: [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride 15629-92-2
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 1000kg
Release date: 2022-09-23

Zhuozhou Wenxi import and Export Co., Ltd

Product: [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride 15629-92-2
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-10

15629-92-2, [1,3-Bis(diphenylphosphino)propane]nickel(II) chlorideRelated Search:

Ammonium chloride Choline chloride Potassium chloride 1,5-Diphenylcarbazide N-(Carboxymethyl)-N-(phosphonomethyl)-glycine Chlorodiphenylphosphine Nickel(II) chloride hexahydrate Sodium chloride BIS-Tris Propane Nickel chloride Calcium chloride Propane 1,3-BIS(PHENYLPHOSPHINO)PROPANE 1,3-BIS(DIMETHYLPHOSPHINO)PROPANE Methylene Chloride DICHLOROBIS(TRIMETHYLPHOSPHINE)NICKEL(II) 1,3-Bis(diphenylphosphino)propane Nickel

NiCl2(DPPP)NiCl2(DPPP)

1.3-Bis(dipheny phosphine) propane nickel(II)chloride

DICHLORO[1,3-BIS-(DIPHENYLPHOSPHINO)PROPANE] NICKE

NICL2(DPPP)/ 1,3-BIS(DIPHENY PHOSPHINE) PROPANE NICKEL(II)CHLORIDE

1,3-Bis(diphenyl phosphine)propane nickel(II)dichloride

1,3-Bis-(diphenylphosphino)-propane nickel chloride

Dichlorobis(1,3-diphenylphosphino)propaneünickel(II), C 59.9%

(1,3-dppp)NiCl2, 1,3-Bis(diphenylphosphino)propane nickel(II) chloride

Dichloro1,3-Bis-(diphenylphosphino ) propane nickel (II)（DPPE.Nicl2） 98%

1,3-Bis(diphenylphosphino)propane nickel(II) chlor

1,3-B

3-Bis(diphenylphosphino)propane]nickel(II) chloride

(1,3-dppp)NiCl2

Ni(dppp)Cl2

phosphino)propane]dichL

NiCl2(dppp)

[1,3-Bis(diphenylphosphino)propane]dichloronicke(II)

B**[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride

[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride, 99% 1GR

[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride, 99% 5GR

DICHLORO[1,3-BIS(DIPHENYLPHOSPHINO)PROPANE]NICKEL(II)

[1,3-BIS(DIPHENYLPHOSPHINO)PROPANE]DICHLORONICKEL(II)

1,3-BIS(DIPHENYLPHOSPHINO)PROPANE NICKEL (II) CHLORIDE

[1,3-BIS(DIPHENYLPHOSPHINO)PROPANE]NICKEL(II) DICHLORIDE

1,3-BIS(DIPHENYLPHOSPHINE)PROPANE NICKEL(II) CHLORIDE

1,3-Bis(diphenylphosphiNA)propane nickel(II) chloride

1,3-Bis(diphenylphosphino)propane nickel(II) chloride,98% (DPPP)NiCl2

[1,3-Bis(diphenylphosphino)propane]dichloronickel(II) Dichloro[1,3-bis(diphenylphosphino)propane]nickel(II)

(1,3-Bis[Diphenylphosphino]Propane)Dichloronickel

Dichloro[bis(1,3-diphenylphosphino)propane]nickel(II)

1,3-BIS-(DIPHENYLPHOSPHINO)-PROPAN-

1,3-Bis(dipenylphosphino)propanenickel(II) chloride

Dichloro[1,3-Bis-(Diphenylphos

1,3-Bis(diphenylphosphino)propanenickel(II)chloride,99%

1,3-Bis(diphenylphosphino)propane nickel(Ⅱ) chloride

[1,3-Bis(diphenylphosphino)propane]nickel(II) Dichloride &gt

1,3-Bis(diphenylphosphino)propane nickel(II) chloride, 99%, reagent grade

[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride ISO 9001：2015 REACH

1, 3-bis (diphenylphosphine propane) nickel dichloride

Dichloro[1,1'-(1,3-propanediyl)bis[1,1-diphenylphosphine-κP]]nickel

(1,3-Bis(diphenylphosphino) propane)dichloridenickel(II)

1,3-Bis(diphenylphosphino

Nickel, dichloro[1,1′-(1,3-propanediyl)bis[1,1-diphenylphosphine-κP]]-

Dichloro[1,1'-bis(diphenylphosphino)ferrocene]nickel(II)

di-cyclohexylphosphino)ferrocene]

3-diphenylphosphanylpropyl(diphenyl)phosphane dichloronickel

15629-92-2

C27H26CI2NIP2

C27H26Cl2P2Ni

C6H52PCH23PC6H52NiCl2

C27H26P2NiCl2

C6H52PCH2CH2CH2PC6H52NiCl2

C27H26Cl2NiP2

Catalysts for Organic Synthesis

Classes of Metal Compounds

Homogeneous Catalysts

Metal Complexes

Transition Metal Compounds