ChemicalBook > CAS DataBase List > METHYL 2-BROMOMETHYL-5-CHLORO-BENZOATE

METHYL 2-BROMOMETHYL-5-CHLORO-BENZOATE

Product Name: METHYL 2-BROMOMETHYL-5-CHLORO-BENZOATE
CAS No.: 668262-52-0
Chemical Name: METHYL 2-BROMOMETHYL-5-CHLORO-BENZOATE
Synonyms: -5-chlorobenzoate;METHYL 2-BROMOMETHYL-5-CHLORO-BENZOATE;2-BROMOMETHYL-5-CHLORO-BENZOIC ACID METHYL ESTER;2-carboxy-4-chloro-broMoMethylbenzene Methyl ester;Benzoic acid, 2-(bromomethyl)-5-chloro-, methyl ester
CBNumber: CB3762945
Molecular Formula: C9H8BrClO2
Formula Weight: 263.52
MOL File: 668262-52-0.mol

Less

METHYL 2-BROMOMETHYL-5-CHLORO-BENZOATE Property

Boiling point:: 331.0±32.0 °C(Predicted)
Density: 1.561±0.06 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: liquid
color: Yellow

Less

Safety

HS Code: 2916310090

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

Less

N-Bromosuccinimide Price

Apolloscientific

Product number: OR400300
Product name: Methyl2-(bromomethyl)-5-chlorobenzoate
Packaging: 250mg
Price: $58
Updated: 2021/12/16

SynQuest Laboratories

Product number: 2723-D-00
Product name: Methyl 2-(bromomethyl)-5-chlorobenzoate
Packaging: 250mg
Price: $64
Updated: 2021/12/16

AK Scientific

Product number: Z5013
Product name: Methyl2-(bromomethyl)-5-chlorobenzoate
Packaging: 250mg
Price: $117
Updated: 2021/12/16

Apolloscientific

Product number: OR400300
Product name: Methyl2-(bromomethyl)-5-chlorobenzoate
Packaging: 1g
Price: $145
Updated: 2021/12/16

SynQuest Laboratories

Product number: 2723-D-00
Product name: Methyl 2-(bromomethyl)-5-chlorobenzoate
Packaging: 1g
Price: $160
Updated: 2021/12/16

Less

METHYL 2-BROMOMETHYL-5-CHLORO-BENZOATE Chemical Properties,Usage,Production

Synthesis

99585-13-4

668262-52-0

General procedure for the synthesis of methyl 2-(bromomethyl)-5-chlorobenzoate from methyl 2-methyl-5-chlorobenzoate: methyl 5-chloro-2-methylbenzoate (10.0 g, 54 mmol), N-bromosuccinimide (NBS, 10.6 g, 59.5 mmol), and azobisisobutyronitrile (AIBN, 200 mg) were dissolved in 1,2-dichloroethane ( 300 mL). The reaction mixture was irradiated and stirred for 2 h under photocatalytic conditions using [PHOTOLAMP]. Upon completion of the reaction, the mixture was cooled to room temperature and concentrated under reduced pressure. The residue was purified by silica gel column chromatography with heptane/dichloromethane as eluent (gradient elution: 9:1, 4:1, 1:1) to afford 11.8 g of methyl 2-(bromomethyl)-5-chlorobenzoate (83% yield). The product was characterized by 1H NMR (300 MHz, CDCl3): δ 7.98 (d, J = 2.1 Hz, 1H), 7.49 (dd, J = 2.2, 8.2 Hz, 1H), 7.43 (d, J = 8.2 Hz, 1H), 4.93 (s, 2H), 3.97 (s, 3H).

References

[1] Patent: WO2004/18414, 2004, A2. Location in patent: Page 112
[2] Patent: WO2005/21508, 2005, A1. Location in patent: Page/Page column 148
[3] Israel Journal of Chemistry, 1971, vol. 9, p. 111 - 118
[4] Bioorganic and Medicinal Chemistry Letters, 2008, vol. 18, # 5, p. 1628 - 1631
[5] Bioorganic and Medicinal Chemistry Letters, 2013, vol. 23, # 1, p. 360 - 365

METHYL 2-BROMOMETHYL-5-CHLORO-BENZOATE Preparation Products And Raw materials

Raw materials

Preparation Products

Less

METHYL 2-BROMOMETHYL-5-CHLORO-BENZOATE Suppliers

China 58 India 1 United Kingdom 1 United States 9 Global 69

Beijing Eternalchem Co,. Ltd.

Tel: 010-59484199 18611897322
Email: sales@eternalchem.com
Country: China
ProdList: 4383
Advantage: 60

Chemsky（shanghai）International Co.,Ltd.

Tel: 021-50135380
Email: shchemsky@sina.com
Country: China
ProdList: 32321
Advantage: 50

Shanghai Sheepchem Co., Ltd.

Tel: +86 (21) 6715-7650
Fax: +86 (21) 6715-7651
Email: sheepchem@163.com
Country: China
ProdList: 994
Advantage: 60

Runpharm Technology Limited

Tel: 18171398856 2968382473
Fax: 0086-21-50758330
Email: service@runpharm.com
Country: China
ProdList: 716
Advantage: 55

Shanghai Raise Chemical Technology Co.,Ltd

Tel: +86-021-50935922
Fax: +86-021-33847795
Country: China
ProdList: 7865
Advantage: 55

Shanghai Carlow Chemicals Co., Ltd.

Tel: 21-33526724 18930996265
Fax: 37023730
Email: info@carlowchem.com
Country: China
ProdList: 1922
Advantage: 58

Shanghai Leto Pharmatech Co.,Ltd.

Tel: 18016401466
Fax: QQ: 1375988926
Email: sales@letopharm.com
Country: China
ProdList: 245
Advantage: 58

Wuhan Chemduro Pharm Tech Co. Ltd.

Tel: 18040571231/1402788087
Fax: sales@chemduro.com
Country: China
ProdList: 1973
Advantage: 58

Zhengzhou Guancheng Laboratory equipment Sales

Tel: 0371-88888888 272369594
Fax: QQ:272369594
Email: 2723695949@qq.com
Country: China
ProdList: 4956
Advantage: 50

Changzhou Anxuan Chemical, Co., Ltd.

Tel: 13912302692 13912302692;
Fax: 0519-88064678
Email: sales@anxuanchem.com
Country: China
ProdList: 4828
Advantage: 58

DebyeTec.com Inc.

Tel: 18-086626237 18086626237
Fax: qq:2693528373
Email: 2693528373@qq.com
Country: China
ProdList: 2973
Advantage: 56

SanoChem (Chengdu) Tech. Co., Ltd.

Tel: 28-87999436 02887999436
Fax: QQ:2746983436
Email: sales@sano-chem.com
Country: China
ProdList: 3795
Advantage: 55

Shanghai Chenzhu Pharmaceutical Co., Ltd.

Tel: 13162380607
Fax: QQ:1696175688
Email: 1696175688@qq.com
Country: China
ProdList: 817
Advantage: 55

Shijiazhuang Sdyano Fine Chemical Co., Ltd.

Tel: 0311-89250318 031166536426
Fax: 4000311741
Email: master@sjzsdyn.com
Country: China
ProdList: 3495
Advantage: 58

BioPharmaMatrix,Inc.

Tel: 0510-86010668
Fax: 0510-86010668
Email: sales@biopharmamatrix.com
Country: China
ProdList: 4740
Advantage: 55

Amadis Chemical Company Limited

Tel: 571-89925085
Fax: 0086-571-89925065
Email: sales@amadischem.com
Country: China
ProdList: 131957
Advantage: 58

Adobe Chem Co., Ltd.

Tel: 2332782371
Fax: QQ: 2332782371
Email: adobechem@qq.com
Country: China
ProdList: 7980
Advantage: 58

Chengdu Novel Biomedical Co., Ltd.

Tel: 028-85255396 18302801538
Fax: 028-85255396
Email: cdnovell@163.com
Country: China
ProdList: 2390
Advantage: 58

Capot Chemical Co.,Ltd.

Tel: +86-（0）57185586718; +8613336195806
Fax: +86-571-85864795
Email: sales@capot.com
Country: China
ProdList: 29735
Advantage: 60

Aikon International Limited

Tel: 025-66061636 18013972705
Fax: (3)02557626880
Email: qqyang@aikonchem.com
Country: China
ProdList: 15814
Advantage: 58

Shanghai Jizhi Biochemical Technology Co. Ltd.

Tel: 4009004166/18616739031 18616739031
Email: 3007523370@qq.com
Country: China
ProdList: 52687
Advantage: 58

Shanghai Moss Medicine Technology Co., Ltd.

Tel: +86-188369842 +86-15618151133
Fax: QQ188369842
Email: 188369842@qq.com
Country: China
ProdList: 1959
Advantage: 58

Shanghai zhigan biotechnology co., LTD

Tel
Email: zhiqianbio@126.com
Country: China
ProdList: 19778
Advantage: 58

Zhejiang J&C Biological Technology Co.,Limited

Tel: +1-2135480471
Email: sales@sarms4muscle.com
Country: China
ProdList: 10473
Advantage: 58

Hefei TNJ Chemical Industry Co.,Ltd.

Tel: +86-0551-65418684 +8618949823763
Fax: 0086-551-65418684
Email: sales@tnjchem.com
Country: China
ProdList: 25356
Advantage: 58

Win-Win chemical CO., Limited

Tel: +86-0086-577-64498589 +86-15355981851
Fax: 0086-577-56994596
Email: sales@win-winchemical.com
Country: China
ProdList: 14359
Advantage: 58

Wuxi Kehua Biological Technology Co., Ltd.

Tel: 0510-86838766 13636419861
Email: 2258830676@qq.com
Country: China
ProdList: 5044
Advantage: 58

Shanghai Amico Chemicals Co. LTD

Tel: 微信 17321281695 18019252918
Fax: qq:1454668768
Email: 1454668768@qq.com
Country: China
ProdList: 14873
Advantage: 58

Chengdu Feibo Pharm Technology Co., Ltd

Tel: +86 028-84641798 15982321820
Email: abby@arkpharm.com
Country: China
ProdList: 10000
Advantage: 58

career henan chemical co

Tel: +86-0371-86658258 +8613203830695
Fax: 0086-371-86658258
Email: factory@coreychem.com
Country: China
ProdList: 29798
Advantage: 58

Wuhan chuanghao Biotechnology Co., Ltd

Tel: 13361917963
Email: 876725023@qq.com
Country: China
ProdList: 281
Advantage: 58

Guangzhou Yuheng Pharmaceutical Technology Co., Ltd

Tel: +8613580539051
Email: joe@yuhengpharm.com
Country: CHINA
ProdList: 21142
Advantage: 58

JW & Y Pharmlab Co., Ltd.

Tel: 021-64340559 13651849907
Fax: 021-64345308
Email: xinyu_shi@jwypharmlab.com.cn
Country: China
ProdList: 9381
Advantage: 58

Zhengzhou convergence chemical co., LTD

Tel: 0371-0371-55153829 18003835034
Email: 2853979819@qq.com
Country: China
ProdList: 9998
Advantage: 58

Hubei Co-prosperity Medicine Technonlogy Co., Ltd

Tel: 2383948258 19172820304
Email: 2383948258@qq.com
Country: China
ProdList: 12987
Advantage: 58

Beijing Jin Ming Biotechnology Co., Ltd.

