ChemicalBook > CAS DataBase List > 3-Bromophenylboronic acid

3-Bromophenylboronic acid

Product Name
3-Bromophenylboronic acid
CAS No.
89598-96-9
Chemical Name
3-Bromophenylboronic acid
Synonyms
3-Bromophenylboronic;M-BBBA;AKOS BRN-0083;RARECHEM AH PB 0076;3-bromophenylboric acid;3-BROMOPHENYLBORONIC ACID;3-BROMOBENZENEBORONIC ACID;3-Bromophenylboronic acid,97%;B-(3-bromophenyl)boronic acid;3-Bromophenylboronic acid ,98%
CBNumber
CB3755185
Molecular Formula
C6H6BBrO2
Formula Weight
200.83
MOL File
89598-96-9.mol
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3-Bromophenylboronic acid Property

Melting point:
164-168 °C (lit.)
Boiling point:
330.5±44.0 °C(Predicted)
Density 
1.67±0.1 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
DMSO (Slightly), Methanol (Slightly)
pka
7.55±0.10(Predicted)
form 
Crystalline Powder
color 
White
BRN 
3127104
InChI
InChI=1S/C6H6BBrO2/c8-6-3-1-2-5(4-6)7(9)10/h1-4,9-10H
InChIKey
AFSSVCNPDKKSRR-UHFFFAOYSA-N
SMILES
B(C1=CC=CC(Br)=C1)(O)O
CAS DataBase Reference
89598-96-9(CAS DataBase Reference)
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
36/37/38-22
Safety Statements 
37/39-26
WGK Germany 
3
HazardClass 
IRRITANT
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
441627
Product name
3-Bromophenylboronic acid
Packaging
5g
Price
$87.3
Updated
2025/07/31
TCI Chemical
Product number
B2890
Product name
3-Bromophenylboronic Acid (contains varying amounts of Anhydride)
Packaging
1g
Price
$33
Updated
2025/07/31
TCI Chemical
Product number
B2890
Product name
3-Bromophenylboronic Acid (contains varying amounts of Anhydride)
Packaging
5g
Price
$86
Updated
2025/07/31
TCI Chemical
Product number
B2890
Product name
3-Bromophenylboronic Acid (contains varying amounts of Anhydride)
Packaging
25g
Price
$258
Updated
2025/07/31
TRC
Product number
B687625
Product name
3-Bromophenylboronic acid
Packaging
2.5g
Price
$65
Updated
2021/12/16
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3-Bromophenylboronic acid Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powder

Uses

Reactant involved in a variety of organic reactions including:• ;Oxidative cross coupling1,2• ;Gold salt catalyzed homocoupling3• ;1,4-Addition reactions with α,β-unsaturated ketones4• ;Enantioselective addition reactions5• ;Suzuki-Miyaura coupling for synthesis of anthranilamide-protected arylboronic acids6• ;C-H Functionalization of quinones7

Uses

suzuki reaction

Uses

Reactant involved in a variety of organic reactions including:

  • Oxidative cross coupling
  • Gold salt catalyzed homocoupling
  • 1,4-Addition reactions with α,β-unsaturated ketones
  • Enantioselective addition reactions
  • Suzuki-Miyaura coupling for synthesis of anthranilamide-protected arylboronic acids
  • C-H Functionalization of quinones

Synthesis

121-43-7

591-18-4

89598-96-9

In a 500 mL round bottom flask, 1-bromo-3-iodobenzene (25.0 g, 88 mmol) was dissolved in 200 mL of tetrahydrofuran. The reaction solution was cooled to -78°C under nitrogen protection. n-Butyllithium (60.75 mL, 97 mmol) was slowly added dropwise to the cooled solution over a period of 30 minutes and stirring was continued at the same temperature for 1 hour. Subsequently, trimethyl borate (11 g, 106 mmol) was added dropwise at the same temperature, and then the mixture was gradually warmed to room temperature and stirred overnight. Upon completion of the reaction, 2 equivalents of hydrochloric acid was added dropwise to the reaction solution for acidification and stirring was continued for 1 hour. The reaction mixture was extracted with ethyl acetate, the organic layers were combined and concentrated under reduced pressure. The resulting crystals were dissolved in cold hexane to give Intermediate 11-a (12 g, 67.6% yield).

References

[1] Patent: KR2015/130206, 2015, A. Location in patent: Paragraph 0862-0867
[2] Patent: KR2016/13678, 2016, A. Location in patent: Paragraph 0324-0330

3-Bromophenylboronic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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3-Bromophenylboronic acid Suppliers

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View Lastest Price from 3-Bromophenylboronic acid manufacturers

Henan Fengda Chemical Co., Ltd
Product
3-Bromophenylboronic acid 89598-96-9
Price
US $34.00-1.20/kg
Min. Order
1kg
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-04-08
Guangzhou Sunton Biotechnology Co., Ltd.
Product
pharm intermediates 3-Bromophenylboronic acid 89598-96-9
Price
US $48.00-40.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200tons
Release date
2021-04-16
LY Global chemicals co.,ltd .
Product
3-Bromophenylboronic acid 89598-96-9
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%Min
Supply Ability
1000kg
Release date
2023-03-12

89598-96-9, 3-Bromophenylboronic acidRelated Search:

1,2-Dibromobenzene Bromoxynil 4-Bromobenzaldehyde Triphenylphosphine Folic acid Glycine Phenylboronic acid Ethyl 2-(Chlorosulfonyl)acetate 4-Bromobenzotrifluoride Bromoxynil octanoate 3-Bromofluorobenzene 2-Bromobenzaldehyde Zinc borate 1,4-Dibromobenzene 4-BROMOPHENYLBORONIC ACID,P-BROMOPHENYLBORONIC ACID,4-Bromophenylboronic Acid (contains varying amounts of Anhydride) Phenylacetone 5-BROMO-2-ETHOXYPHENYLBORONIC ACID 1-Bromo-4-nitrobenzene

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  • Boronic acid, (3-broMophenyl)-
  • 3-BroMophenylboronic acid, 97%, May contain varying aMounts of anhydride
  • Boronicacid, B-(3-broMophenyl)-
  • M-BBBA
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  • pharm intermediates 3-Bromophenylboronic acid
  • Boronic acid, B-(3-bromophenyI)-
  • 3-bromophenylboric acid
  • meta-bromophenylboronic acid, 98%
  • 3-Bromophenylboronic acid - [B1920]
  • 89598-96-9
  • C6H6O2BBr
  • Aryl
  • Boronic Acids
  • Boronic Acids and Derivatives
  • Organometallic Reagents
  • Aryl Boronic Acids
  • Boronic Acids and Derivatives
  • Chemical Synthesis
  • Monosubstituted Aryl Boronic Acids
  • Organometallic Reagents
  • Boronate Ester
  • Potassium Trifluoroborate
  • Boronic Acids and Derivatives
  • blocks
  • BoronicAcids
  • Bromides
  • Boric Acid
  • Boronic acids
  • Boronic Acid
  • B (Classes of Boron Compounds)
  • Boronic Acids
  • Aryl
  • Organoborons