ChemicalBook > CAS DataBase List > 2-Bromo-4-methoxybenzenol

2-Bromo-4-methoxybenzenol

Product Name
2-Bromo-4-methoxybenzenol
CAS No.
17332-11-5
Chemical Name
2-Bromo-4-methoxybenzenol
Synonyms
2-BROMO-4-METHOXYPHENOL;4-Methoxy-2-bromophenol;3-Bromo-4-hydroxyanisole;2-bromo-4-methoxylphenol;2-BROMO-4-METHOXYBENZENOL;Phenol, 2-bromo-4-methoxy-;2-Bromo-4-methoxyphenol >2-Bromo-4-methoxyphenol ,98%
CBNumber
CB3717617
Molecular Formula
C7H7BrO2
Formula Weight
203.03
MOL File
17332-11-5.mol
More
Less

2-Bromo-4-methoxybenzenol Property

Melting point:
47
Boiling point:
115 °C
Density 
1.585±0.06 g/cm3(Predicted)
storage temp. 
Inert atmosphere,Room Temperature
form 
powder to crystal
pka
8.92±0.18(Predicted)
color 
White to Light yellow to Light orange
CAS DataBase Reference
17332-11-5(CAS DataBase Reference)
More
Less

Safety

Hazard Codes 
Xi
Risk Statements 
20/21/22-36/37/38
Safety Statements 
26-36/37/39
Hazard Note 
Irritant
HS Code 
29071990
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

More
Less

N-Bromosuccinimide Price

TCI Chemical
Product number
B3135
Product name
2-Bromo-4-methoxyphenol
Purity
>98.0%(T)
Packaging
5g
Price
$81
Updated
2025/07/31
TCI Chemical
Product number
B3135
Product name
2-Bromo-4-methoxyphenol
Purity
>98.0%(T)
Packaging
25g
Price
$274
Updated
2025/07/31
TRC
Product number
B696770
Product name
2-Bromo-4-methoxyphenol
Packaging
100mg
Price
$45
Updated
2021/12/16
TRC
Product number
B696770
Product name
2-Bromo-4-methoxyphenol
Packaging
500mg
Price
$65
Updated
2021/12/16
Matrix Scientific
Product number
044943
Product name
2-Bromo-4-methoxyphenol
Purity
97%
Packaging
5g
Price
$60
Updated
2021/12/16
More
Less

2-Bromo-4-methoxybenzenol Chemical Properties,Usage,Production

Chemical Properties

Off-white solid

Synthesis

150-76-5

17332-11-5

General procedure for the synthesis of 2-bromo-4-methoxyphenol from p-hydroxyanisole: 2.6 mL (100 mMol) of bromine dissolved in 10 mL of carbon disulfide was slowly added dropwise to 12.4 g (100 mMol) of 4-methoxyphenol dissolved in 20 mL of carbon disulfide at 0 °C. The reaction temperature was maintained at 30 °C. After 30 min, 1 mL of bromine dissolved in 10 mL of carbon disulfide was added dropwise. The reaction temperature was maintained at 30 °C. After 30 min, 1 mL of the solution of bromine dissolved in 10 mL of carbon disulfide was added dropwise. After completion of the reaction, the mixture was concentrated under reduced pressure. The residue was dissolved in ether and washed sequentially with 100 mL of water and 100 mL of saturated aqueous sodium chloride. The organic phase was dried with magnesium sulfate and concentrated under reduced pressure. The residue was purified by silica gel column chromatography using a gradient elution with hexane containing 0 to 20% ethyl acetate. The fractions containing the target product were combined and concentrated under reduced pressure to give 11.6 g (57% yield) of 2-bromo-4-methoxyphenol as a crystalline solid.1H-NMR (CDCl3): δ 7.0 (d, 1H), 6.95 (d, 1H), 6.8 (dd, 1H), 5.15 (s, 1H), 3.75 (s, 3H).

References

[1] Organic Letters, 2004, vol. 6, # 4, p. 457 - 460
[2] Synthetic Communications, 2007, vol. 37, # 2, p. 323 - 328
[3] Chemistry - A European Journal, 2012, vol. 18, # 11, p. 3286 - 3291
[4] Chemical Communications, 2012, vol. 48, # 52, p. 6577 - 6579
[5] Patent: WO2013/97224, 2013, A1. Location in patent: Page/Page column 72

2-Bromo-4-methoxybenzenol Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

2-Bromo-4-methoxybenzenol Suppliers

Americas 1 China 146 Europe 1 France 1 Germany 1 India 5 Japan 2 United Kingdom 10 United States 27 Global 194
TCI Chemicals (India) Pvt. Ltd.
Tel
--
Fax
--
Email
sales-in@tcichemicals.com
Country
India
ProdList
6768
Advantage
58
Basr Fine Chemicals Private Limited
Tel
--
Fax
--
Country
India
ProdList
632
Advantage
58
Reax Chemicals
Tel
--
Fax
--
Country
India
ProdList
4217
Advantage
58
A.J Chemicals
Tel
--
Fax
--
Email
sales@ajchem.in
Country
India
ProdList
6100
Advantage
58
More
Less

View Lastest Price from 2-Bromo-4-methoxybenzenol manufacturers

Shaanxi Dideu New Materials Co. Ltd
Product
2-BroMo-4-Methoxyphenol 17332-11-5
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98.0%
Supply Ability
10000KGS
Release date
2024-11-19
Career Henan Chemical Co
Product
2-Bromo-4-methoxybenzenol 17332-11-5
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
25kg
Release date
2019-07-12

17332-11-5, 2-Bromo-4-methoxybenzenolRelated Search:

4-Methoxybenzyl cyanide 3-Bromophenol Guaiacol POLY(ETHYLENE GLYCOL) METHYL ETHER ACRYLATE Anisole (Trifluoromethoxy)benzene 2-Bromophenol p-Anisaldehyde 4-Methoxyphenol Bromine 1,4-Dibromo-2,5-dimethoxybenzene 4-BROMO-2,5-DIMETHOXYTOLUENE 4-Bromo-2,5-dimethoxybenzaldehyde 1-Bromo-2,5-dimethoxybenzene 4-BROMO-2,5-DIMETHOXYPHENETHYLAMINE HCL TETRADECABROMO-1,4-DIPHENOXYBENZENE 5- BROMO-2-METHOXYPHENOL 4-BROMO-2-METHOXYPHENOL

  • 2-BROMO-4-METHOXYBENZENOL
  • 2-BROMO-4-METHOXYPHENOL
  • 2-bromo-4-methoxylphenol
  • 3-Bromo-4-hydroxyanisole
  • 2-Bromo-4-methoxyphenol ,98%
  • 4-Methoxy-2-bromophenol
  • 2-Bromo-4-methoxyphenol &gt
  • Phenol, 2-bromo-4-methoxy-
  • 17332-11-5
  • Alcohol& Phenol& Ethers
  • Phenol&Thiophenol&Mercaptan
  • blocks
  • Bromides
  • Anisoles, Alkyloxy Compounds & Phenylacetates
  • Bromine Compounds
  • Phenols