ChemicalBook > CAS DataBase List > 4-Bromo-2,6-dimethylphenol

4-Bromo-2,6-dimethylphenol

Product Name: 4-Bromo-2,6-dimethylphenol
CAS No.: 2374-05-2
Chemical Name: 4-Bromo-2,6-dimethylphenol
Synonyms: AKOS BBB/373;4-bromo-6-xylenol;4-BROMO-2,6-XYLENOL;BROMO(4-)2,6-XYLENOL;2,6-Xylenol, 4-bromo-;4-Bromo-2,6-xylenol 97%;4-BROMO-2,6-DIMETHYLPHENOL;2,6-Dimethyl-4-bromophenol;Phenol, 4-bromo-2,6-dimethyl-;4-Bromo-2,6-dimethylphenol 99%
CBNumber: CB3471641
Molecular Formula: C8H9BrO
Formula Weight: 201.06
MOL File: 2374-05-2.mol

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4-Bromo-2,6-dimethylphenol Property

Melting point:: 74-78 °C (lit.)
Boiling point:: 195.33°C (rough estimate)
Density: 1.3646 (rough estimate)
refractive index: 1.5650 (estimate)
storage temp.: Inert atmosphere,Room Temperature
form: powder to crystal
pka: 10.10±0.23(Predicted)
color: White to Light yellow to Light orange
Water Solubility: Slightly soluble in water.
BRN: 1862399
InChI: InChI=1S/C8H9BrO/c1-5-3-7(9)4-6(2)8(5)10/h3-4,10H,1-2H3
InChIKey: ZLVFYUORUHNMBO-UHFFFAOYSA-N
SMILES: C1(O)=C(C)C=C(Br)C=C1C
CAS DataBase Reference: 2374-05-2(CAS DataBase Reference)
NIST Chemistry Reference: Phenol, 4-bromo-2,6-dimethyl-(2374-05-2)
EPA Substance Registry System: Phenol, 4-bromo-2,6-dimethyl- (2374-05-2)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-37/39
RIDADR: UN 2811 6.1/PG 3
WGK Germany: 3
RTECS: ZE6780000
TSCA: Yes
HazardClass: IRRITANT
HS Code: 29081990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 196371
Product name: 4-Bromo-2,6-xylenol
Purity: 97%
Packaging: 100g
Price: $94.2
Updated: 2025/07/31

TCI Chemical

Product number: B2060
Product name: 4-Bromo-2,6-dimethylphenol
Purity: >98.0%(GC)
Packaging: 25g
Price: $170
Updated: 2025/07/31

TCI Chemical

Product number: B2060
Product name: 4-Bromo-2,6-dimethylphenol
Purity: >98.0%(GC)
Packaging: 250g
Price: $1270
Updated: 2025/07/31

TRC

Product number: B691678
Product name: 4-Bromo-2,6-dimethylphenol
Packaging: 2.5g
Price: $65
Updated: 2021/12/16

TRC

Product number: B691678
Product name: 4-Bromo-2,6-dimethylphenol
Packaging: 1g
Price: $55
Updated: 2021/12/16

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4-Bromo-2,6-dimethylphenol Chemical Properties,Usage,Production

Chemical Properties

LIGHT PINK-BEIGE TO BROWN CRYSTALS OR POWDER

Uses

It is used as a preservatives for coatings, slurries and to control microbial fouling in paper mills , oil field and leather process and water treatment process against microbial attack.

Preparation

4-Bromo-2,6-dimethylphenol is prepared by bromination of 2,6-dimethylphenol in glacial acetic acid at 15 ℃ and used as a microbicide in disinfectants.

General Description

Iodine initiated polymerization of 4-bromo-2,6-xylenol in tetrahydrofuran solution has been investigated. 4-Bromo-2,6-xylenol on bromination in chloroform or carbobn tetrachloride yields 3,4-dibromo-2,6-xylenol and 3,4,5-tribromo-2,6-xylenol.

