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Methyl 2-bromomethyl-3-methoxybenzoate

Product Name
Methyl 2-bromomethyl-3-methoxybenzoate
CAS No.
71887-28-0
Chemical Name
Methyl 2-bromomethyl-3-methoxybenzoate
Synonyms
METHYL 2-BROMOMETHYL-3-METHOXY-BENZOATE;2-Bromomethyl-3-methoxybenzoic acid methyl ester;Benzoic acid, 2-(bromomethyl)-3-methoxy-, methyl ester
CBNumber
CB6767264
Molecular Formula
C10H11BrO3
Formula Weight
259.1
MOL File
71887-28-0.mol
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Methyl 2-bromomethyl-3-methoxybenzoate Property

Melting point:
112-114 °C(Solv: hexane (110-54-3))
Boiling point:
330.0±32.0 °C(Predicted)
Density 
1.432
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
Appearance
White to off-white Solid
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H227Combustible liquid

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Frontier Specialty Chemicals
Product number
J15272
Product name
Methyl2-bromomethyl-3-methoxybenzoate
Purity
97%
Packaging
1g
Price
$50
Updated
2021/12/16
AK Scientific
Product number
7381AH
Product name
Methyl2-bromomethyl-3-methoxybenzoate
Packaging
250mg
Price
$123
Updated
2021/12/16
Frontier Specialty Chemicals
Product number
J15272
Product name
Methyl2-bromomethyl-3-methoxybenzoate
Purity
97%
Packaging
5g
Price
$150
Updated
2021/12/16
AK Scientific
Product number
7381AH
Product name
Methyl2-bromomethyl-3-methoxybenzoate
Packaging
1g
Price
$213
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0142425
Product name
METHYL-2-BROMOMETHYL-3-METHOXY-BENZOATE
Purity
98.00%
Packaging
5MG
Price
$502.73
Updated
2021/12/16
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Methyl 2-bromomethyl-3-methoxybenzoate Chemical Properties,Usage,Production

Synthesis

42981-93-1

71887-28-0

General procedure for the synthesis of methyl 2-bromomethyl-3-methoxybenzoate from methyl 3-methoxy-2-methylbenzoate: to a solution of CHCl3 (2-5 mL/mmol) or CCl4 (5 mL/mmol) containing methyl 3-methoxy-2-methylbenzoate (1.00 eq.), N-bromosuccinimide (NBS, 1.10- 2.20 eq.) and azobisisobutyronitrile (AIBN, 0.02-0.04 eq.). The reaction mixture was heated to reflux for 2-22 hours and subsequently cooled to room temperature. Upon completion of the reaction, the solvent is removed by evaporation under reduced pressure if CHCl3 is used as solvent, or by distillation if CCl4 is used, to give the target product methyl 2-bromomethyl-3-methoxybenzoate. Precautions: CHCl3 and CCl4 are highly toxic and carcinogenic, protective gloves should be worn and the operation should be carried out in a fume hood.

References

[1] Tetrahedron, 2018, vol. 74, # 2, p. 224 - 239
[2] Journal of Organic Chemistry, 1980, vol. 45, # 1, p. 12 - 15
[3] Patent: WO2004/26875, 2004, A1. Location in patent: Page 38
[4] Patent: US2004/106791, 2004, A1. Location in patent: Page 9
[5] Chinese Chemical Letters, 2012, vol. 23, # 1, p. 9 - 12

Methyl 2-bromomethyl-3-methoxybenzoate Preparation Products And Raw materials

Raw materials

Preparation Products

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Methyl 2-bromomethyl-3-methoxybenzoate Suppliers

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  • METHYL 2-BROMOMETHYL-3-METHOXY-BENZOATE
  • 2-Bromomethyl-3-methoxybenzoic acid methyl ester
  • Benzoic acid, 2-(bromomethyl)-3-methoxy-, methyl ester
  • 71887-28-0