ChemicalBook > CAS DataBase List > Rhodiumtriphenylacetate
Rhodiumtriphenylacetate
- Product Name
- Rhodiumtriphenylacetate
- CAS No.
- 142214-04-8
- Chemical Name
- Rhodiumtriphenylacetate
- Synonyms
- Rh2(TPA)4;Rh2(triphenylacetate)4;oromethane Adduct;DichloroMethane Adduct;Rhodiumtriphenylacetate;acetato)dirhodium(II) DichL;Rhodium(II) triphenyl acetate;Rh2(TPA)4 Dichloromethane Adduct;Rhodium(II)triphenylacetate dimer;Rhodium(3+) tris(triphenylacetate)
- CBNumber
- CB41073999
- Molecular Formula
- C60H45O6Rh
- Formula Weight
- 964.9012
- MOL File
- 142214-04-8.mol
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Rhodiumtriphenylacetate Property
- Melting point:
- 260-263°C
- storage temp.
- Inert atmosphere,Room Temperature
- form
- powder to crystal
- color
- Green to Dark green
- InChI
- InChI=1S/3C20H16O2.Rh/c3*21-19(22)20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h3*1-15H,(H,21,22);/q;;;+3/p-3
- InChIKey
- LJIVYHNRWSWCRU-UHFFFAOYSA-K
- SMILES
- [Rh+3].C([O-])(=O)C(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.C([O-])(=O)C(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.C([O-])(=O)C(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1
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Safety
- Hazard Codes
- Xn
- Risk Statements
- 40
- Safety Statements
- 23-24/25-36/37
- WGK Germany
- 2
- HS Code
- 2931.90.6000
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H351Suspected of causing cancer
- Precautionary statements
-
P201Obtain special instructions before use.
P202Do not handle until all safety precautions have been read and understood.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P308+P313IF exposed or concerned: Get medical advice/attention.
P405Store locked up.
P501Dispose of contents/container to..…
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 725455
- Product name
- Rhodium(II) triphenylacetate dimer
- Purity
- as complex with dichloromethane
- Packaging
- 100mg
- Price
- $135
- Updated
- 2025/07/31
TCI Chemical
- Product number
- T1544
- Product name
- Tetrakis(triphenylacetato)dirhodium(II) Dichloromethane Adduct
- Packaging
- 100mg
- Price
- $117
- Updated
- 2025/07/31
TRC
- Product number
- B130388
- Product name
- Tetrakis(triphenylacetato)dirhodium(II) Dichloromethane Adduct
- Packaging
- 5mg
- Price
- $45
- Updated
- 2021/12/16
TRC
- Product number
- B130388
- Product name
- Tetrakis(triphenylacetato)dirhodium(II) Dichloromethane Adduct
- Packaging
- 25mg
- Price
- $130
- Updated
- 2021/12/16
Chem-Impex
- Product number
- 40675
- Product name
- Tetrakis(triphenylacetato)dirhodium(II)dichloromethaneadduct,88-105%(Assaybytitration)
- Purity
- 88-105%(Assaybytitration)
- Packaging
- 100MG
- Price
- $152.32
- Updated
- 2021/12/16
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Rhodiumtriphenylacetate Chemical Properties,Usage,Production
Uses
Catalyst for:
- Amination of allene carbamates
- Allene aziridination to stereoselectively prepare cyclic cabamates
- C-H bond nitrene insertion
- Enantioselective cyclopropanation
- Preparation of cyclic oxonium ylides
reaction suitability
core: rhodium
reagent type: catalyst
reaction type: C-H Activation
Rhodiumtriphenylacetate Preparation Products And Raw materials
Raw materials
Preparation Products
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