ChemicalBook > CAS DataBase List > 4-Chlorobenzyl chloride

4-Chlorobenzyl chloride

Product Name
4-Chlorobenzyl chloride
CAS No.
104-83-6
Chemical Name
4-Chlorobenzyl chloride
Synonyms
P-CHLOROBENZYL CHLORIDE;PCBC;CHLOROBENZYL CHLORIDE;PARA-CHLOROBENZYLCHLORIDE;a13-14884;NSC 34032;p-chlorobenzyl;AKOS BBS-00003957;,4-Dichlorotoluene;A,P-DICHLOROTOLUENE
CBNumber
CB9141470
Molecular Formula
C7H6Cl2
Formula Weight
161.03
MOL File
104-83-6.mol
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4-Chlorobenzyl chloride Property

Melting point:
27-29 °C (lit.)
Boiling point:
216-222 °C (lit.)
Density 
1.26
Flash point:
208 °F
refractive index 
1.5575
storage temp. 
Store at RT.
solubility 
insoluble
form 
Crystalline Low Melting Solid
Specific Gravity
1.26
color 
Colorless to white
Water Solubility 
insoluble
Sensitive 
Lachrymatory
BRN 
471558
Henry's Law Constant
2.9×10-2 mol/(m3Pa) at 25℃, HSDB (2015)
Stability:
Moisture Sensitive
Major Application
environmental
pharmaceutical
InChI
1S/C7H6Cl2/c8-5-6-1-3-7(9)4-2-6/h1-4H,5H2
InChIKey
JQZAEUFPPSRDOP-UHFFFAOYSA-N
SMILES
ClCc1ccc(Cl)cc1
CAS DataBase Reference
104-83-6(CAS DataBase Reference)
NIST Chemistry Reference
Benzene, 1-chloro-4-(chloromethyl)-(104-83-6)
EPA Substance Registry System
4-Chlorobenzyl chloride (104-83-6)
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Safety

Hazard Codes 
C,N,Xn
Risk Statements 
34-51/53-20/21/22-52/53-43-22
Safety Statements 
26-36/37/39-45-29-61-36/37
RIDADR 
UN 2235 6.1/PG III (CHLOROBENZYL CHLORIDES, LIQUID)
RIDADR 
UN 3427 6.1/PG III (CHLOROBENZYL CHLORIDES, SOLID)
WGK Germany 
2
RTECS 
XT0720000
F 
19-21
Hazard Note 
Corrosive/Lachrymatory
TSCA 
TSCA listed
HazardClass 
6.1
PackingGroup 
III
HS Code 
29049090
Storage Class
6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
Hazard Classifications
Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Aquatic Chronic 2
Skin Sens. 1
Hazardous Substances Data
104-83-6(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H317May cause an allergic skin reaction

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
111961
Product name
4-Chlorobenzyl chloride
Purity
95%
Packaging
100g
Price
$79.5
Updated
2026/03/19
Sigma-Aldrich
Product number
111961
Product name
4-Chlorobenzyl chloride
Purity
95%
Packaging
500g
Price
$112
Updated
2026/03/19
TCI Chemical
Product number
D0421
Product name
4-Chlorobenzyl Chloride
Packaging
25G
Price
$37
Updated
2026/03/19
TCI Chemical
Product number
D0421
Product name
4-Chlorobenzyl Chloride
Packaging
500G
Price
$172
Updated
2026/03/19
Sigma-Aldrich
Product number
67575
Product name
4-Chlorobenzyl chloride
Purity
analytical standard
Packaging
100mg
Price
$95.9
Updated
2022/05/15
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4-Chlorobenzyl chloride Chemical Properties,Usage,Production

Chemical Properties

Colorless to light yellow liqui

Uses

Reagent used in derivatization of, for example, a calix[4]arene1 and a tryptamine.2

Uses

4-Chlorobenzyl Chloride is a benzylchloride derivative used in the preparation of various biologically active compounds such as bronchodilators and antibacterial agents.

Uses

4-Chlorobenzyl chloride was the test compound for determining rat hepatocellular thiols by HPLC. As a reagent used in derivatization of, for example, a calix[4]arene and a tryptamine. It is widely used as an intermediate for manufacturing organic compounds like benzyl alcohol and benzyl cyanide. Also used in fuel as a gum inhibitor.

General Description

4-Chlorobenzyl chloride is generally used in the preparation of quaternary ammonium salts. It acts as an intermediate in the production of rice herbicide, pharmaceuticals and pesticides.

Hazard

Irritating to skin, eyes.

Purification Methods

Dry it over CaSO4, then fractionally distil it under reduced pressure. Crystallise it from heptane or dry diethyl ether at low temperature. [Beilstein 5 IV 816.] LACHRYMATORY.

4-Chlorobenzyl chloride Preparation Products And Raw materials

Raw materials

Benzoyl peroxide AIBN Chlorine Zinc chloride Paraformaldehyde Sulfuryl chloride 4-Chlorotoluene

Preparation Products

1-(4-CHLOROBENZYL)PIPERAZINE 2-(4-CHLORO-PHENYL)-ACETAMIDINE 2-(4-chlorophenyl)-3-oxovaleronitrile SULCONAZOLE Paclobutrazol W.P. 4-Chlorodiphenylmethane 4-Chlorobenzylamine Thiobencarb 4-Chlorobenzaldehyde Butoconazole 3-(4-Chlorophenyl)propanoic acid 4-Chlorobenzyl cyanide 2-(4-Chlorophenyl)-3-methylbutyric acid 1-(4-chlorobenzyl)-(1H-1，2，4-triazol-yl)-pinacolone 4-CHLOROBENZYL MERCAPTAN 4-Chlorobenzylsulfonyl chloride 4-(4-CHLORO-BENZYLOXY)-PHENYLAMINE Paclobutrazol brofenvalerate Econazole
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4-Chlorobenzyl chloride Suppliers

Americas 1 Belgium 3 Canada 3 China 310 Europe 5 France 1 Germany 7 India 37 Italy 1 Japan 8 Slovakia 1 South Korea 3 Switzerland 3 The Netherlands 2 Ukraine 3 United Kingdom 13 United States 47 Global 448
Zibo Liantan Chemical Co., Ltd
Tel
0533-0533-13695336297 13695336297
Email
277051887@qq.com
Country
China
ProdList
12
Advantage
58
CANGZHOU RUNLIQING CHEMICAL CO.,LTD
Tel
199-6973-4477 19933774222
Email
rlqwyx@163.com
Country
China
ProdList
17
Advantage
58
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006356688 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
Dr. J. Pharmachem (India)
Tel
+91 20 24332987
Fax
+91 20 24332137
Email
info@jpharmachem.com
Country
India
ProdList
97
Advantage
55
Danyang Wanlong Chemical Co., Ltd
Tel
86-511-8681 0993
Fax
0511-86810666
Email
jeff@wanlongchem.com
Country
China
ProdList
63
Advantage
55
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44802
Advantage
61
Shijiazhuang Sdyano Fine Chemical Co., Ltd.
Tel
0311-89250318 031166536426
Fax
4000311741
Email
master@sjzsdyn.com
Country
China
ProdList
2826
Advantage
65
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Country
China
ProdList
18207
Advantage
66
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View Lastest Price from 4-Chlorobenzyl chloride manufacturers

Hebei Chuanghai Biotechnology Co., Ltd
Product
4-Chlorobenzyl chloride 104-83-6
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-26
Speranza Chemical Co., Ltd.
Product
4-Chlorobenzyl Chloride 104-83-6
Price
US $20.00/KG
Min. Order
1KG
Purity
98%+
Supply Ability
300MT/year
Release date
2019-12-24
Hebei Chuanghai Biotechnology Co,.LTD
Product
4-Chlorobenzyl chloride 104-83-6
Price
US $9.00/KG
Min. Order
1KG
Purity
99.9
Supply Ability
1 ton
Release date
2024-08-22

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