6-Quinolineboronic acid pinacol ester, 97%
- Product Name
- 6-Quinolineboronic acid pinacol ester, 97%
- CAS No.
- 406463-06-7
- Chemical Name
- 6-Quinolineboronic acid pinacol ester, 97%
- Synonyms
- 6-Quinolineboronic acid pina;Quinoline-6-boronic acid picol ester;6-Quinolineboronic acid pinacol ester;Quinoline-6-boronic acid,pinacol ester;6-Quinolineboronic acid pinacol ester 97%;6-Quinolineboronic acid pinacol ester, 97%;4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)quinoline;2-(Quinolin-6-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;Quinoline, 6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-;6-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)quinoline, 6-Quinolylboronic acid pinacol ester
- CBNumber
- CB3973099
- Molecular Formula
- C15H18BNO2
- Formula Weight
- 255.12
- MOL File
- 406463-06-7.mol
6-Quinolineboronic acid pinacol ester, 97% Property
- Melting point:
- 62-66 °C(lit.)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- Powder or Crystalline Solid
- color
- White to pale orange
- InChIKey
- VMFALDWCEQUFSX-UHFFFAOYSA-N
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 641618
- Product name
- 6-Quinolineboronic acid pinacol ester
- Purity
- 97%
- Packaging
- 1g
- Price
- $44.59
- Updated
- 2025/07/31
- Product number
- 641618
- Product name
- 6-Quinolineboronic acid pinacol ester
- Purity
- 97%
- Packaging
- 5g
- Price
- $305
- Updated
- 2025/07/31
- Product number
- T3507
- Product name
- 6-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)quinoline
- Purity
- >98.0%(GC)(T)
- Packaging
- 1g
- Price
- $48
- Updated
- 2025/07/31
- Product number
- P991995
- Product name
- 6-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)quinoline
- Packaging
- 100mg
- Price
- $75
- Updated
- 2021/12/16
- Product number
- 093226
- Product name
- 6-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)quinoline
- Purity
- 95+%
- Packaging
- 1g
- Price
- $208
- Updated
- 2021/12/16
6-Quinolineboronic acid pinacol ester, 97% Chemical Properties,Usage,Production
Synthesis
5332-25-2
73183-34-3
406463-06-7
Step 2. Synthesis of 6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)quinoline A tetrahydrofuran (20 mL) solution of 6-bromoquinoline (5 g, 23.92 mmol, 1.00 equiv) was added to a pre-dried and purged 100 mL round bottom flask under nitrogen protection. Potassium acetate (KOAc, 3.55 g, 1.50 eq.), pinacol ester of bisboronic acid (18.23 g, 71.77 mmol, 3.00 eq.), and [1,1'-bis(diphenylphosphino)ferrocene]palladium(II) dichloride (Pd(dppf)2Cl2, 1.95 g) were then added sequentially. The reaction mixture was placed in an oil bath at 80 °C and the reaction was stirred overnight. After completion of the reaction, the insoluble solids were removed by filtration. The filtrate was concentrated under reduced pressure and purified by silica gel column chromatography with the eluent ethyl acetate/petroleum ether (1:50, v/v). 6.62 g (109% yield) of 6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)quinoline was finally obtained as a red oil.
References
[1] Patent: US2012/277224, 2012, A1. Location in patent: Page/Page column 90
[2] Patent: WO2008/51493, 2008, A2. Location in patent: Page/Page column 104
[3] Patent: CN105254613, 2016, A. Location in patent: Paragraph 0071; 0072; 0073
[4] Patent: WO2015/162538, 2015, A1. Location in patent: Page/Page column 66
[5] Organic Letters, 2014, vol. 16, # 17, p. 4562 - 4565
6-Quinolineboronic acid pinacol ester, 97% Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 6-Quinolineboronic acid pinacol ester, 97% manufacturers
- Product
- 6-Quinolineboronic acid pinacol ester, 97% 406463-06-7
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 200kg
- Release date
- 2019-12-31