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Methyl 2-bromomethylbenzoate

Product Name
Methyl 2-bromomethylbenzoate
CAS No.
2417-73-4
Chemical Name
Methyl 2-bromomethylbenzoate
Synonyms
METHYL 2-BROMOMETHYL BENZOATE;RARECHEM AL BO 0035;ART-CHEM-BB B019566;2-BROMOMETHYL-1-BENZOIC ACID;2-BroMoMethylbenzoic Methylester;2-(BROMOMETHYL)BENZOIC ACID METHYL ESTER;o-(Bromomethyl)benzoic acid methyl ester;Benzoic acid, 2-(bromomethyl)-, methyl ester
CBNumber
CB7308451
Molecular Formula
C9H9BrO2
Formula Weight
229.07
MOL File
2417-73-4.mol
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Methyl 2-bromomethylbenzoate Property

Melting point:
32-32.5 °C
Boiling point:
114 °C(Press: 0.44 Torr)
Density 
1.460±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
solubility 
Chloroform (Sparingly), Hexane (Slightly)
form 
Solid
color 
White Low Melting
InChI
InChI=1S/C9H9BrO2/c1-12-9(11)8-5-3-2-4-7(8)6-10/h2-5H,6H2,1H3
InChIKey
QKASDIPENBEWBU-UHFFFAOYSA-N
SMILES
C(OC)(=O)C1=CC=CC=C1CBr
CAS DataBase Reference
2417-73-4(CAS DataBase Reference)
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Safety

HS Code 
2916310090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TRC
Product number
M295180
Product name
Methyl2-Bromomethylbenzoate
Packaging
25g
Price
$225
Updated
2021/12/16
Matrix Scientific
Product number
074145
Product name
Methyl 2-bromomethylbenzoate
Purity
95+%
Packaging
25g
Price
$289
Updated
2021/12/16
SynQuest Laboratories
Product number
2723-9-03
Product name
Methyl 2-bromomethylbenzoate
Purity
95%
Packaging
10g
Price
$295
Updated
2021/12/16
Medical Isotopes, Inc.
Product number
34900
Product name
Methyl2-bromomethylbenzoate
Packaging
1g
Price
$319
Updated
2021/12/16
Apolloscientific
Product number
OR301372
Product name
Methyl2-(bromomethyl)benzoate
Packaging
25g
Price
$327
Updated
2021/12/16
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Methyl 2-bromomethylbenzoate Chemical Properties,Usage,Production

Uses

Methyl 2-Bromomethylbenzoate is a reactant in the preparation of Methyl 2-((4-(2-(2-methylphenoxy)acetyl)piperazin-1-yl)methyl)benzoate with neuroprotective activity.

Synthesis

89-71-4

2417-73-4

General procedure for the synthesis of methyl 2-bromomethylbenzoate from methyl o-toluate: (2) 1.50 g (10 mmol) of methyl o-toluate was added to a 250 mL round-bottom flask and dissolved in 80 mL of carbon tetrachloride. Subsequently 1.98 g (11 mmol) of N-bromosuccinimide (NBS) and 48 mg (0.2 mmol) of benzoyl peroxide (BPO) were added. The mixture was heated to reflux for 1.5 h to ensure complete reaction. Upon completion of the reaction, insoluble material was removed by filtration and the solvent was subsequently evaporated to give methyl 2-bromomethylbenzoate. The reaction was quantitative.

References

[1] Journal of Medicinal Chemistry, 2000, vol. 43, # 24, p. 4667 - 4677
[2] Chemical Communications, 2010, vol. 46, # 13, p. 2227 - 2229
[3] Patent: US2011/237786, 2011, A1. Location in patent: Page/Page column 7
[4] Zeitschrift fuer Naturforschung, B: Chemical Sciences, 1989, vol. 44, # 9, p. 1132 - 1148
[5] Journal of Heterocyclic Chemistry, 1980, vol. 17, # 9, p. 1359 - 1360

Methyl 2-bromomethylbenzoate Preparation Products And Raw materials

Raw materials

Benzoyl peroxide N-Bromosuccinimide Methyl o-toluate

Preparation Products

2-((1-(TERT-BUTOXYCARBONYL)PIPERIDIN-4-YL)METHYL)BENZOIC ACID METHYL 2-((PIPERIDIN-4-YL)METHYL)BENZOATE
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View Lastest Price from Methyl 2-bromomethylbenzoate manufacturers

Career Henan Chemical Co
Product
Methyl 2-bromomethylbenzoate 2417-73-4
Price
US $9.80/KG
Min. Order
1g
Purity
≥99%
Supply Ability
100kg
Release date
2020-01-03

2417-73-4, Methyl 2-bromomethylbenzoateRelated Search:

METSULFURON METHYL Methylparaben Sodium benzoate Benzyl benzoate Methyl bromoacetate Methyl benzoate Denatonium Benzoate Anhydrous Methyl acetate Kresoxim-methyl Methyl 2-(chlorosulfonyl)benzoate 4-Bromomethylbenzoic acid Methyl 2-iodobenzoate Bensulfuron methyl Methyl acrylate p-Toluic acid Emamectin benzoate Thiophanate-methyl Methyl

  • 2-(BROMOMETHYL)BENZOIC ACID METHYL ESTER
  • 2-BROMOMETHYL-1-BENZOIC ACID
  • METHYL 2-BROMOMETHYL BENZOATE
  • ART-CHEM-BB B019566
  • RARECHEM AL BO 0035
  • 2-BroMoMethylbenzoic Methylester
  • o-(Bromomethyl)benzoic acid methyl ester
  • Benzoic acid, 2-(bromomethyl)-, methyl ester
  • 2417-73-4
  • 7116-89-1
  • Aromatic Esters
  • Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts