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Methyltriphenylphosphonium iodide

Product Name
Methyltriphenylphosphonium iodide
CAS No.
2065-66-9
Chemical Name
Methyltriphenylphosphonium iodide
Synonyms
methyltriphenylphosphonium;MPJ;Methyltriphenylphosp;MethyltriphenylphosphoniuM iod;Triphenylmethylphosphine iodide;METHYLTRIPHENYPHOSPHONIUMIODIDE;Methyltriphenylphosphanium iodid;Triphenylmethylphosphinium iodide;METHYLTRIPHENYLPHOSPHONIUM IODIDE;Methyltriphenylphosphanium iodide
CBNumber
CB3673698
Molecular Formula
C19H18IP
Formula Weight
404.22
MOL File
2065-66-9.mol
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Methyltriphenylphosphonium iodide Property

Melting point:
183-185 °C(lit.)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Powder
color 
White to light yellow
Water Solubility 
SOLUBLE
Sensitive 
Light Sensitive & Hygroscopic
InChI
InChI=1S/C19H18P.HI/c1-20(17-11-5-2-6-12-17,18-13-7-3-8-14-18)19-15-9-4-10-16-19;/h2-16H,1H3;1H/q+1;/p-1
InChIKey
JNMIXMFEVJHFNY-UHFFFAOYSA-M
SMILES
[P+](C)(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.[I-]
CAS DataBase Reference
2065-66-9(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi,T
Risk Statements 
36/37/38-25
Safety Statements 
26-36-45-37/39-28A
RIDADR 
UN3464
WGK Germany 
3
HazardClass 
6.1
PackingGroup 
III
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
245054
Product name
Methyltriphenylphosphonium iodide
Purity
97%
Packaging
25g
Price
$86.9
Updated
2024/03/01
TCI Chemical
Product number
M0253
Product name
Methyltriphenylphosphonium Iodide
Purity
>98.0%(T)
Packaging
25g
Price
$48
Updated
2024/03/01
TCI Chemical
Product number
M0253
Product name
Methyltriphenylphosphonium Iodide
Purity
>98.0%(T)
Packaging
100g
Price
$153
Updated
2024/03/01
Alfa Aesar
Product number
A15644
Product name
Methyltriphenylphosphonium iodide, 98%
Packaging
25g
Price
$52.65
Updated
2024/03/01
Alfa Aesar
Product number
A15644
Product name
Methyltriphenylphosphonium iodide, 98%
Packaging
100g
Price
$153.65
Updated
2024/03/01
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Methyltriphenylphosphonium iodide Chemical Properties,Usage,Production

Chemical Properties

WHITE TO LIGHT YELLOW POWDER

Uses

suzuki reaction

Uses

Methyltriphenylphosphonium iodide is as a reactant for synthesis of triphenylamine-based dyes and polyolefinic aromatic molecules with pyrene for use in dye-sensitized solar cells. Used as ligand in coupling reaction. It is also used as a precursor to a Wittig reagent.

Preparation

Methyltriphenylphosphonium iodide was prepared by the following procedure. Triphenylphosphine was recrystallized from ethanol and dried over phosphorus pentoxide under reduced pressure for 12 hr. A solution of 39 g (0.15 mol) of triphenylphosphine and 10.0 mL (22.8 g, 0.16 mol) of iodomethane in 105 mL of benzene was allowed to stir at room temperature for 12 hr. The precipitate was filtered, washed with benzene, and dried over phosphorus pentoxide under reduced pressure for 12 hr. The yield was 57 g (94%), mp 189°C (lit.2 mp 182°C).

Methyltriphenylphosphonium iodide Preparation Products And Raw materials

Raw materials

Preparation Products

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Methyltriphenylphosphonium iodide Suppliers

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View Lastest Price from Methyltriphenylphosphonium iodide manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
Methyltriphenylphosphonium iodide 2065-66-9
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-02-23
Hebei Weibang Biotechnology Co., Ltd
Product
Methyltriphenylphosphonium iodide 2065-66-9
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-10-29
Hebei Chuanghai Biotechnology Co,.LTD
Product
Methyltriphenylphosphonium iodide 2065-66-9
Price
US $9.00/KG
Min. Order
1KG
Purity
99.9
Supply Ability
1 ton
Release date
2024-08-21

2065-66-9, Methyltriphenylphosphonium iodideRelated Search:

Methyl acrylate Iodotrimethylsilane Methylparaben Potassium iodide Trimethylsulfoxonium iodide Propidium iodide Ethyltriphenylphosphonium iodide Trimethylphenylammonium chloride Triphenylphosphine Chlorodimethylphenylsilane Kresoxim-methyl Bensulfuron methyl Methyltriphenylphosphonium bromide Thiophanate-methyl Methyl(triphenyl)phosphonium chloride Methyl trioctyl ammonium chloride potassium methyltrifluoroborate METHYL(TRIPHENYLPHOSPHINE)GOLD (I)

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  • C19H19IP
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  • Wittig Reagents
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  • Synthetic Organic Chemistry
  • Wittig & Horner-Emmons Reaction
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