ChemicalBook > CAS DataBase List > N'-Hydroxycyclopropanecarboximidamide

N'-Hydroxycyclopropanecarboximidamide

Product Name: N'-Hydroxycyclopropanecarboximidamide
CAS No.: 51285-13-3
Chemical Name: N'-Hydroxycyclopropanecarboximidamide
Synonyms: AKOS B030098;Cyclopropanecarboxamide oxime;N-HYDROXYCYCLOPROPANECARBOXAMIDINE;N’-Hydroxycyclopropanecarboxamidine;N-Hydroxy-cyclopropan-carboximidamide;N'-Hydroxycyclopropanecarboximidamide;N'-Hydroxycyclopropanecarboximideamide;Cyclopropanecarboximidamide,N-hydroxy-;(Z)-N'-hydroxycyclopropanecarboxamidine;Cyclopropanecarboximidamide, N-hydroxy- (9CI)
CBNumber: CB3853711
Molecular Formula: C4H8N2O
Formula Weight: 100.12
MOL File: 51285-13-3.mol

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N'-Hydroxycyclopropanecarboximidamide Property

Melting point:: 34-40°
Boiling point:: 176.0±23.0 °C(Predicted)
Density: 1.50±0.1 g/cm3(Predicted)
storage temp.: 2-8°C
pka: 15.04±0.20(Predicted)
Appearance: White to off-white Solid
InChI: InChI=1S/C4H8N2O/c5-4(6-7)3-1-2-3/h3,7H,1-2H2,(H2,5,6)
InChIKey: OMCUPXRCMTUDHI-UHFFFAOYSA-N
SMILES: C1(C(NO)=N)CC1
CAS DataBase Reference: 51285-13-3

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Safety

HazardClass: IRRITANT

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TRC

Product number: H950103
Product name: N''-Hydroxycyclopropanecarboximidamide
Packaging: 100mg
Price: $45
Updated: 2021/12/16

TRC

Product number: H950103
Product name: N''-Hydroxycyclopropanecarboximidamide
Packaging: 500mg
Price: $65
Updated: 2021/12/16

AK Scientific

Product number: W6626
Product name: (Z)-N'-Hydroxycyclopropanecarboxamidine
Packaging: 250mg
Price: $72
Updated: 2021/12/16

Matrix Scientific

Product number: 065786
Product name: N'-Hydroxycyclopropanecarboximidamide
Packaging: 500mg
Price: $315
Updated: 2021/12/16

AK Scientific

Product number: W6626
Product name: (Z)-N'-Hydroxycyclopropanecarboxamidine
Packaging: 1g
Price: $114
Updated: 2021/12/16

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N'-Hydroxycyclopropanecarboximidamide Chemical Properties,Usage,Production

Uses

N''-Hydroxycyclopropanecarboximidamide

Synthesis

5500-21-0

51285-13-3

General procedure for the synthesis of N-hydroxycyclopropanecarboxamidine from cyclopropanecarbonitrile: A mixture of cyclopropanecarbonitrile (5 g, 74.6 mmol) and hydroxylamine (50 wt% aqueous, 5.91 g, 89.5 mmol) in ethanol (15 mL) was reacted with stirring at 80 °C overnight. Upon completion of the reaction, the mixture was cooled to room temperature and the volatile solvent was subsequently removed under reduced pressure to afford the crude product N-hydroxycyclopropanecarboxamidine (7.0 g, 94% yield). The product could be directly used in the subsequent reaction without further purification. The product was analyzed by LCMS showing m/z = 101.2 [M + H]+, which was consistent with the theoretically calculated value (exact mass of C4H8N2O: 100.1).1H NMR (400 MHz, DMSO-d6) data were as follows: δ 0.54-0.60 (m, 2H), 0.61-0.66 (m, 2H), 1.28-1.36 (m, 1H) , 5.18 (bs, 2H), 8.68 (bs, 1H).

References

[1] Patent: WO2012/145361, 2012, A1. Location in patent: Page/Page column 167; 168
[2] Patent: WO2011/104680, 2011, A1. Location in patent: Page/Page column 82
[3] Patent: US5464848, 1995, A
[4] Patent: US5106853, 1992, A
[5] Patent: US5124460, 1992, A

N'-Hydroxycyclopropanecarboximidamide Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from N'-Hydroxycyclopropanecarboximidamide manufacturers

Career Henan Chemical Co

Product: N'-Hydroxycyclopropanecarboximidamide 51285-13-3
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1kg,5kg,100kg
Release date: 2019-07-04

51285-13-3, N'-HydroxycyclopropanecarboximidamideRelated Search:

Cyclopropanecarboxamidoxime,monohydrochloride N-HYDROXYPROPIONAMIDINE N'-hydroxycyclopropanecarboximidamide hydrochloride CYCLOPROPANECARBOXAMIDINE N'-Hydroxy-2-methylpropanimidamide N-HYDROXYBUTYRAMIDINE N'-Hydroxycyclopropanecarboximidamide

AKOS B030098

N-HYDROXYCYCLOPROPANECARBOXAMIDINE

Cyclopropanecarboximidamide, N-hydroxy- (9CI)

N'-Hydroxycyclopropanecarboximideamide

Cyclopropanecarboxamide oxime

(Z)-N'-hydroxycyclopropanecarboxamidine

Cyclopropanecarboximidamide,N-hydroxy-

N'-Hydroxycyclopropanecarboximidamide

N’-Hydroxycyclopropanecarboxamidine

N-Hydroxy-cyclopropan-carboximidamide

51285-13-3

AMIDINE

OXIME

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