ChemicalBook > CAS DataBase List > 4-Bromobenzonitrile
4-Bromobenzonitrile
- Product Name
- 4-Bromobenzonitrile
- CAS No.
- 623-00-7
- Chemical Name
- 4-Bromobenzonitrile
- Synonyms
- P-BROMOBENZONITRILE;4-cyanobromobenzene;1-Bromo-4-cyanobenzene;4-bromobenzoic acid nitrile;PBBN;Of broMoxynil;4-Brombenzonitril;4-bromo-benzonitril;p-Cyanobromobenzene;BROMOBENZONITRILE-4
- CBNumber
- CB3423145
- Molecular Formula
- C7H4BrN
- Formula Weight
- 182.02
- MOL File
- 623-00-7.mol
More
Less
4-Bromobenzonitrile Property
- Melting point:
- 110-115 °C(lit.)
- Boiling point:
- 235-237 °C(lit.)
- Density
- 1,562 g/cm3
- refractive index
- 1.5999 (estimate)
- Flash point:
- 130°C
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- 0.2g/l
- form
- Powder or Flakes
- color
- White to light yellow or flakes
- Water Solubility
- Very slightly soluble in water(0.2g/L). Soluble in alcohol and ether.
- BRN
- 2041518
- InChIKey
- HQSCPPCMBMFJJN-UHFFFAOYSA-N
- LogP
- 2.3 at 22.5℃ and pH7
- CAS DataBase Reference
- 623-00-7(CAS DataBase Reference)
- NIST Chemistry Reference
- 4-Bromobenzoic acid nitrile(623-00-7)
More
Less
Safety
- Hazard Codes
- Xn,T,Xi
- Risk Statements
- 22-36/37/38-20/21/22
- Safety Statements
- 61-36/37/39-26-24/25
- RIDADR
- UN 3439 6.1/PG 3
- WGK Germany
- 2
- RTECS
- DI2460000
- Hazard Note
- Toxic/Irritant
- HazardClass
- 6.1
- PackingGroup
- III
- HS Code
- 29269095
More
Less
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H319Causes serious eye irritation
H412Harmful to aquatic life with long lasting effects
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
More
Less
N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- B58407
- Product name
- 4-Bromobenzonitrile
- Purity
- 99%
- Packaging
- 10g
- Price
- $53.8
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- B58407
- Product name
- 4-Bromobenzonitrile
- Purity
- 99%
- Packaging
- 50g
- Price
- $168
- Updated
- 2024/03/01
TCI Chemical
- Product number
- B1426
- Product name
- 4-Bromobenzonitrile
- Purity
- >97.0%(GC)
- Packaging
- 25g
- Price
- $49
- Updated
- 2024/03/01
TCI Chemical
- Product number
- B1426
- Product name
- 4-Bromobenzonitrile
- Purity
- >97.0%(GC)
- Packaging
- 250g
- Price
- $488
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- A10914
- Product name
- 4-Bromobenzonitrile, 98+%
- Packaging
- 10g
- Price
- $44.65
- Updated
- 2024/03/01
More
Less
4-Bromobenzonitrile Chemical Properties,Usage,Production
Chemical Properties
4-Bromobenzonitrile is white to light yellow powder or flakes
Uses
4- Bromobenzonitrile is classified as organic nitriles, which are commonly use solvents and are reacted further for various applications such as manufacture of polymers and intermediates for pharmaceu ticals and other organic chemicals,
Uses
4-Bromobenzonitrile is used as reagents and solvents. Reaction of 2-propanol, 4-bromobenzonitrile, and NaH in the presence of 1.5 mol % Pd2(dba)3 and 3 mol % (S)-(-)2,2?-bis(di-p-tolylphosphino)- 1,1?-binaphthyl at 50°C afforded 4-isopropoxy- benzonitrile in 80% isolated yield. The synthesis of 4-cyanobiphenyl at room temperature in a flow injection microreactor, using a supported catalyst, without the addition of a base gave a product yield of 67±7% (n=6). This was achieved by injecting 4-bromobenzonitrile. The 3-arylation of 2,5-dimethylthiophene with 4-bromopropiophenone, 4-trifluoromethylbromobenzene or 4-bromobenzonitrile gave 3-5 in only 38-50% yields in Palladium-catalysed direct 3-or 4-arylation of thiophene derivatives using aryl bromides.
Synthesis Reference(s)
Tetrahedron Letters, 27, p. 1925, 1986 DOI: 10.1016/S0040-4039(00)84413-5
Synthesis
To a 10 mL glass tube aryl halide (1 mmol), K4FeCN6 (0.6 mmol,220 mg), K2CO3 (1.5 mmol, 207 mg), catalyst (10 mg), and 2 mL DMF were added and the mixture was stirred for appropriate reaction time at 120 ℃ under argon atmosphere. The progress of the reaction was monitored by GC analysis. After completion of the reaction, the reaction mixture was washed with 5 mL water, and the crude product was isolated using dichloromethane (5× 1 mL). Organic extracts were combined, evaporated, and purified by flash chromatography using hexane/EtOAc to give 4-Bromobenzonitrile.
