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Diacetone-D-glucose

Product Name
Diacetone-D-glucose
CAS No.
582-52-5
Chemical Name
Diacetone-D-glucose
Synonyms
GLUCOFURANOSE;(3aR,5S,6S,6aR)-5-((R)-2,2-DiMethyl-1,3-dioxolan-4-yl)-2,2-diMethyltetrahydrofuro[2,3-d][1,3]dioxol-6-ol;DIACETONEGLUCOSE;1,2:5,6-DI-O-ISOPROPYLIDENE-A-D-GLUCOFURANOSE;1,2:5,6-DIISOPROPYLENE-ALPHA-D-GLUCOFURANOSE;1,2:5,6-Di-O-isopropylidene-α-D-glucofuranose;1,2:5,6-DI-O-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSE;1,2:5,6-O-DI-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSIDE;ucose;NSC 1223
CBNumber
CB3673320
Molecular Formula
C12H20O6
Formula Weight
260.29
MOL File
582-52-5.mol
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Diacetone-D-glucose Property

Melting point:
110-111 °C(lit.)
alpha 
-11 º (c=5, EtOH)
Boiling point:
323.54°C (rough estimate)
Density 
1.1432 (rough estimate)
refractive index 
-18.5 ° (C=5, H2O)
storage temp. 
Inert atmosphere,Store in freezer, under -20°C
solubility 
Chloroform (Slightly), Methanol (Slightly), Water (Slightly, Sonicated)
pka
13.15±0.60(Predicted)
form 
Powder
color 
White to yellow
optical activity
[α]20/D 18°, c = 1% in H2O
Water Solubility 
slightly soluble
Merck 
14,2965
BRN 
84386
InChIKey
KEJGAYKWRDILTF-YENDLIOYSA-N
EPA Substance Registry System
Diacetone glucose (582-52-5)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
24/25-36/37-26
WGK Germany 
2
RTECS 
LZ4958000
F 
3-10
TSCA 
Yes
HS Code 
29329970
Toxicity
LD50 oral in mouse: 4gm/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
31460
Product name
1,2:5,6-Di-O-isopropylidene-α-D-glucofuranose
Purity
purum,≥98.0%(TLC)
Packaging
25g
Price
$62.6
Updated
2024/03/01
Sigma-Aldrich
Product number
31460
Product name
1,2:5,6-Di-O-isopropylidene-α-D-glucofuranose
Purity
purum,≥98.0%(TLC)
Packaging
100g
Price
$138
Updated
2024/03/01
Sigma-Aldrich
Product number
S83055
Product name
5-(2,2-DIMETHYL-(1,3)DIOXOLAN-4-YL)-2,2-DIMETHYL-4H-FURO(2,3-D)(1,3)DIOXOL-6-OL
Purity
AldrichCPR
Packaging
250MG
Price
$28.6
Updated
2023/06/20
TCI Chemical
Product number
D1949
Product name
1,2:5,6-Di-O-isopropylidene-alpha-D-glucofuranose
Purity
>97.0%(GC)
Packaging
10g
Price
$16
Updated
2024/03/01
TCI Chemical
Product number
D1949
Product name
1,2:5,6-Di-O-isopropylidene-alpha-D-glucofuranose
Purity
>97.0%(GC)
Packaging
25g
Price
$40
Updated
2024/03/01
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Diacetone-D-glucose Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powde

Uses

It is mainly used in biochemical reaction and used as medicine intermediate. It is used in synthesize for below products: L-gulose;1,2:5,6-Di-O-isopropylidene-a-D-gulofuranose; Alllose; ;1,2:5,6-Double-O-Isopropylidene-3-C-(1-Methoxycarbonyl)Ethide-alfa-D-Furanose) ;1,2:5,6-Di-O-isopropylidene-a-D-ribo-hexofuranose-3-ulose;6-deoxy idose.

