ChemicalBook > CAS DataBase List > 4-Iodobenzyl bromide
4-Iodobenzyl bromide
- Product Name
- 4-Iodobenzyl bromide
- CAS No.
- 16004-15-2
- Chemical Name
- 4-Iodobenzyl bromide
- Synonyms
- SKL242;EGFR-1（18-;R-Protopanoxadiol;p-odobenzyl bromide;P-IODOBENZYL BROMIDE;4-IODOBENZYL BROMIDE;à-bromo-4-iodotoluene;α-broMo-4-iodotoluene;4-IodobenzylBromide>4-Iodobenzyl bromide,97%
- CBNumber
- CB3421989
- Molecular Formula
- C7H6BrI
- Formula Weight
- 296.93
- MOL File
- 16004-15-2.mol
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4-Iodobenzyl bromide Property
- Melting point:
- 78-82 °C(lit.)
- Boiling point:
- 140°C 15mm
- Density
- 2.0672 (rough estimate)
- refractive index
- 1.6500 (estimate)
- Flash point:
- 140°C/15mm
- storage temp.
- 2-8°C
- form
- Adhering Crystalline Powder
- color
- Light yellow
- Water Solubility
- Insoluble in water.
- Sensitive
- Light Sensitive/Lachrymatory
- BRN
- 2325160
- InChI
- InChI=1S/C7H6BrI/c8-5-6-1-3-7(9)4-2-6/h1-4H,5H2
- InChIKey
- BQTRMYJYYNQQGK-UHFFFAOYSA-N
- SMILES
- C1(CBr)=CC=C(I)C=C1
- CAS DataBase Reference
- 16004-15-2(CAS DataBase Reference)
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Safety
- Hazard Codes
- C,T
- Risk Statements
- 34-63-42/43-36/37/38
- Safety Statements
- 26-36/37/39-45-23
- RIDADR
- UN 3261 8/PG 2
- WGK Germany
- 3
- Hazard Note
- Corrosive/Lachrymatory/Light Sensitive
- HazardClass
- IRRITANT
- HazardClass
- 8
- PackingGroup
- Ⅱ
- HS Code
- 29039990
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P363Wash contaminated clothing before reuse.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 515604
- Product name
- 4-Iodobenzyl bromide
- Purity
- 95%
- Packaging
- 1g
- Price
- $34.8
- Updated
- 2025/07/31
Sigma-Aldrich
- Product number
- 515604
- Product name
- 4-Iodobenzyl bromide
- Purity
- 95%
- Packaging
- 5g
- Price
- $103.94
- Updated
- 2025/07/31
TCI Chemical
- Product number
- I0571
- Product name
- 4-Iodobenzyl Bromide
- Packaging
- 5G
- Price
- $62
- Updated
- 2025/07/31
TCI Chemical
- Product number
- I0571
- Product name
- 4-Iodobenzyl Bromide
- Packaging
- 25G
- Price
- $277
- Updated
- 2025/07/31
TRC
- Product number
- I737248
- Product name
- 4-Iodobenzyl Bromide
- Packaging
- 2.5g
- Price
- $75
- Updated
- 2021/12/16
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4-Iodobenzyl bromide Chemical Properties,Usage,Production
Chemical Properties
light yellow adhering crystalline powder
Uses
4-Iodobenzyl bromide is used as an organic chemical synthesis intermediate.
Synthesis
624-31-7
16004-15-2
4-Iodotoluene (Compound 1C, 25 g) was added with N-bromosuccinimide (23.5 g) and benzoyl peroxide (375 mg) in carbon tetrachloride (375 ml) and heated to reflux for 7 hours under light conditions. After completion of the reaction, the mixture was stirred at room temperature overnight. Subsequently, the insoluble material was removed by filtration and the filtrate was concentrated under reduced pressure. The concentrated residue was recrystallized with ethyl acetate and hexane to afford the target product 4-iodobenzyl bromide (Compound 1D) in 60.3% yield. [0027] NMR hydrogen spectral data (CDCl3, with TMS as internal standard): δ 7.72 (d, 2H), 7.14 (d, 2H), 4.39 (s, 2H).
References
[1] Macromolecules, 2013, vol. 46, # 12, p. 4754 - 4763
[2] Acta Crystallographica Section C: Crystal Structure Communications, 2003, vol. 59, # 4, p. o216-o218
[3] Journal of Materials Chemistry C, 2015, vol. 3, # 4, p. 734 - 741
[4] Chemistry - An Asian Journal, 2017, vol. 12, # 6, p. 690 - 697
[5] Journal of Organic Chemistry, 2014, vol. 79, # 1, p. 223 - 229
4-Iodobenzyl bromide Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 4-Iodobenzyl bromide manufacturers
Hefei Lbao Physical & Chemical Science Co.,Ltd
- Product
- 4-Iodobenzyl bromide 16004-15-2
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- Customise
- Release date
- 2025-11-07
Shenzhen Nexcon Pharmatechs Ltd.
- Product
- 4-Iodobenzyl bromide 16004-15-2
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 2000
- Release date
- 2025-09-04
Hebei Chuanghai Biotechnology Co., Ltd
- Product
- 4-Iodobenzyl bromide 16004-15-2
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20 mt
- Release date
- 2024-11-13
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