4-Bromobenzonitrile Preparation Products And Raw materials
Raw materials
Preparation Products
More
Less
4-Bromobenzonitrile Suppliers
- Tel
- 15827391819
- 283479231@qq.com
- Country
- China
- ProdList
- 10
- Advantage
- 58
- Tel
- 13349903920 13349903920
- 1540154086@qq.com
- Country
- China
- ProdList
- 2995
- Advantage
- 58
- Tel
- 15225201380 18336995067
- 3656693041@qq.com
- Country
- China
- ProdList
- 1822
- Advantage
- 58
- Tel
- 18353358123 18353358123
- 839877395@qq.com
- Country
- China
- ProdList
- 180
- Advantage
- 58
- Tel
- 86-13349903920; 13349903920
- Fax
- -
- 869523959@qq.com
- Country
- China
- ProdList
- 9693
- Advantage
- 58
- Tel
- 021-50182298 021-50180596
- Fax
- +86-21-57758967
- sales@boylechem.com
- Country
- China
- ProdList
- 2208
- Advantage
- 55
- Tel
- 010-82848833 400-666-7788
- Fax
- 86-10-82849933
- jkinfo@jkchemical.com
- Country
- China
- ProdList
- 94657
- Advantage
- 76
- Tel
- 021-61259108 18621169109
- Fax
- 86-21-61259102
- market03@meryer.com
- Country
- China
- ProdList
- 40228
- Advantage
- 62
- Tel
- 400-6106006
- Fax
- 021-67582001/03/05
- saleschina@alfa-asia.com
- Country
- China
- ProdList
- 30123
- Advantage
- 84
- Tel
- 021-67121386
- Fax
- 021-67121385
- Sales-CN@TCIchemicals.com
- Country
- China
- ProdList
- 24529
- Advantage
- 81
- Tel
- 400-021-7337 2355568890
- Fax
- 0086-21-50182339
- sales@demochem.com
- Country
- China
- ProdList
- 2572
- Advantage
- 57
- Tel
- 021-021-58432009 400-005-6266
- Fax
- 021-58436166
- sales8178@energy-chemical.com
- Country
- China
- ProdList
- 44688
- Advantage
- 61
- Tel
- 0311-89250318 031166536426
- Fax
- 4000311741
- master@sjzsdyn.com
- Country
- China
- ProdList
- 2963
- Advantage
- 65
- Tel
- 86-027-67849912
- Fax
- 86-027-87531808
- sales@chemwish.com
- Country
- China
- ProdList
- 35896
- Advantage
- 56
- Tel
- +86 (0) 571 85 58 67 18
- Fax
- 0086-571-85864795
- sales@capotchem.com
- Country
- China
- ProdList
- 18207
- Advantage
- 66
- Tel
- 010-82967028 13552068683
- Fax
- +86-10-82967029
- 2355560935@qq.com
- Country
- China
- ProdList
- 12390
- Advantage
- 60
- Tel
- 13817811078
- Fax
- 86-021-50426522,50426273
- sales@jingyan-chemical.com
- Country
- China
- ProdList
- 9976
- Advantage
- 60
- Tel
- +86-21-54098501
- Fax
- +86-21-54096319
- sales@sinch.com.cn
- Country
- China
- ProdList
- 11598
- Advantage
- 64
- Tel
- 0573-85285100 18627885956
- Fax
- 0573-85285100
- isenchem@163.com
- Country
- China
- ProdList
- 9513
- Advantage
- 66
- Tel
- 021-50795510 4000665055
- Fax
- 021-50795055
- sales@accelachem.com
- Country
- China
- ProdList
- 11655
- Advantage
- 64
- Tel
- 025-83697070
- Fax
- +86-25-83453306
- info@chemlin.com.cn
- Country
- China
- ProdList
- 19179
- Advantage
- 64
- Tel
- 021-54306202 13764082696
- info@hanhongsci.com
- Country
- China
- ProdList
- 42958
- Advantage
- 64
- Tel
- 021-50135380
- shchemsky@sina.com
- Country
- China
- ProdList
- 32321
- Advantage
- 50
- Tel
- +86 (21) 6435-5022
- Country
- China
- ProdList
- 4267
- Advantage
- 65
- Tel
- Fax
- E-Mail Inquiry
- info@syntechem.com
- Country
- China
- ProdList
- 12984
- Advantage
- 57
- Tel
- 400-1166-196 18981987031
- Fax
- 028-84555506 800101999
- cdhxsj@163.com
- Country
- China
- ProdList
- 11707
- Advantage
- 57
- Tel
- 0086-21-58956006
- Fax
- 0086-21-58956100
- Country
- China
- ProdList
- 7811
- Advantage
- 57
- Tel
- 400 638 7771
- sales@heowns.com
- Country
- China
- ProdList
- 14435
- Advantage
- 57
- Tel
- 86-21-63210123
- Fax
- 86-21-63290778 86-21-63218885
- sj_scrc@sinopharm.com
- Country
- China
- ProdList
- 9815
- Advantage
- 79
- Tel
- 021-51613915-820 13611835272
- Fax
- 021 51613951
