2-(BROMOMETHYL)BENZYL ALCOHOL, 95%

Product Name: 2-(BROMOMETHYL)BENZYL ALCOHOL, 95%
CAS No.: 74785-02-7
Chemical Name: 2-(BROMOMETHYL)BENZYL ALCOHOL, 95%
Synonyms: (2-(broMoMethyl)phenyl)Methanol;BenzeneMethanol, 2-(broMoMethyl)-;2-(BroMoMethyl)benzyl alcohol 95%;2-(BROMOMETHYL)BENZYL ALCOHOL, 95%;2-(Bromomethyl)benzenemethanol, 2-Hydroxymethylbenzylbromide
CBNumber: CB7972656
Molecular Formula: C8H9BrO
Formula Weight: 201.06
MOL File: 74785-02-7.mol

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2-(BROMOMETHYL)BENZYL ALCOHOL, 95% Property

Melting point:: 66-68 °C
Boiling point:: 279.6±20.0 °C(Predicted)
Density: 1.514±0.06 g/cm3(Predicted)
storage temp.: 2-8°C
pka: 14.18±0.10(Predicted)
form: solid
Appearance: White to off-white Solid
InChI: InChI=1S/C8H9BrO/c9-5-7-3-1-2-4-8(7)6-10/h1-4,10H,5-6H2
InChIKey: JDBQNNKIOFSPOA-UHFFFAOYSA-N
SMILES: C1(CO)=CC=CC=C1CBr

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Safety

Hazard Codes: C,N
Risk Statements: 22-34-43-50
Safety Statements: 26-28-36/37/39-45-61
RIDADR: UN 3261 8/PG 2
WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H317May cause an allergic skin reaction

H400Very toxic to aquatic life

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 667706
Product name: 2-(Bromomethyl)benzyl alcohol
Purity: 95%
Packaging: 1g
Price: $328
Updated: 2025/07/31

TRC

Product number: B870075
Product name: (2-(bromomethyl)phenyl)methanol
Packaging: 10mg
Price: $45
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB139993
Product name: (2-(Bromomethyl)phenyl)methanol
Packaging: 250mg
Price: $100
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB139993
Product name: (2-(Bromomethyl)phenyl)methanol
Packaging: 500mg
Price: $180
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB139993
Product name: (2-(Bromomethyl)phenyl)methanol
Packaging: 1g
Price: $270
Updated: 2021/12/16

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2-(BROMOMETHYL)BENZYL ALCOHOL, 95% Chemical Properties,Usage,Production

Synthesis

612-14-6

74785-02-7

To 48% hydrobromic acid (15.0 mL) was added 1,2-benzenedimethanol (4.0 g, 29.0 mmol), and the reaction mixture was stirred for 2 h at room temperature. After the reaction was completed, 1N NaOH aqueous solution was added to neutralize to pH 7. The reaction mixture was diluted with ethyl acetate (200 mL), washed sequentially with saturated NaHCO3 solution (20 mL) and brine (20 mL), and the organic phase was dried over anhydrous Na2SO4. The solvent was removed by concentration under reduced pressure and the crude product was purified by silica gel column chromatography (Combi Flash Rf apparatus, ethyl acetate/hexane solvent system, 0-30% gradient elution) to afford 2.6 g (45% yield) of the target compound S14 as a white solid.1H NMR (500 MHz, CDCl3) δ: 7.30-7.45 (m, 4H), 4.85 (s, 2H), 4.64 (s, 2H), 1.81 (br s, 1H).

References

[1] Journal of the American Chemical Society, 2010, vol. 132, # 49, p. 17366 - 17369
[2] Journal of the American Chemical Society, 1980, vol. 102, p. 4193
[3] Synthesis, 1982, # 12, p. 1014 - 1015
[4] Patent: WO2015/69932, 2015, A1. Location in patent: Page/Page column 90; 91
[5] Patent: WO2015/188197, 2015, A2. Location in patent: Page/Page column 78

2-(BROMOMETHYL)BENZYL ALCOHOL, 95% Preparation Products And Raw materials

Raw materials

Preparation Products

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2-(BROMOMETHYL)BENZYL ALCOHOL, 95% Suppliers

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74785-02-7, 2-(BROMOMETHYL)BENZYL ALCOHOL, 95%Related Search:

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2-(Bromomethyl)benzenemethanol, 2-Hydroxymethylbenzylbromide

2-(BroMoMethyl)benzyl alcohol 95%

BenzeneMethanol, 2-(broMoMethyl)-

(2-(broMoMethyl)phenyl)Methanol

2-(BROMOMETHYL)BENZYL ALCOHOL, 95%

74785-02-7

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