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(3-acrylamidophenyl)boronic acid

Product Name
(3-acrylamidophenyl)boronic acid
CAS No.
99349-68-5
Chemical Name
(3-acrylamidophenyl)boronic acid
Synonyms
(m-AcryL;amidophenyL;3-(Propenamido);Boronic acid acrylamide;Phenylboronate acrylamide;(3-Acrylamidophenyl)boronicaci;3-Acrylamidobenzeneboronic Acid;(M-ACRYLAMIDOPHENYL)BORONIC ACID;3-(Propenamido)phenylboronic acid;3-(AcrylaMido)phenylboronic acid 98%
CBNumber
CB3837283
Molecular Formula
C9H10BNO3
Formula Weight
190.99
MOL File
99349-68-5.mol
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(3-acrylamidophenyl)boronic acid Property

Melting point:
129-146°C
Density 
1.22±0.1 g/cm3(Predicted)
storage temp. 
2-8°C
pka
8.05±0.10(Predicted)
form 
powder to crystal
color 
White to Amber
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Safety

Hazard Codes 
Xn
Risk Statements 
22
WGK Germany 
3
HS Code 
2931900090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
771465
Product name
3-(Acrylamido)phenylboronic acid
Purity
98%
Packaging
1g
Price
$151
Updated
2025/07/31
TCI Chemical
Product number
A3199
Product name
3-Acrylamidophenylboronic Acid (contains varying amounts of Anhydride)
Packaging
1g
Price
$128
Updated
2025/07/31
TCI Chemical
Product number
A3199
Product name
3-Acrylamidophenylboronic Acid (contains varying amounts of Anhydride)
Packaging
5g
Price
$379
Updated
2025/07/31
TRC
Product number
A191315
Product name
3-(Acrylamido)phenylboronic acid
Packaging
500mg
Price
$100
Updated
2021/12/16
TRC
Product number
A191315
Product name
3-(Acrylamido)phenylboronic acid
Packaging
2.5g
Price
$330
Updated
2021/12/16
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(3-acrylamidophenyl)boronic acid Chemical Properties,Usage,Production

Uses

suzuki reaction

Uses

This acrylamide monomer contains a glucose sensitive boronic acid commonly used for intelligent polymers solutions and gels;for drug delivery systems;sensors;actuator systems;and bioreactors.

Synthesis

30418-59-8

814-68-6

99349-68-5

General procedure for the synthesis of 3-acrylamidophenylboronic acid from 3-aminophenylboronic acid and acryloyl chloride: 3-aminophenylboronic acid (0.566 g, 3.65 mmol) and Na2CO3 (0.67 g, 80.3 mmol) were added to 20 mL of a 1:1 (v/v) solvent mixture of tetrahydrofuran and water and the mixture was cooled to 0 °C. Acryloyl chloride (960 mg, 8.06 mmol) was slowly added dropwise under stirring conditions. After the dropwise addition, the mixture was allowed to warm up naturally to room temperature and stirring was continued for 2 hours. Upon completion of the reaction, 10 mL of water was added to terminate the reaction, followed by extraction of the reaction mixture with ethyl acetate (20 mL x 3). The organic phases were combined, washed with saturated NaCl solution (10 mL) and finally the organic layer was dried with anhydrous Na2SO4. After concentrating the organic layer, it was purified by column chromatography to give the light yellow solid product 3-acrylamidophenylboronic acid (0.32 g, 40.1% yield).

References

[1] Journal of Medicinal Chemistry, 2017, vol. 60, # 11, p. 4636 - 4656
[2] Soft Matter, 2014, vol. 10, # 6, p. 911 - 920
[3] Journal of the American Chemical Society, 2011, vol. 133, # 49, p. 19832 - 19838
[4] Patent: CN104945411, 2018, B. Location in patent: Paragraph 0077; 0078; 0079
[5] New Journal of Chemistry, 2012, vol. 36, # 2, p. 438 - 451

(3-acrylamidophenyl)boronic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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(3-acrylamidophenyl)boronic acid Suppliers

Carbosynth
Tel
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Fax
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Email
sales@carbosynth.com
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United Kingdom
ProdList
6005
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58
Apollo Scientific Ltd.
Tel
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Fax
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Email
sales@apolloscientific.co.uk
Country
United Kingdom
ProdList
6084
Advantage
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Leancare Ltd.
Tel
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Email
enquiry@leancare.co.uk
Country
United Kingdom
ProdList
6446
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42
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View Lastest Price from (3-acrylamidophenyl)boronic acid manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
3-Acrylamidophenylboronic acid 99349-68-5
Price
US $2.00-6.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100kg
Release date
2025-07-29
Qingdao RENAS Polymer Material Co., Ltd.
Product
(3-acrylamidophenyl)boronic acid 99349-68-5
Price
US $0.00/kg
Min. Order
20kg
Purity
99%
Supply Ability
20 tons
Release date
2025-04-09
Shaanxi Dideu New Materials Co. Ltd
Product
(M-ACRYLAMIDOPHENYL)BORONIC ACID 99349-68-5
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10000KGS
Release date
2025-03-05

99349-68-5, (3-acrylamidophenyl)boronic acidRelated Search:


  • (M-ACRYLAMIDOPHENYL)BORONIC ACID
  • 3-(Acrylamido)phenylboronic acid, 3-[(Prop-2-enoyl)amino]benzeneboronic acid
  • 3-(Acryloylamino)benzeneboronic acid
  • 3-(AcrylaMido)phenylboronic acid 98%
  • 3-(Propenamido)phenylboronic acid
  • Boronic acid acrylamide
  • N-Acryloyl-3-aminophenylboronic acid
  • Phenylboronate acrylamide
  • Boronic acid, B-[3-[(1-oxo-2-propen-1-yl)amino]phenyl]-
  • N-Acryloyl-m-aminophenylboronic acid
  • 3-Acrylamidophenylboronic Acid (contains varying amounts of Anhydride)
  • 3-(Propenamido)
  • (m-AcryL
  • amidophenyL
  • 3-Acrylamidobenzeneboronic Acid
  • (3-Acrylamidophenyl)boronicaci
  • Synonym(s): 3-(propenamido)phenylboronic acid, N-acryloyl-3-aminophenylboronic acid, boronic acid acrylamide, phenylboronate acrylamide
  • 99349-68-5
  • 9934-68-5
  • C9H10BNO3
  • Aryl
  • Organoborons