- mmwang@sunwaypharm.cn
- Country
- China
- ProdList
- 9734
- Advantage
- 57
- Tel
- Please Send Email 18652950785
- Fax
- 025-87193546
- chemweiao@163.com
- Country
- China
- ProdList
- 4378
- Advantage
- 65
- Tel
- 0086-755-86198205
- acinfo@aemonchem.com
- Country
- China
- ProdList
- 1931
- Advantage
- 57
- Tel
- +86 (573) 82222445 (0)18006601000 452520369
- Fax
- +86 (573) 82222643
- sales@maya-r.com
- Country
- China
- ProdList
- 11707
- Advantage
- 57
- Tel
- 0571-82693216
- Fax
- +86-571-82880190
- info@yuhaochemical.com
- Country
- China
- ProdList
- 9387
- Advantage
- 52
- Tel
- 0370-2785118 17550508557
- Fax
- QQ：3470079902
- 675141927@qq.com
- Country
- China
- ProdList
- 3203
- Advantage
- 55
- Tel
- 027-8866 0053/88660577/88660578
- Fax
- 027-8899 1911
- Country
- China
- ProdList
- 1073
- Advantage
- 55
- Tel
- 0535-0535-6300169 15253505805
- Fax
- (535) 6300169
- yangli@ytderun.com
- Country
- China
- ProdList
- 107
- Advantage
- 60
- Tel
- 86-21-34053660
- Fax
- 86-21-34053661
- sale@labgogo.com
- Country
- China
- ProdList
- 9865
- Advantage
- 52
- Tel
- 800-810-5118
- Fax
- +86-10-84193589
- cnchemical@thermofisher.com
- Country
- China
- ProdList
- 17770
- Advantage
- 75
- Tel
- 400-810-7969 010-59572699
- Fax
- 010-59572688
- ningzi.li@inno-chem.com.cn
- Country
- China
- ProdList
- 6134
- Advantage
- 55
- Tel
- +86-21-60341587
- Fax
- +86-21-61294319
- sales@topbiochem.com
- Country
- China
- ProdList
- 6175
- Advantage
- 58
- Tel
- 21-50456736 18602143071
- Fax
- 021-50761379
- chen@riyngroup.com
- Country
- China
- ProdList
- 1052
- Advantage
- 30
- Tel
- 025-66099280 17798518460
- Fax
- (1)02557626880
- cfzhang@aikonchem.com
- Country
- China
- ProdList
- 19915
- Advantage
- 55
- Tel
- 18017383231 18017383231
- Fax
- qq：2817624287
- lyh_antaeus@163.com
- Country
- China
- ProdList
- 9347
- Advantage
- 55
- Tel
- 4009209199
- Fax
- 86-021-52271987
- sales@9dingchem.com
- Country
- China
- ProdList
- 18209
- Advantage
- 56
- Tel
- 021-61552785
- Fax
- 021-55660885
- sales@shshiji.com
- Country
- China
- ProdList
- 9545
- Advantage
- 55
- Tel
- 86-0755-86635001
- Fax
- 86-0755-22642228
- cantotech@126.com
- Country
- China
- ProdList
- 4566
- Advantage
- 55
- Tel
- 021-62960152
- Fax
- 021-52212593
- 934678158@qq.com
- Country
- China
- ProdList
- 9899
- Advantage
- 55
- Tel
- +86 0510-85629785
- Fax
- +86 0510-85625359
- Country
- China
- ProdList
- 2327
- Advantage
- 58
- Tel
- 0570-3066667
- Fax
- 0570-3063388
- Country
- China
- ProdList
- 3930
- Advantage
- 58
More
Less
View Lastest Price from 4-Bromobenzonitrile manufacturers
Hebei Weibang Biotechnology Co., Ltd
- Product
- 4-Bromobenzonitrile 623-00-7
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100 mt
- Release date
- 2024-11-13
Hebei Chuanghai Biotechnology Co,.LTD
- Product
- 4-Bromobenzonitrile 623-00-7
- Price
- US $9.00/KG
- Min. Order
- 1KG
- Purity
- 99.9
- Supply Ability
- 1 ton
- Release date
- 2024-08-15
Hebei Fengqiang Trading Co., LTD
- Product
- 4-Bromobenzonitrile 623-00-7
- Price
- US $100.00/bag
- Min. Order
- 1bag
- Purity
- 99
- Supply Ability
- 5000
- Release date
- 2023-08-30
623-00-7, 4-BromobenzonitrileRelated Search:
4-Bromophenylacetonitrile
4-Bromophenylacetic acid
4-Bromobenzoic acid
4-Bromo-alpha-phenethylamine
4-Bromostyrene
(4-bromophenyl)(indolin-7-yl)methanone
Bromfenac Impurity 34
Bromfenac Impurity 48
7-(4-BroMobenzoyl)-
bromfenac sodiumImpurity e
Bromfenac Impurity 43
bromfenac sodiumImpurity 2
Bromfenac Impurity 8
Bromfenac Impurity 35
Methanone, (4-broMophenyl)(3-chloro-1H-indol-7-yl)-
Bromfenac Impurity 51
Bromfenac Impurity 57
Bromfenac-d4 Sodium Salt