3,5-DIBROMOBENZYL ALCOHOL
- Product Name
- 3,5-DIBROMOBENZYL ALCOHOL
- CAS No.
- 145691-59-4
- Chemical Name
- 3,5-DIBROMOBENZYL ALCOHOL
- Synonyms
- RARECHEM AL BD 0770;3,5-DIBROMOBENZYL ALCOHOL;3,5-Dibromobenzenemethanol;(3,5-DibroMophenyl)Methanol;Benzenemethanol, 3,5-dibromo-;1,3-Dibromo-5-hydroxymethylbenzene
- CBNumber
- CB3422562
- Molecular Formula
- C7H6Br2O
- Formula Weight
- 265.93
- MOL File
- 145691-59-4.mol
3,5-DIBROMOBENZYL ALCOHOL Property
- Melting point:
- 107-108°C
- Boiling point:
- 328℃
- Density
- 1.960
- Flash point:
- 152℃
- storage temp.
- Sealed in dry,Room Temperature
- pka
- 13.98±0.10(Predicted)
- Appearance
- Light brown to brown Solid
- Water Solubility
- Slightly soluble in water.
- InChI
- InChI=1S/C7H6Br2O/c8-6-1-5(4-10)2-7(9)3-6/h1-3,10H,4H2
- InChIKey
- ZQNSHKZQTZSNTB-UHFFFAOYSA-N
- SMILES
- C1(CO)=CC(Br)=CC(Br)=C1
- CAS DataBase Reference
- 145691-59-4(CAS DataBase Reference)
Safety
- Hazard Codes
- C
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36/37/39
- HS Code
- 2906290090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- D422855
- Product name
- 3,5-DibromobenzylAlcohol
- Packaging
- 50mg
- Price
- $60
- Updated
- 2021/12/16
- Product number
- HCH0020855
- Product name
- 3,5-DIBROMO BENZYL ALCOHOL
- Purity
- 95.00%
- Packaging
- 10G
- Price
- $1236.07
- Updated
- 2021/12/16
- Product number
- FD64456
- Product name
- 3,5-Dibromobenzyl alcohol
- Packaging
- 1g
- Price
- $70
- Updated
- 2021/12/16
- Product number
- X8143
- Product name
- 3,5-Dibromobenzylalcohol
- Packaging
- 1g
- Price
- $75
- Updated
- 2021/12/16
- Product number
- FD64456
- Product name
- 3,5-Dibromobenzyl alcohol
- Packaging
- 2g
- Price
- $100
- Updated
- 2021/12/16
3,5-DIBROMOBENZYL ALCOHOL Chemical Properties,Usage,Production
Uses
It is used in the synthesis of substituted benzylamines.
Synthesis
618-58-6
145691-59-4
Step 1: To a stirred solution of 3,5-dibromobenzoic acid (2 g, 7.168 mmol) in tetrahydrofuran (20 mL) was slowly added borane dimethyl sulfide (3.4 mL, 35.842 mmol, 5 eq.) at 0 °C. The reaction mixture was stirred at room temperature overnight. Upon completion of the reaction, the mixture was cooled to 0 °C and the reaction was carefully quenched with methanol (appropriate amount). Subsequently, the reaction mixture was concentrated under reduced pressure to afford (3,5-dibromophenyl)methanol as an off-white solid (1.8 g, 94% yield). The product was characterized by 1H NMR (400 MHz, DMSO-d6): δ 4.47 (d, J = 6Hz, 2H), 5.39 (t, J = 6Hz, 1H), 7.49 (s, 2H), 7.65 (s, 1H).
References
[1] Patent: WO2017/46739, 2017, A1. Location in patent: Page/Page column 60
[2] Patent: JP2005/120047, 2005, A. Location in patent: Page/Page column 165
[3] Synlett, 2002, # 2, p. 251 - 254
[4] European Journal of Medicinal Chemistry, 2011, vol. 46, # 9, p. 4227 - 4237
3,5-DIBROMOBENZYL ALCOHOL Preparation Products And Raw materials
Raw materials
Preparation Products
3,5-DIBROMOBENZYL ALCOHOL Suppliers
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- Germany
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View Lastest Price from 3,5-DIBROMOBENZYL ALCOHOL manufacturers
- Product
- 3,5-DIBROMOBENZYL ALCOHOL 145691-59-4
- Price
- US $1.00/KG
- Min. Order
- 1g
- Purity
- 95-99%
- Supply Ability
- 1MT/month
- Release date
- 2019-07-31