ChemicalBook > CAS DataBase List > Borane-2-picoline complex

Borane-2-picoline complex

Product Name
Borane-2-picoline complex
CAS No.
3999-38-0
Chemical Name
Borane-2-picoline complex
Synonyms
Pic-BH3;2-picoline borane;2-methylpyridine borane;2-Methylpyridine borane complex;(2-Methylpyridin-1-iuM-1-yl)trihydroborate;Borane-2-picoL;orane-2-picoline coMplex;BORANE - 2-PICOLINE COMPLEX;2- methylpyridine -N- borane;2-Methylpyridine - borane (1:1)
CBNumber
CB3500718
Molecular Formula
C6H10BN
Formula Weight
106.96
MOL File
3999-38-0.mol
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Borane-2-picoline complex Property

Melting point:
48 °C
Density 
1.297 g/mL at 25 °C
Flash point:
100°(212°F)
storage temp. 
2-8°C
solubility 
Dichloromethane (Sparingly), Ethyl Acetate (Slightly)
form 
Solid
color 
White
Water Solubility 
Slightly sol. in water, cyclohexane, very sol. in methanol, THF, diglyme, and benzene
Sensitive 
Moisture Sensitive
InChIKey
ZMASBEFBIXMNCP-UHFFFAOYSA-N
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Safety

Hazard Codes 
F,Xn,Xi
Risk Statements 
14/15-40-36/37/38-26
Safety Statements 
36/37-43-26-36/37/38-14/15
RIDADR 
UN 3130 6.1(4.3) / PGII
WGK Germany 
3
HazardClass 
4.3
PackingGroup 
II
HS Code 
29333990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H261In contact with water releases flammable gas

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P231+P232Handle under inert gas. Protect from moisture.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
654213
Product name
2-Methylpyridine borane complex solution
Purity
95%
Packaging
5g
Price
$74.9
Updated
2024/03/01
Sigma-Aldrich
Product number
771759
Product name
2-Methylpyridine borane complex solution
Purity
0.5 M in dichloromethane
Packaging
10ml
Price
$45.2
Updated
2023/06/20
TCI Chemical
Product number
B3018
Product name
Borane - 2-Methylpyridine Complex
Purity
>85.0%(T)
Packaging
5g
Price
$69
Updated
2024/03/01
TCI Chemical
Product number
B3018
Product name
Borane - 2-Methylpyridine Complex
Purity
>85.0%(T)
Packaging
25g
Price
$207
Updated
2024/03/01
Alfa Aesar
Product number
H66642
Product name
Borane-2-methylpyridine complex, 95%
Packaging
5g
Price
$70.5
Updated
2024/03/01
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Borane-2-picoline complex Chemical Properties,Usage,Production

Uses

Environmentally benign reducing agent. Reactant for: Reductive amination. N-Benzyl-protection of amino acid derivatives by reductive alkylation. Reductive alkoxyamination.

Uses

Used as reactant for N-Benzyl-protection of amino acid derivatives by reductive alkylation, reductive alkoxyamination, as reducing agent for the labeling of oligosaccharides by reductive amination, synthesis of alkoxyamine derivatives, via reduction of oxime ethers, reductive amination reactions of C1-C10 aldehyde 2,4-dinitrophenylhydrazones, synthesis of various trifluoromethylated amino compounds and an alternative reagent for reductive aminations.

General Description

2-Methylpyridine borane complex is a nontoxic alternate to the reducing agent sodium cyanoborohydride.

Borane-2-picoline complex Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Borane-2-picoline complex manufacturers

Hebei Yanxi Chemical Co., Ltd.
Product
Borane - 2-Methylpyridine Complex 3999-38-0
Price
US $40.00-40.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
10 tons
Release date
2023-09-20
Hebei Guanlang Biotechnology Co., Ltd.
Product
Borane-2-picoline complex 3999-38-0
Price
US $0.00-0.00/KG
Min. Order
50KG
Purity
99%
Supply Ability
500000kg
Release date
2022-09-30
Hebei Guanlang Biotechnology Co,.LTD
Product
Borane-2-picoline complex 3999-38-0
Price
US $1.90/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 ton
Release date
2021-07-28

3999-38-0, Borane-2-picoline complexRelated Search:

Methoxydiethylborane Borane-tetrahydrofuran complex 2,4,6-Collidine 2-Chloro-5-chloromethylpyridine 2,6-Lutidine 4-Methylpyridine INTERMEDIATES Azamethiphos 2-Picoline Boron nitride Boron Dimethylaminoborane Borane tert-butylamine complex 1-FLUORO-2,4,6-TRIMETHYLPYRIDINIUM TETRAFLUOROBORATE 1,2,4,6-Tetraphenylpyridinium tetrafluoroborate N-BENZYL-2,4,6-TRIPHENYL PYRIDINIUM TETRAFLUOROBORATE Borane-2-picoline complex 2,6-DIETHYL-4-PHENYL-1-[3-(TRIFLUOROMETHYL)BENZYL]PYRIDINIUM TETRAFLUOROBORATE

  • 2-Methylpyridine borane complex
  • 2-Methylpyridine - borane (1:1)
  • Borane - 2-Picoline Complex 2-Picoline Borane 2-Methylpyridine Borane
  • orane-2-picoline coMplex
  • BORANE - 2-PICOLINE COMPLEX
  • 2-methylpyridine borane
  • 2-picoline borane
  • borane - 2-methylpyridine complex
  • Trihydro(2-methylpyridine)-boron
  • (2-Methylpyridin-1-iuM-1-yl)trihydroborate
  • Boron,trihydro(2-Methylpyridine)-, (T-4)-
  • 2-Methylpyridine borane coMplex solution 95%
  • 2-Methylpyridine borane complex solution
  • Borane-2-picoL
  • Borane - 2-Methylpyridine Complex &gt
  • Borane-2-picoline complex ISO 9001：2015 REACH
  • Factories direct supplier Borane-2-picoline complex CAS 3999-38-0
  • Pic-BH3
  • Borane-2-methylpyridine complex, 95%,
  • 2- methylpyridine -N- borane
  • Borane - 2-Methylpyridine Complex, ≥ 85.0%
  • 3999-38-0
  • C6H10BN
  • B (Classes of Boron Compounds)
  • Boranes
  • Reduction
  • Synthetic Organic Chemistry
  • 3999-38-0