TERT-BUTOXY ACETIC ACID
- Product Name
- TERT-BUTOXY ACETIC ACID
- CAS No.
- 13211-32-0
- Chemical Name
- TERT-BUTOXY ACETIC ACID
- Synonyms
- 2-tert-Butoxyacetic;TERT-BUTOXY ACETIC ACID;2-(tert-Butoxy)aceticaci;2-TERT-BUTOXYACETIC ACID;(tert-Butoxy)ethanoic acid;O-TERT-BUTYL-GLYCOLLIC ACID;2-TERTIARY-BUTOXYACETIC ACID;2-(1,1-Dimethylethoxy)acetic acid;Acetic acid,2-(1,1-dimethylethoxy)-;2-[(2-methylpropan-2-yl)oxy]acetic acid
- CBNumber
- CB1384879
- Molecular Formula
- C6H12O3
- Formula Weight
- 132.16
- MOL File
- 13211-32-0.mol
TERT-BUTOXY ACETIC ACID Property
- Melting point:
- -5 °C
- Boiling point:
- 104-106 °C(Press: 12 Torr)
- Density
- 1.027±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- form
- solid
- pka
- 3.55±0.10(Predicted)
- color
- Light yellow part liquid/part
- InChI
- InChI=1S/C6H12O3/c1-6(2,3)9-4-5(7)8/h4H2,1-3H3,(H,7,8)
- InChIKey
- HQLILHPGWSURBT-UHFFFAOYSA-N
- SMILES
- C(O)(=O)COC(C)(C)C
- CAS DataBase Reference
- 13211-32-0(CAS DataBase Reference)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36/37/39
- HazardClass
- IRRITANT
- HS Code
- 2918999090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H272May intensify fire; oxidizer
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P220Keep/Store away from clothing/…/combustible materials.
P221Take any precaution to avoid mixing with combustibles/…
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P337+P313IF eye irritation persists: Get medical advice/attention.
P370+P378In case of fire: Use … for extinction.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- T135550
- Product name
- tert-ButoxyAceticAcid
- Packaging
- 50mg
- Price
- $60
- Updated
- 2021/12/16
- Product number
- FB145750
- Product name
- tert-Butoxyacetic acid
- Packaging
- 2g
- Price
- $75
- Updated
- 2021/12/16
- Product number
- Z4086
- Product name
- 2-(tert-Butoxy)aceticacid
- Packaging
- 5g
- Price
- $109
- Updated
- 2021/12/16
- Product number
- FB145750
- Product name
- tert-Butoxyacetic acid
- Packaging
- 5G
- Price
- $120
- Updated
- 2021/12/16
- Product number
- 012582
- Product name
- tert-Butoxy acetic acid
- Purity
- 97%
- Packaging
- 1g
- Price
- $14
- Updated
- 2021/12/16
TERT-BUTOXY ACETIC ACID Chemical Properties,Usage,Production
Synthesis Reference(s)
Tetrahedron Letters, 24, p. 3165, 1983 DOI: 10.1016/S0040-4039(00)88125-3
Synthesis
865-47-4
79-11-8
13211-32-0
Chloroacetic acid (100 g, 1058.2 mmol) was added slowly and dropwise to a suspension containing tert-butanol (1300 mL) and potassium tert-butanolate (262 g, 2335 mmol) at 30-50 °C. The reaction mixture was heated to 80-85 °C and maintained at this temperature for 6-8 hours. Upon completion of the reaction, it was cooled to 30-45 °C, water (200 mL) was added and subsequently concentrated under reduced pressure. Water (800 mL) was again added at 20-35 °C and washed with methyl tert-butyl ether (MTBE). The pH of the aqueous phase was adjusted to 1.5-3.0 using 4N sulfuric acid solution, after which the product was extracted with MTBE. The organic phase was washed with aqueous sodium chloride solution and the organic phase was concentrated under reduced pressure to give tert-butoxyacetic acid (CTOX) as a liquid product (yield 62.9%; GC purity = 99.38%).1H NMR (400 MHz, CDCl3): δ 7.267 (s, 1H), 4.029 (s, 2H), 1.271 (s, 9H).
References
[1] Patent: WO2017/201179, 2017, A1. Location in patent: Page/Page column 24
TERT-BUTOXY ACETIC ACID Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from TERT-BUTOXY ACETIC ACID manufacturers
- Product
- TERT-BUTOXY ACETIC ACID 13211-32-0
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1ton
- Release date
- 2022-10-14
- Product
- TERT-BUTOXY ACETIC ACID 13211-32-0
- Price
- US $0.00/g
- Min. Order
- 1g
- Purity
- 95%min
- Supply Ability
- 20kg/month
- Release date
- 2019-11-19
- Product
- TERT-BUTOXY ACETIC ACID 13211-32-0
- Price
- US $2058.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 50kg
- Release date
- 2018-08-13