Uses

1,2:5,6-Di-O-isopropylidene-α-D-glucofuranose is a compound useful in organic synthesis.

Purification Methods

Diacetone-D-glucose crystallises from Et2O, (needles), pet ether or *C6H6 and sublimes in vacuo. It is soluble in 7 volumes of H2O and 200 volumes of pet ether at their boiling points. The solubility in H2O at 17.5o is 4.3%. It precipitates from aqueous solutions on basification with NaOH. [Schmid & Karrer Helv Chim Acta 32 1371 1949, Fischer & Rund Chem Ber 49 90, 93 1916, IR: Kuhn Anal Chem 22 276 1950, Beilstein 19/12 V 318.]

Diacetone-D-glucose Preparation Products And Raw materials

Raw materials

Preparation Products

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Diacetone-D-glucose Suppliers

Americas 1 Austria 1 Belgium 3 Canada 2 China 380 Czech 1 Europe 4 France 1 Germany 11 India 47 Italy 1 Japan 3 Poland 1 Slovakia 1 Sweden 2 Switzerland 8 The Netherlands 1 Ukraine 1 United Kingdom 26 United States 60 Global 555
Toronto Research Chemicals
Tel
--
Fax
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Email
info@trc-canada.com
Country
Canada
ProdList
6038
Advantage
71
Alberta Research Council
Tel
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Fax
--
Country
Canada
ProdList
429
Advantage
30
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View Lastest Price from Diacetone-D-glucose manufacturers

Xinxiang Aurora Biotechnology Co.,Ltd.
Product
Diacetone-D-glucose 582-52-5
Price
US $0.00-0.00/Kg
Min. Order
1Kg
Purity
98%
Supply Ability
20Ton
Release date
2024-11-01
Baoji Guokang Bio-Technology Co., Ltd.
Product
Diacetone-D-glucose 582-52-5
Price
US $95.00/Kg/Bag
Min. Order
1KG
Purity
99%
Supply Ability
100kg
Release date
2021-06-02
Hebei Yanxi Chemical Co., Ltd.
Product
Diacetone-d-Glucose 582-52-5
Price
US $0.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
20tons
Release date
2023-10-10

582-52-5, Diacetone-D-glucoseRelated Search:

Acetylacetone 1,2-O-Isopropylidene-D-glucofuranose D-Glucose monohydrate Calcium pyruvate Pyruvic acid D(+)-Glucose Diacetone acrylamide CORN SYRUP 2,5-Hexanedione Diacetone Alcohol Glucose oxidase 1,2:5,6-Bis-O-(1-methylethylidene)-D-mannitol Propiophenone L-GLUCOSE DIACETONE-D-GLUCOSE Acetone Diacetin Phenylacetone

