Methyl 2-bromomethylbenzoate

Product Name: Methyl 2-bromomethylbenzoate
CAS No.: 2417-73-4
Chemical Name: Methyl 2-bromomethylbenzoate
Synonyms: METHYL 2-BROMOMETHYL BENZOATE;RARECHEM AL BO 0035;ART-CHEM-BB B019566;2-BROMOMETHYL-1-BENZOIC ACID;2-BroMoMethylbenzoic Methylester;2-(BROMOMETHYL)BENZOIC ACID METHYL ESTER;o-(Bromomethyl)benzoic acid methyl ester;Benzoic acid, 2-(bromomethyl)-, methyl ester
CBNumber: CB7308451
Molecular Formula: C9H9BrO2
Formula Weight: 229.07
MOL File: 2417-73-4.mol

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Methyl 2-bromomethylbenzoate Property

Melting point:: 32-32.5 °C
Boiling point:: 114 °C(Press: 0.44 Torr)
Density: 1.460±0.06 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
solubility: Chloroform (Sparingly), Hexane (Slightly)
form: Solid
color: White Low Melting
InChI: InChI=1S/C9H9BrO2/c1-12-9(11)8-5-3-2-4-7(8)6-10/h2-5H,6H2,1H3
InChIKey: QKASDIPENBEWBU-UHFFFAOYSA-N
SMILES: C(OC)(=O)C1=CC=CC=C1CBr
CAS DataBase Reference: 2417-73-4(CAS DataBase Reference)

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Safety

HS Code: 2916310090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TRC

Product number: M295180
Product name: Methyl2-Bromomethylbenzoate
Packaging: 25g
Price: $225
Updated: 2021/12/16

Matrix Scientific

Product number: 074145
Product name: Methyl 2-bromomethylbenzoate
Purity: 95+%
Packaging: 25g
Price: $289
Updated: 2021/12/16

SynQuest Laboratories

Product number: 2723-9-03
Product name: Methyl 2-bromomethylbenzoate
Purity: 95%
Packaging: 10g
Price: $295
Updated: 2021/12/16

Medical Isotopes, Inc.

Product number: 34900
Product name: Methyl2-bromomethylbenzoate
Packaging: 1g
Price: $319
Updated: 2021/12/16

Apolloscientific

Product number: OR301372
Product name: Methyl2-(bromomethyl)benzoate
Packaging: 25g
Price: $327
Updated: 2021/12/16

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Methyl 2-bromomethylbenzoate Chemical Properties,Usage,Production

Uses

Methyl 2-Bromomethylbenzoate is a reactant in the preparation of Methyl 2-((4-(2-(2-methylphenoxy)acetyl)piperazin-1-yl)methyl)benzoate with neuroprotective activity.

Synthesis

89-71-4

2417-73-4

General procedure for the synthesis of methyl 2-bromomethylbenzoate from methyl o-toluate: (2) 1.50 g (10 mmol) of methyl o-toluate was added to a 250 mL round-bottom flask and dissolved in 80 mL of carbon tetrachloride. Subsequently 1.98 g (11 mmol) of N-bromosuccinimide (NBS) and 48 mg (0.2 mmol) of benzoyl peroxide (BPO) were added. The mixture was heated to reflux for 1.5 h to ensure complete reaction. Upon completion of the reaction, insoluble material was removed by filtration and the solvent was subsequently evaporated to give methyl 2-bromomethylbenzoate. The reaction was quantitative.

References

[1] Journal of Medicinal Chemistry, 2000, vol. 43, # 24, p. 4667 - 4677
[2] Chemical Communications, 2010, vol. 46, # 13, p. 2227 - 2229
[3] Patent: US2011/237786, 2011, A1. Location in patent: Page/Page column 7
[4] Zeitschrift fuer Naturforschung, B: Chemical Sciences, 1989, vol. 44, # 9, p. 1132 - 1148
[5] Journal of Heterocyclic Chemistry, 1980, vol. 17, # 9, p. 1359 - 1360

Methyl 2-bromomethylbenzoate Preparation Products And Raw materials

Raw materials

Benzoyl peroxide N-Bromosuccinimide Methyl o-toluate

Preparation Products

2-((1-(TERT-BUTOXYCARBONYL)PIPERIDIN-4-YL)METHYL)BENZOIC ACID METHYL 2-((PIPERIDIN-4-YL)METHYL)BENZOATE

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Methyl 2-bromomethylbenzoate Suppliers

China 161 Europe 2 Germany 3 India 5 Russia 1 Slovakia 1 Switzerland 1 United Kingdom 12 United States 27 Global 213

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View Lastest Price from Methyl 2-bromomethylbenzoate manufacturers

Career Henan Chemical Co

Product: Methyl 2-bromomethylbenzoate 2417-73-4
Price: US $9.80/KG
Min. Order: 1g
Purity: ≥99%
Supply Ability: 100kg
Release date: 2020-01-03

2417-73-4, Methyl 2-bromomethylbenzoateRelated Search:

METSULFURON METHYL Methylparaben Sodium benzoate Benzyl benzoate Methyl bromoacetate Methyl benzoate Denatonium Benzoate Anhydrous Methyl acetate Kresoxim-methyl Methyl 2-(chlorosulfonyl)benzoate 4-Bromomethylbenzoic acid Methyl 2-iodobenzoate Bensulfuron methyl Methyl acrylate p-Toluic acid Emamectin benzoate Thiophanate-methyl Methyl

2-(BROMOMETHYL)BENZOIC ACID METHYL ESTER

2-BROMOMETHYL-1-BENZOIC ACID

METHYL 2-BROMOMETHYL BENZOATE

ART-CHEM-BB B019566

RARECHEM AL BO 0035

2-BroMoMethylbenzoic Methylester

o-(Bromomethyl)benzoic acid methyl ester

Benzoic acid, 2-(bromomethyl)-, methyl ester

2417-73-4

7116-89-1

Aromatic Esters

Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts