ChemicalBook > CAS DataBase List > 4-Bromobenzonitrile
4-Bromobenzonitrile
- Product Name
- 4-Bromobenzonitrile
- CAS No.
- 623-00-7
- Chemical Name
- 4-Bromobenzonitrile
- Synonyms
- P-BROMOBENZONITRILE;4-cyanobromobenzene;1-Bromo-4-cyanobenzene;4-bromobenzoic acid nitrile;PBBN;Of broMoxynil;4-Brombenzonitril;4-bromo-benzonitril;p-Cyanobromobenzene;BROMOBENZONITRILE-4
- CBNumber
- CB3423145
- Molecular Formula
- C7H4BrN
- Formula Weight
- 182.02
- MOL File
- 623-00-7.mol
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4-Bromobenzonitrile Property
- Melting point:
- 110-115 °C(lit.)
- Boiling point:
- 235-237 °C(lit.)
- Density
- 1,562 g/cm3
- refractive index
- 1.5999 (estimate)
- Flash point:
- 130°C
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- 0.2g/l
- form
- Powder or Flakes
- color
- White to light yellow or flakes
- Water Solubility
- Very slightly soluble in water(0.2g/L). Soluble in alcohol and ether.
- BRN
- 2041518
- InChIKey
- HQSCPPCMBMFJJN-UHFFFAOYSA-N
- LogP
- 2.3 at 22.5℃ and pH7
- CAS DataBase Reference
- 623-00-7(CAS DataBase Reference)
- NIST Chemistry Reference
- 4-Bromobenzoic acid nitrile(623-00-7)
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Safety
- Hazard Codes
- Xn,T,Xi
- Risk Statements
- 22-36/37/38-20/21/22
- Safety Statements
- 61-36/37/39-26-24/25
- RIDADR
- UN 3439 6.1/PG 3
- WGK Germany
- 2
- RTECS
- DI2460000
- Hazard Note
- Toxic/Irritant
- HazardClass
- 6.1
- PackingGroup
- III
- HS Code
- 29269095
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H319Causes serious eye irritation
H412Harmful to aquatic life with long lasting effects
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- B58407
- Product name
- 4-Bromobenzonitrile
- Purity
- 99%
- Packaging
- 10g
- Price
- $53.8
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- B58407
- Product name
- 4-Bromobenzonitrile
- Purity
- 99%
- Packaging
- 50g
- Price
- $168
- Updated
- 2024/03/01
TCI Chemical
- Product number
- B1426
- Product name
- 4-Bromobenzonitrile
- Purity
- >97.0%(GC)
- Packaging
- 25g
- Price
- $49
- Updated
- 2024/03/01
TCI Chemical
- Product number
- B1426
- Product name
- 4-Bromobenzonitrile
- Purity
- >97.0%(GC)
- Packaging
- 250g
- Price
- $488
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- A10914
- Product name
- 4-Bromobenzonitrile, 98+%
- Packaging
- 10g
- Price
- $44.65
- Updated
- 2024/03/01
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4-Bromobenzonitrile Chemical Properties,Usage,Production
Chemical Properties
4-Bromobenzonitrile is white to light yellow powder or flakes
Uses
4- Bromobenzonitrile is classified as organic nitriles, which are commonly use solvents and are reacted further for various applications such as manufacture of polymers and intermediates for pharmaceu ticals and other organic chemicals,
Uses
4-Bromobenzonitrile is used as reagents and solvents. Reaction of 2-propanol, 4-bromobenzonitrile, and NaH in the presence of 1.5 mol % Pd2(dba)3 and 3 mol % (S)-(-)2,2?-bis(di-p-tolylphosphino)- 1,1?-binaphthyl at 50°C afforded 4-isopropoxy- benzonitrile in 80% isolated yield. The synthesis of 4-cyanobiphenyl at room temperature in a flow injection microreactor, using a supported catalyst, without the addition of a base gave a product yield of 67±7% (n=6). This was achieved by injecting 4-bromobenzonitrile. The 3-arylation of 2,5-dimethylthiophene with 4-bromopropiophenone, 4-trifluoromethylbromobenzene or 4-bromobenzonitrile gave 3-5 in only 38-50% yields in Palladium-catalysed direct 3-or 4-arylation of thiophene derivatives using aryl bromides.
Synthesis Reference(s)
Tetrahedron Letters, 27, p. 1925, 1986 DOI: 10.1016/S0040-4039(00)84413-5
Synthesis
To a 10 mL glass tube aryl halide (1 mmol), K4FeCN6 (0.6 mmol,220 mg), K2CO3 (1.5 mmol, 207 mg), catalyst (10 mg), and 2 mL DMF were added and the mixture was stirred for appropriate reaction time at 120 ℃ under argon atmosphere. The progress of the reaction was monitored by GC analysis. After completion of the reaction, the reaction mixture was washed with 5 mL water, and the crude product was isolated using dichloromethane (5× 1 mL). Organic extracts were combined, evaporated, and purified by flash chromatography using hexane/EtOAc to give 4-Bromobenzonitrile.
4-Bromobenzonitrile Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 4-Bromobenzonitrile manufacturers
Hebei Fengqiang Trading Co., LTD
- Product
- 4-Bromobenzonitrile 623-00-7
- Price
- US $100.00/bag
- Min. Order
- 1bag
- Purity
- 99
- Supply Ability
- 5000
- Release date
- 2023-08-30
Hebei Mojin Biotechnology Co., Ltd
- Product
- 4-Bromobenzonitrile 623-00-7
- Price
- US $0.00/ASSAYS
- Min. Order
- 1ASSAYS
- Purity
- 99%
- Supply Ability
- 20ton
- Release date
- 2021-10-08
Hebei Guanlang Biotechnology Co,.LTD
- Product
- 4-Bromobenzonitrile 623-00-7
- Price
- US $9.00/KG
- Min. Order
- 1KG
- Purity
- 99.9
- Supply Ability
- 1 ton
- Release date
- 2023-05-24
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