Synthesis

576-26-1

2374-05-2

In a 10 mL two-neck flask equipped with a reflux condenser, 2,6-dimethylphenol (0.25 mmol) and tetrabutylammonium bromide (161.2 mg, 0.50 mmol) were added. The flask was evacuated and backfilled three times with argon. To the reaction mixture was added ultrapure water (0.5 mL), trifluoroacetic acid (57.5 μL, 0.75 mmol) and 30% hydrogen peroxide (77 μL, 0.75 mmol). The reaction mixture was stirred at 25 °C under argon protection. Upon completion of the reaction, the reaction was quenched with 1:1 saturated aqueous sodium thiosulfate and saturated aqueous sodium bicarbonate and extracted with ether. The organic layers were combined, dried over anhydrous sodium sulfate, filtered and concentrated under reduced pressure. 1,3,5-Trimethoxybenzene or hexamethylbenzene was added as an internal standard and the NMR yield of the product was determined by 1H NMR analysis. The spectral data obtained for 4-bromo-2,6-dimethylphenol were consistent with those of commercially available standards.

Toxicity evaluation

LD50 (i.p., mouse) 650 mg/kg.

References

[1] Bulletin of the Chemical Society of Japan, 1989, vol. 62, # 10, p. 3373 - 3375
[2] Synthetic Communications, 2010, vol. 40, # 21, p. 3226 - 3232
[3] Organic Letters, 2006, vol. 8, # 19, p. 4291 - 4293
[4] Chinese Chemical Letters, 2012, vol. 23, # 4, p. 387 - 390
[5] Organic Letters, 2015, vol. 17, # 12, p. 2886 - 2889

4-Bromo-2,6-dimethylphenol Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 4-Bromo-2,6-dimethylphenol manufacturers

Career Henan Chemical Co

Product: 4-Bromo-2,6-dimethylphenol 2374-05-2
Price: US $1.00/KG
Min. Order: 1KG
Purity: 95-99%
Supply Ability: 100kg/week
Release date: 2019-08-05

2374-05-2, 4-Bromo-2,6-dimethylphenolRelated Search:

Xylenol 2,4-Dimethyl aniline 2,6-Lutidine 2,6-Dimethylphenol 3,4-Dimethylaniline 3-Bromophenol 4-Bromophenol 2-Bromophenol 4-Bromo-2,6-di-tert-butylphenol XYLENOL ORANGE 6-BROMO-8-(CHLOROMETHYL)-4H-1,3-BENZODIOXINE 5-BROMO-2,3-DIHYDROBENZOFURAN-7-CARBOXYLIC ACID 4-BROMO-2,6-DIMETHYLANISOLE Bromine 2,6-DIBROMO-4-CHLORO-3,5-DIMETHYLPHENOL 4-Bromo-2,5-dimethylphenol 4-BROMO-3,5-DIMETHYLPHENOL,4-bromo-3,5-dimethylphenol 4-Bromo-3,5-xylenol ,4-Bromo-3,5-dimethylphenol 99% 4,4'-(3H-2,1-benzoxathiol-3-ylidene)bis[3-bromo-2,5-dimethylphenol] S,S-dioxide

BROMO(4-)2,6-XYLENOL

4-BROMO-2,6-XYLENOL

4-BROMO-2,6-DIMETHYLPHENOL

AKOS BBB/373

4-bromo-6-xylenol

4-BROMO-2,6-DIMETHYLPHENOL, 99.5+%

4-Brom-2,6-dimethylphenol, 99%

4-Bromo-2,6-dimethylphenol 99%

4-BROMO-2,6-DIMETHYLPHENOL / 4-BROMO-2,6-XYLENOL

4-Bromo-2,6-dimethylphenol, GC 99%

2,6-Dimethyl-4-bromophenol

4-Bromo-2,6-dimethylphenol 95+%

4-Bromo-2,6-dimethylphenol,99%

5-Bromo-2-hydroxy-m-xylene, 4-Bromo-2,6-xylenol

4-Bromo-2,6-xylenol 97%

2,6-Xylenol, 4-bromo-

Phenol, 4-bromo-2,6-dimethyl-

2374-05-2

2374-5-2

5/2/2374

173248

173-24-8

2374-05-02

2374-65-2

C8H9OBr

BrC6H2CH32OH

ARYL HALIDE

Building Blocks

Phenols

Oxygen Compounds

Organic Building Blocks

Bromine Compounds

Phenols

Aromatic Phenols

Benzene series

Phenol&Thiophenol&Mercaptan