Tel: 010-60605840 15801484223;
Email: psaitong@jm-bio.com
Country: China
ProdList: 29757
Advantage: 58

Shanghai Haohong Pharmaceutical Co., Ltd.

Tel: 400-8210725 4008210725
Email: malulu@leyan.com
Country: China
ProdList: 40000
Advantage: 58

Hefei Mokai Pharmaceutical Technology Co., Ltd

Tel: 18130062233
Email: 3362556465@qq.com
Country: China
ProdList: 8100
Advantage: 58

Shaanxi Yudingzhuo Medical Technology Co., Ltd.

Tel: 18992018580 18165105898
Fax: QQ:1617857088
Email: 13608210612@163.com
Country: China
ProdList: 2984
Advantage: 58

Bide Pharmatech Ltd.

Tel: 400-1647117 13681763483
Email: product02@bidepharm.com
Country: China
ProdList: 59936
Advantage: 58

Qi Qi hang Biotechnology Co., Ltd.

Tel: 15870833005
Email: 2232044025@qq.com
Country: China
ProdList: 8206
Advantage: 58

Bide Pharmatech Ltd.

Tel: 400-6005915
Email: sales@picasso-e.com
Country: China
ProdList: 39653
Advantage: 58

Beijing Solarbio Science & Tecnology Co., Ltd.

Tel: 010-50973130 17801761073
Email: Gsiyu@solarbio.com
Country: China
ProdList: 50464
Advantage: 58

Shanghai Jieshikai Biotechnology Co. , Ltd.

Tel: 021-57520305 13795461237
Email: zhuruyan@jskchem.com
Country: China
ProdList: 49234
Advantage: 58

https://hanhongsci.com/

Tel: 021-54306202 18917919676
Email: info@hanhongsci.com
Country: China
ProdList: 29995
Advantage: 58

Huzhou Chengbo Biotechnology Co., Ltd

Tel: 13626726938
Country: China
ProdList: 3879
Advantage: 58

Shanghai Aladdin Biochemical Technology Co.,Ltd.

Tel: 400-6206333 13167063860
Email: anhua.mao@aladdin-e.com
Country: China
ProdList: 48457
Advantage: 58

Wuhan WinYuanBei Trading Company

Tel: 86-13349903920 13349903920
Fax: -
Email: 869523959@qq.com
Country: China
ProdList: 9625
Advantage: 58

BEIJINGYIWANJINGRUI

Tel: 15866847540
Email: dengyt2000@163.com
Country: China
ProdList: 4100
Advantage: 58

Shandong benrite new chemical materials co.,ltd

Tel: 0533-2866658 15615638350
Email: sales@benritechem.com
Country: China
ProdList: 6650
Advantage: 58

Less

View Lastest Price from METHYL 2-BROMOMETHYL-5-CHLORO-BENZOATE manufacturers

Career Henan Chemical Co

Product: Methyl 2-(bromomethyl)-5-chlorobenzoate 668262-52-0
Price: US $1.00/KG
Min. Order: 1KG
Purity: ≥98%
Supply Ability: 20 tons
Release date: 2020-01-09

668262-52-0, METHYL 2-BROMOMETHYL-5-CHLORO-BENZOATERelated Search:

2-(BROMOMETHYL)BENZYL ALCOHOL, 95% 5-CHLORO-2-METHYL-BENZOIC ACID METHYL ESTER METHYL 2-BROMOMETHYL-5-CHLORO-BENZOATE 2-(Bromomethyl)benzoic acid Methyl 2-bromomethylbenzoate

METHYL 2-BROMOMETHYL-5-CHLORO-BENZOATE

Benzoic acid, 2-(bromomethyl)-5-chloro-, methyl ester

2-BROMOMETHYL-5-CHLORO-BENZOIC ACID METHYL ESTER

2-carboxy-4-chloro-broMoMethylbenzene Methyl ester

-5-chlorobenzoate

668262-52-0