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N'-Hydroxycyclopropanecarboximidamide

Product Name
N'-Hydroxycyclopropanecarboximidamide
CAS No.
51285-13-3
Chemical Name
N'-Hydroxycyclopropanecarboximidamide
Synonyms
AKOS B030098;Cyclopropanecarboxamide oxime;N-HYDROXYCYCLOPROPANECARBOXAMIDINE;N’-Hydroxycyclopropanecarboxamidine;N-Hydroxy-cyclopropan-carboximidamide;N'-Hydroxycyclopropanecarboximidamide;N'-Hydroxycyclopropanecarboximideamide;Cyclopropanecarboximidamide,N-hydroxy-;(Z)-N'-hydroxycyclopropanecarboxamidine;Cyclopropanecarboximidamide, N-hydroxy- (9CI)
CBNumber
CB3853711
Molecular Formula
C4H8N2O
Formula Weight
100.12
MOL File
51285-13-3.mol
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N'-Hydroxycyclopropanecarboximidamide Property

Melting point:
34-40°
Boiling point:
176.0±23.0 °C(Predicted)
Density 
1.50±0.1 g/cm3(Predicted)
storage temp. 
2-8°C
pka
15.04±0.20(Predicted)
Appearance
White to off-white Solid
InChI
InChI=1S/C4H8N2O/c5-4(6-7)3-1-2-3/h3,7H,1-2H2,(H2,5,6)
InChIKey
OMCUPXRCMTUDHI-UHFFFAOYSA-N
SMILES
C1(C(NO)=N)CC1
CAS DataBase Reference
51285-13-3
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Safety

HazardClass 
IRRITANT
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TRC
Product number
H950103
Product name
N''-Hydroxycyclopropanecarboximidamide
Packaging
100mg
Price
$45
Updated
2021/12/16
TRC
Product number
H950103
Product name
N''-Hydroxycyclopropanecarboximidamide
Packaging
500mg
Price
$65
Updated
2021/12/16
AK Scientific
Product number
W6626
Product name
(Z)-N'-Hydroxycyclopropanecarboxamidine
Packaging
250mg
Price
$72
Updated
2021/12/16
Matrix Scientific
Product number
065786
Product name
N'-Hydroxycyclopropanecarboximidamide
Packaging
500mg
Price
$315
Updated
2021/12/16
AK Scientific
Product number
W6626
Product name
(Z)-N'-Hydroxycyclopropanecarboxamidine
Packaging
1g
Price
$114
Updated
2021/12/16
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N'-Hydroxycyclopropanecarboximidamide Chemical Properties,Usage,Production

Uses

N''-Hydroxycyclopropanecarboximidamide

Synthesis

5500-21-0

51285-13-3

General procedure for the synthesis of N-hydroxycyclopropanecarboxamidine from cyclopropanecarbonitrile: A mixture of cyclopropanecarbonitrile (5 g, 74.6 mmol) and hydroxylamine (50 wt% aqueous, 5.91 g, 89.5 mmol) in ethanol (15 mL) was reacted with stirring at 80 °C overnight. Upon completion of the reaction, the mixture was cooled to room temperature and the volatile solvent was subsequently removed under reduced pressure to afford the crude product N-hydroxycyclopropanecarboxamidine (7.0 g, 94% yield). The product could be directly used in the subsequent reaction without further purification. The product was analyzed by LCMS showing m/z = 101.2 [M + H]+, which was consistent with the theoretically calculated value (exact mass of C4H8N2O: 100.1).1H NMR (400 MHz, DMSO-d6) data were as follows: δ 0.54-0.60 (m, 2H), 0.61-0.66 (m, 2H), 1.28-1.36 (m, 1H) , 5.18 (bs, 2H), 8.68 (bs, 1H).

References

[1] Patent: WO2012/145361, 2012, A1. Location in patent: Page/Page column 167; 168
[2] Patent: WO2011/104680, 2011, A1. Location in patent: Page/Page column 82
[3] Patent: US5464848, 1995, A
[4] Patent: US5106853, 1992, A
[5] Patent: US5124460, 1992, A

N'-Hydroxycyclopropanecarboximidamide Preparation Products And Raw materials

Raw materials

Preparation Products

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N'-Hydroxycyclopropanecarboximidamide Suppliers

ChemCollect GmbH
Tel
--
Fax
--
Email
contact@chemcollect.de
Country
Germany
ProdList
6214
Advantage
54
AKos Consulting and Solutions GmbH
Tel
--
Fax
--
Email
akos@akosgmbh.eu
Country
Germany
ProdList
1061
Advantage
60
Service Chemical Inc.
Tel
--
Fax
--
Email
sales@chemos-group.com
Country
Germany
ProdList
6350
Advantage
71
AKos Consulting & Solutions GmbH
Tel
--
Fax
--
Email
akos@akosgmbh.de
Country
Germany
ProdList
6717
Advantage
72
ABCR GmbH & CO. KG
Tel
--
Fax
--
Email
info@abcr.de
Country
Germany
ProdList
6831
Advantage
75
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View Lastest Price from N'-Hydroxycyclopropanecarboximidamide manufacturers

Career Henan Chemical Co
Product
N'-Hydroxycyclopropanecarboximidamide 51285-13-3
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1kg,5kg,100kg
Release date
2019-07-04

51285-13-3, N'-HydroxycyclopropanecarboximidamideRelated Search:


  • AKOS B030098
  • N-HYDROXYCYCLOPROPANECARBOXAMIDINE
  • Cyclopropanecarboximidamide, N-hydroxy- (9CI)
  • N'-Hydroxycyclopropanecarboximideamide
  • Cyclopropanecarboxamide oxime
  • (Z)-N'-hydroxycyclopropanecarboxamidine
  • Cyclopropanecarboximidamide,N-hydroxy-
  • N'-Hydroxycyclopropanecarboximidamide
  • N’-Hydroxycyclopropanecarboxamidine
  • N-Hydroxy-cyclopropan-carboximidamide
  • 51285-13-3
  • AMIDINE
  • OXIME
  • pharmacetical