Methyl 2-bromomethyl-3-methoxybenzoate

Product Name: Methyl 2-bromomethyl-3-methoxybenzoate
CAS No.: 71887-28-0
Chemical Name: Methyl 2-bromomethyl-3-methoxybenzoate
Synonyms: METHYL 2-BROMOMETHYL-3-METHOXY-BENZOATE;2-Bromomethyl-3-methoxybenzoic acid methyl ester;Benzoic acid, 2-(bromomethyl)-3-methoxy-, methyl ester
CBNumber: CB6767264
Molecular Formula: C10H11BrO3
Formula Weight: 259.1
MOL File: 71887-28-0.mol

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Methyl 2-bromomethyl-3-methoxybenzoate Property

Melting point:: 112-114 °C(Solv: hexane (110-54-3))
Boiling point:: 330.0±32.0 °C(Predicted)
Density: 1.432
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
Appearance: White to off-white Solid

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H227Combustible liquid

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Frontier Specialty Chemicals

Product number: J15272
Product name: Methyl2-bromomethyl-3-methoxybenzoate
Purity: 97%
Packaging: 1g
Price: $50
Updated: 2021/12/16

AK Scientific

Product number: 7381AH
Product name: Methyl2-bromomethyl-3-methoxybenzoate
Packaging: 250mg
Price: $123
Updated: 2021/12/16

Frontier Specialty Chemicals

Product number: J15272
Product name: Methyl2-bromomethyl-3-methoxybenzoate
Purity: 97%
Packaging: 5g
Price: $150
Updated: 2021/12/16

AK Scientific

Product number: 7381AH
Product name: Methyl2-bromomethyl-3-methoxybenzoate
Packaging: 1g
Price: $213
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0142425
Product name: METHYL-2-BROMOMETHYL-3-METHOXY-BENZOATE
Purity: 98.00%
Packaging: 5MG
Price: $502.73
Updated: 2021/12/16

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Methyl 2-bromomethyl-3-methoxybenzoate Chemical Properties,Usage,Production

Synthesis

42981-93-1

71887-28-0

General procedure for the synthesis of methyl 2-bromomethyl-3-methoxybenzoate from methyl 3-methoxy-2-methylbenzoate: to a solution of CHCl3 (2-5 mL/mmol) or CCl4 (5 mL/mmol) containing methyl 3-methoxy-2-methylbenzoate (1.00 eq.), N-bromosuccinimide (NBS, 1.10- 2.20 eq.) and azobisisobutyronitrile (AIBN, 0.02-0.04 eq.). The reaction mixture was heated to reflux for 2-22 hours and subsequently cooled to room temperature. Upon completion of the reaction, the solvent is removed by evaporation under reduced pressure if CHCl3 is used as solvent, or by distillation if CCl4 is used, to give the target product methyl 2-bromomethyl-3-methoxybenzoate. Precautions: CHCl3 and CCl4 are highly toxic and carcinogenic, protective gloves should be worn and the operation should be carried out in a fume hood.

References

[1] Tetrahedron, 2018, vol. 74, # 2, p. 224 - 239
[2] Journal of Organic Chemistry, 1980, vol. 45, # 1, p. 12 - 15
[3] Patent: WO2004/26875, 2004, A1. Location in patent: Page 38
[4] Patent: US2004/106791, 2004, A1. Location in patent: Page 9
[5] Chinese Chemical Letters, 2012, vol. 23, # 1, p. 9 - 12

Methyl 2-bromomethyl-3-methoxybenzoate Preparation Products And Raw materials

Raw materials

Preparation Products

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Methyl 2-bromomethyl-3-methoxybenzoate Suppliers

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METHYL 2-BROMOMETHYL-3-METHOXY-BENZOATE

2-Bromomethyl-3-methoxybenzoic acid methyl ester

Benzoic acid, 2-(bromomethyl)-3-methoxy-, methyl ester

71887-28-0