  • 1,2:5,6-O-DI-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSIDE
  • 1,2:5,6-DIISOPROPYLENE-ALPHA-D-GLUCOFURANOSE
  • 5-(2,2-DIMETHYL-[1,3]DIOXOLAN-4-YL)-2,2-DIMETHYL-TETRAHYDRO-FURO[2,3-D][1,3]DIOXOLE
  • A-D-GLUCOFURANOSE
  • Diacetone-D-glucose, 98+%
  • DIACETONE-D-GLUCOSE
  • DIACETONEGLUCOSE
  • DIACETONE-ALPHA-D-GLUCOSE
  • DIACETONE-ALPHA-D-GLC
  • D-GLUCOSE DIACETONIDE
  • DIISOPROPYLIDENEGLUCOFURANOSE
  • DI-O-ISOPROPYLIDENE-A-D-GLUCOFURANOSE, 1,2,5,6-
  • GLUCOFURANOSE
  • .alpha.-D-Glucofuranose, 1,2:5,6-bis-O-(1-methylethylidene)-
  • 1,2:5,6-di-o-isopropylidene-à-d-glucofuranose
  • 1,2:5,6-Di-O-isopropylidene-a-L-glucofuranose
  • 1,2:5,6-DI-O-ISOPROPYLIDENE-A-D-GLUCOFURANOSE,98%
  • a-D-Glucofuranose, 1,2:5,6-bis-O-(1-methylethylidene)-
  • Diacetone-D-Glucose/1,2:5,6-Di-O-Isopropylidene-Alpha-D-Glucofuranose
  • 1,2:5,6-Di-isopropylidene-glucofuranose
  • 1,2:5,6-DI-O-ISOPROPYLIDENE-ALFA-D-GLUCOFURANOSE
  • 1,2,5,6-DI-O-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSE (DIACETONE-D-GLUCOSE)
  • D-Glucose diacetonide, Diacetone-D-glucose
  • 1,2,5,6-diisopropylidene-D-glucose, D-Glucose diacetonide, Diacetone-D-glucose
  • (3aR,5S,6S,6aR)-5-[(4S)-2,2-Dimethyl-1,3-dioxolan-4-yl]-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[4,5-d][1,3]dioxol-6-ol
  • Di-O-isopropylidene-a-D-glucofuranose
  • Glucose bisacetonide
  • 1,2,5,6-Di-O-isopropylidene-|-L-glucofuranose
  • (3aR,3aα,6aα)-5α-[(4R)-2,2-Dimethyl-1,3-dioxolane-4-yl]-2,2-dimethyltetrahydrofuro[2,3-d]-1,3-dioxole-6α-ol
  • 1-O,2-O:5-O,6-O-Bis(1-methylethylidene)-α-D-glucofuranose
  • 1-O,2-O:5-O,6-O-Bis(isopropylidene)-α-D-glucofuranose
  • 1-O,2-O:5-O,6-O-Diisopropylidene-α-D-glucofuranose
  • Diacetone-D-g
  • ucose
  • 1,2:5,6-Di-O-isopropylidene-alpha-D-glucofuranose, Min. 99%
  • (3aR,5S,6S,6aR)-5-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]-2,2-dimethyl-tetrahydro-2H-furo[2,3-d][1,3]dioxol-6-ol
  • 1,2,5,6-DIISOPROPYLIDENE-D-GLUCOSE
  • 1,2:5,6-DIISOPROPYLIDENE-D-GLUCOSE
  • 1,2;5,6-DI-O-ISOPROPYLIDENE-D-GLUCOFURANOSE
  • 1,2,5,6-DI-O-ISO-PROPYLIDENEGLUCOFURANOSE
  • 1,2:5,6-DI-O-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSIDE
  • 1,2:5,6-DI-O-ISOPROPYLDENE-ALPHA-D-GLUCOFURANOSE
  • 1,2:5,6-DI-O-ISOPROPYLIDENE-A-D-GLUCOFURANOSE
  • (-)-1,2:5,6-DI-O-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSE
  • 1,2,5,6-DI-O-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSE
  • 1,2:5,6-DI-O-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSE
  • 1,2:5,6-bis-o-(1-methylethylidene)-alpha-d-glucofuranos
  • 1:2,5:6-di-o-isopropyliden-alpha-d-glucofuranose
  • 5:6-di-o-isopropylidene-1:alpha-d-glucofuranos
  • Diacetin Glucose
  • 1,2,5,6-Di-O-isopropylidene-alpha-D-glucofuranose (Diacetone-D-g
  • Diacetone-D-Glucos
  • 1,2:5,6-Bis-O-(1-Methylethylidene)-α-D-glucofuranose
  • 1,2:5,6-Di-O-isopropylidene-D-glucose
  • NSC 1223
  • 5,6-Di-O-isopropylidene-alpha-D-glucofuranose
  • (-)-1,2:5,6-DI-O-ISOPROPYLIDENE-A-D-GLUC
  • 1,2:5,6-Bis-O-(1-Methylethylidene)-a-D-Glucofuranose