ChemicalBook > CAS DataBase List > TERT-BUTOXY ACETIC ACID

TERT-BUTOXY ACETIC ACID

Product Name
TERT-BUTOXY ACETIC ACID
CAS No.
13211-32-0
Chemical Name
TERT-BUTOXY ACETIC ACID
Synonyms
2-tert-Butoxyacetic;TERT-BUTOXY ACETIC ACID;2-(tert-Butoxy)aceticaci;2-TERT-BUTOXYACETIC ACID;(tert-Butoxy)ethanoic acid;O-TERT-BUTYL-GLYCOLLIC ACID;2-TERTIARY-BUTOXYACETIC ACID;2-(1,1-Dimethylethoxy)acetic acid;Acetic acid,2-(1,1-dimethylethoxy)-;2-[(2-methylpropan-2-yl)oxy]acetic acid
CBNumber
CB1384879
Molecular Formula
C6H12O3
Formula Weight
132.16
MOL File
13211-32-0.mol
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TERT-BUTOXY ACETIC ACID Property

Melting point:
-5 °C
Boiling point:
104-106 °C(Press: 12 Torr)
Density 
1.027±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
form 
solid
pka
3.55±0.10(Predicted)
color 
Light yellow part liquid/part
InChI
InChI=1S/C6H12O3/c1-6(2,3)9-4-5(7)8/h4H2,1-3H3,(H,7,8)
InChIKey
HQLILHPGWSURBT-UHFFFAOYSA-N
SMILES
C(O)(=O)COC(C)(C)C
CAS DataBase Reference
13211-32-0(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
HazardClass 
IRRITANT
HS Code 
2918999090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H272May intensify fire; oxidizer

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P220Keep/Store away from clothing/…/combustible materials.

P221Take any precaution to avoid mixing with combustibles/…

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P370+P378In case of fire: Use … for extinction.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
T135550
Product name
tert-ButoxyAceticAcid
Packaging
50mg
Price
$60
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB145750
Product name
tert-Butoxyacetic acid
Packaging
2g
Price
$75
Updated
2021/12/16
AK Scientific
Product number
Z4086
Product name
2-(tert-Butoxy)aceticacid
Packaging
5g
Price
$109
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB145750
Product name
tert-Butoxyacetic acid
Packaging
5G
Price
$120
Updated
2021/12/16
Matrix Scientific
Product number
012582
Product name
tert-Butoxy acetic acid
Purity
97%
Packaging
1g
Price
$14
Updated
2021/12/16
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TERT-BUTOXY ACETIC ACID Chemical Properties,Usage,Production

Synthesis Reference(s)

Tetrahedron Letters, 24, p. 3165, 1983 DOI: 10.1016/S0040-4039(00)88125-3

Synthesis

865-47-4

79-11-8

13211-32-0

Chloroacetic acid (100 g, 1058.2 mmol) was added slowly and dropwise to a suspension containing tert-butanol (1300 mL) and potassium tert-butanolate (262 g, 2335 mmol) at 30-50 °C. The reaction mixture was heated to 80-85 °C and maintained at this temperature for 6-8 hours. Upon completion of the reaction, it was cooled to 30-45 °C, water (200 mL) was added and subsequently concentrated under reduced pressure. Water (800 mL) was again added at 20-35 °C and washed with methyl tert-butyl ether (MTBE). The pH of the aqueous phase was adjusted to 1.5-3.0 using 4N sulfuric acid solution, after which the product was extracted with MTBE. The organic phase was washed with aqueous sodium chloride solution and the organic phase was concentrated under reduced pressure to give tert-butoxyacetic acid (CTOX) as a liquid product (yield 62.9%; GC purity = 99.38%).1H NMR (400 MHz, CDCl3): δ 7.267 (s, 1H), 4.029 (s, 2H), 1.271 (s, 9H).

References

[1] Patent: WO2017/201179, 2017, A1. Location in patent: Page/Page column 24

TERT-BUTOXY ACETIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from TERT-BUTOXY ACETIC ACID manufacturers

Henan Aochuang Chemical Co.,Ltd.
Product
TERT-BUTOXY ACETIC ACID 13211-32-0
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1ton
Release date
2022-10-14
Nanjing jinheyou Trading Co., Ltd.
Product
TERT-BUTOXY ACETIC ACID 13211-32-0
Price
US $0.00/g
Min. Order
1g
Purity
95%min
Supply Ability
20kg/month
Release date
2019-11-19
Career Henan Chemical Co
Product
TERT-BUTOXY ACETIC ACID 13211-32-0
Price
US $2058.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50kg
Release date
2018-08-13

13211-32-0, TERT-BUTOXY ACETIC ACIDRelated Search:

TERT-BUTYL VINYL ETHER 2-tert-Butyl-1,4-benzoquinone TERT-BUTYL PROPIOLATE tert-Butyl carbamate BOC-BETA-TBU-D-ALA-OH 4-(Aminocarbonyl)-N-[(1,1-dimethylethoxy)carbonyl]-2,6-dimethyl-L-phenylalanine (BOC-AMINOOXY)ACETIC ACID Boc-L-aspartic acid 4-tert-butyl ester BOC-D-ALPHA-T-BUTYLGLYCINE Boc-D-aspartic acid 4-benzyl ester TERT-BUTYL N-ALLYLCARBAMATE BOC-ALA-GLY-OH 3,3-Dimethylbutyryl chloride TERT-BUTOXY ACETIC ACID Azadirachtin BUTOPYRONOXYL ACIFRAN 3,4-DIHYDRO-2,2-DIMETHYL-4-OXO-2H-PYRAN-6-CARBOXYLIC ACID

  • Acetic acid,2-(1,1-dimethylethoxy)-
  • O-TERT-BUTYL-GLYCOLLIC ACID
  • TERT-BUTOXY ACETIC ACID
  • 2-TERT-BUTOXYACETIC ACID
  • 2-TERTIARY-BUTOXYACETIC ACID
  • 2-tert-Butoxyacetic
  • (tert-Butoxy)ethanoic acid
  • 2-[(2-methylpropan-2-yl)oxy]acetic acid
  • 2-(tert-Butoxy)aceticaci
  • 2-(1,1-Dimethylethoxy)acetic acid
  • 13211-32-0
  • Small molecule