TERT-BUTYL N-ALLYLCARBAMATE
- Product Name
- TERT-BUTYL N-ALLYLCARBAMATE
- CAS No.
- 78888-18-3
- Chemical Name
- TERT-BUTYL N-ALLYLCARBAMATE
- Synonyms
- tert-Butyl allylcarbamate;N-BOC-AllylaMine;N-Boc-3-aminopropene;ALLYL-CARBAMIC ACID TERT-BUTYL ESTER;ert-Butylallylcarbamate;Azacitidine Impurity 53;N-ALLYL-T-BUTYLCARBAMATE;TERT-BUTYL N-ALLYLCARBAMATE;N-Tert-Butyl-Allylcarbamate;tert-Butoxycarbonylallylamine
- CBNumber
- CB7162303
- Molecular Formula
- C8H15NO2
- Formula Weight
- 157.21
- MOL File
- 78888-18-3.mol
TERT-BUTYL N-ALLYLCARBAMATE Property
- Melting point:
- 36-38 °C (lit.)
- Boiling point:
- 48-50°C/0.3mm
- Density
- 0.938 g/mL at 25 °C (lit.)
- refractive index
- 1.4720 (estimate)
- Flash point:
- 175 °F
- storage temp.
- Inert atmosphere,Room Temperature
- pka
- 12.60±0.46(Predicted)
- form
- Low Melting Solid
- color
- Colorless
- Water Solubility
- Insoluble in water. Soluble in methanol.
- InChI
- InChI=1S/C8H15NO2/c1-5-6-9-7(10)11-8(2,3)4/h5H,1,6H2,2-4H3,(H,9,10)
- InChIKey
- AWARHXCROCWEAK-UHFFFAOYSA-N
- SMILES
- C(OC(C)(C)C)(=O)NCC=C
Safety
- Hazard Codes
- Xi,Xn
- Risk Statements
- 22-36/37/38
- Safety Statements
- 22-26-36/37/39
- RIDADR
- UN 1325 4.1/PG 2
- WGK Germany
- 3
- HazardClass
- IRRITANT
- HS Code
- 29241990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H411Toxic to aquatic life with long lasting effects
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P273Avoid release to the environment.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P391Collect spillage. Hazardous to the aquatic environment
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- 422339
- Product name
- tert-Butyl N-allylcarbamate
- Purity
- 98%
- Packaging
- 10g
- Price
- $92.9
- Updated
- 2023/06/20
- Product number
- 422339
- Product name
- tert-Butyl N-allylcarbamate
- Purity
- 98%
- Packaging
- 50g
- Price
- $324
- Updated
- 2023/06/20
- Product number
- B3618
- Product name
- tert-Butyl N-Allylcarbamate
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $36
- Updated
- 2025/07/31
- Product number
- B3618
- Product name
- tert-Butyl N-Allylcarbamate
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $144
- Updated
- 2025/07/31
- Product number
- B415193
- Product name
- tert-ButylAllylcarbamate
- Packaging
- 2.5g
- Price
- $75
- Updated
- 2021/12/16
TERT-BUTYL N-ALLYLCARBAMATE Chemical Properties,Usage,Production
Chemical Properties
white solid crystalline
Uses
tert-Butyl N-allylcarbamate is used in the synthesis of isoxazolidines. Synthesis of 5-substituted thiazolidin-2-ones is from the reaction of xanthates and tert-butyl N-allylcarbamates .
Synthesis
24424-99-5
107-11-9
78888-18-3
The synthesis of tert-butyl N-allylcarbamate was carried out as follows: 1. 2.3 mL (30 mmol, 1 eq.) of freshly distilled allylamine was dissolved in 10 mL of dichloromethane (CH2Cl2) in an ice bath (0 °C). 2. 6.54 g (30 mmol, 1 eq.) of di-tert-butyl dicarbonate (Boc2O) dissolved in 20 mL of dichloromethane was slowly added to the above cooled allylamine solution. 3. The reaction mixture was gradually warmed to room temperature with continuous stirring for 4 hours. 4. Upon completion of the reaction, the reaction mixture was diluted with additional dichloromethane and washed sequentially with 5% citric acid solution and brine. 5. The organic layer was separated and dried over anhydrous sodium sulfate (Na2SO4) and subsequently concentrated under vacuum to afford 3.29 g (68% yield) of the target product tert-butyl N-allylcarbamate. Product characterization data: 1H NMR (500 MHz, CDCl3) δ 1.38 (s, 9H), 3.68 (brs, 2H), 4.53 (brs, 1H), 5.02-5.16 (m, 2H), 5.72-5.84 (m, 1H).
References
[1] Tetrahedron Letters, 2007, vol. 48, # 35, p. 6163 - 6166
[2] Angewandte Chemie - International Edition, 2014, vol. 53, # 41, p. 11075 - 11078
[3] Tetrahedron Letters, 1998, vol. 39, # 15, p. 2099 - 2102
[4] Journal of the Chemical Society. Perkin Transactions 1, 2001, # 16, p. 1916 - 1928
[5] Tetrahedron Letters, 2009, vol. 50, # 46, p. 6244 - 6246
TERT-BUTYL N-ALLYLCARBAMATE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from TERT-BUTYL N-ALLYLCARBAMATE manufacturers
- Product
- TERT-BUTYL N-ALLYLCARBAMATE 78888-18-3
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 1kg-1000kg
- Release date
- 2020-01-03