TERT-BUTYL N,N-DIALLYLCARBAMATE
- Product Name
- TERT-BUTYL N,N-DIALLYLCARBAMATE
- CAS No.
- 151259-38-0
- Chemical Name
- TERT-BUTYL N,N-DIALLYLCARBAMATE
- Synonyms
- N-BOC-DIALLYLAMINE;tert-Butyl diallylcarbamate;TERT-BUTYL N,N-DIALLYLCARBAMATE;tert-ButylN,N-diallylcarbamate, 98%;ert-butylN,N-bis(prop-2-enyl)carbamate;tert-butyl N,N-bis(prop-2-enyl)carbamate;N,N-bis(prop-2-enyl)carbamic acid tert-butyl ester;TERT-BUTYL N,N-DIALLYLCARBAMATE ISO 9001：2015 REACH;tert-Butyl N,N-diallylcarbamate;tert-Butyl diallylcarbamate,98% (stabilized with MEHQ)
- CBNumber
- CB4100971
- Molecular Formula
- C11H19NO2
- Formula Weight
- 197.27
- MOL File
- 151259-38-0.mol
TERT-BUTYL N,N-DIALLYLCARBAMATE Property
- Boiling point:
- 75 °C/1.5 mmHg (lit.)
- Density
- 0.914 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.442(lit.)
- Flash point:
- 81 °C
- storage temp.
- 2-8°C, stored under nitrogen
- pka
- -1.46±0.70(Predicted)
- Appearance
- Colorless to light yellow Liquid
Safety
- WGK Germany
- 3
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P233Keep container tightly closed.
P235Keep cool.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 474800
- Product name
- tert-Butyl N,N-diallylcarbamate
- Purity
- 98%
- Packaging
- 10ml
- Price
- $65.7
- Updated
- 2023/06/20
- Product number
- 474800
- Product name
- tert-Butyl N,N-diallylcarbamate
- Purity
- 98%
- Packaging
- 50ml
- Price
- $232
- Updated
- 2023/01/07
- Product number
- CS-0130879
- Product name
- tert-Butyldiallylcarbamate
- Packaging
- 100g
- Price
- $439
- Updated
- 2021/12/16
- Product number
- CHM0029137
- Product name
- TERT-BUTYL N,N-DIALLYLCARBAMATE
- Purity
- 95.00%
- Packaging
- 10ML
- Price
- $1089.74
- Updated
- 2021/12/16
- Product number
- CHM0029137
- Product name
- TERT-BUTYL N,N-DIALLYLCARBAMATE
- Purity
- 95.00%
- Packaging
- 50ML
- Price
- $2483.25
- Updated
- 2021/12/16
TERT-BUTYL N,N-DIALLYLCARBAMATE Chemical Properties,Usage,Production
Uses
tert-Butyl N,N-diallylcarbamate may be used in the synthesis of heterocyclic compounds.
General Description
tert-Butyl N,N-diallylcarbamate is a protected amine. Ring-closing metathesis (RCM) reactions of tert-butyl N,N-diallylcarbamate in the presence of Hoveyda-Grubbs type catalyst supported on mesoporous molecular sieves have been reported.
Synthesis
24424-99-5
124-02-7
151259-38-0
Example 5: (±)-trans-1-[(9-deaza-adenin-9-yl)methyl]-3-hydroxy-4-vinylpyrrolidine (1. X=vinyl, A=CH, B=NH, D=H); Example 5.1: tert-butyl diallylcarbamate (7); Di-tert-butyl dicarbonate (42.2 g, 193 mmol) was added batchwise to a solution of diallylamine (2) (20 mL, 162 mmol) in methanol (500 mL) at 0°C. After addition, the reaction mixture was gradually warmed to room temperature with continuous stirring for 1 hour. Subsequently, the reaction mixture was concentrated by distillation under reduced pressure. The residue was purified by silica gel column chromatography (eluent: petroleum ether/ethyl acetate gradient elution, 0 to 50% ethyl acetate) to afford the target product tert-butyl diallylcarbamate 7 as a colorless oil (31.9 g, 99% yield). (Org. Biomol. Chem. 2004, 2, 2418-2420).
References
[1] Patent: WO2011/8110, 2011, A1. Location in patent: Page/Page column 41-42
[2] Journal of Organic Chemistry, 2006, vol. 71, # 21, p. 8283 - 8286
[3] Synthesis, 2001, # 1, p. 46 - 48
[4] Synthesis, 2004, # 14, p. 2367 - 2375
[5] Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 2016, vol. 71, # 6, p. 633 - 641
TERT-BUTYL N,N-DIALLYLCARBAMATE Preparation Products And Raw materials
Raw materials
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