Methyl 1H-pyrrole-3-carboxylate

Product Name: Methyl 1H-pyrrole-3-carboxylate
CAS No.: 2703-17-5
Chemical Name: Methyl 1H-pyrrole-3-carboxylate
Synonyms: Methyl Pyrrole-3-carboxylate;EOS-61577;Methyl 3-pyrrolecarboxylate;Methyl1H-pyrrole-3-carboxylat;3-(Methoxycarbonyl)-1H-pyrrole;Methyl 1H-pyrrole-3-carboxylate;Methyl 1H-pyrrole-3-carboxylate, 95+%;Pyrrole-3-carboxylic acid methyl ester;1,1-dibromo-2-(chloromethyl)cyclopropane;1H-Pyrrole-3-carboxylic acid methyl ester
CBNumber: CB41086094
Molecular Formula: C6H7NO2
Formula Weight: 125.13
MOL File: 2703-17-5.mol

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Methyl 1H-pyrrole-3-carboxylate Property

Melting point:: 85-89 °C
Boiling point:: 284℃
Density: 1.184
Flash point:: 126℃
storage temp.: Inert atmosphere,Room Temperature
form: solid
pka: 15.42±0.50(Predicted)
color: Off-white to light yellow
Water Solubility: Slightly soluble in water.
InChI: InChI=1S/C6H7NO2/c1-9-6(8)5-2-3-7-4-5/h2-4,7H,1H3
InChIKey: WLBNVSIQCFHAQB-UHFFFAOYSA-N
SMILES: N1C=CC(C(OC)=O)=C1

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Safety

Risk Statements: 36/37/38
Safety Statements: 26-37-60
WGK Germany: 3
HS Code: 29339900

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 685399
Product name: Methyl 1H-pyrrole-3-carboxylate
Purity: 97%
Packaging: 1g
Price: $72.6
Updated: 2024/03/01

Sigma-Aldrich

Product number: 685399
Product name: Methyl 1H-pyrrole-3-carboxylate
Purity: 97%
Packaging: 250mg
Price: $63.8
Updated: 2023/06/20

Alfa Aesar

Product number: H54340
Product name: Methyl pyrrole-3-carboxylate, 97%
Packaging: 1g
Price: $118.65
Updated: 2024/03/01

Alfa Aesar

Product number: H54340
Product name: Methyl pyrrole-3-carboxylate, 97%
Packaging: 5g
Price: $463.65
Updated: 2024/03/01

Alfa Aesar

Product number: H54340
Product name: Methyl pyrrole-3-carboxylate, 97%
Packaging: 250mg
Price: $37
Updated: 2021/12/16

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Methyl 1H-pyrrole-3-carboxylate Chemical Properties,Usage,Production

Uses

Methyl pyrrole-3-carboxylate is used as an organic chemical synthesis intermediate.

Application

A solution of methyl 1H-pyrrole-3-carboxylate (4.48 g, 35.8 mmol) in THF (70 mL) was cooled to -78 °C, N-bromosuccinimide (6.30 g, 35.4 mmol) was added, pyridine (five drops) was added, and the mixture was left standing in a freezer (-20 °C) for 3 days. The reaction mixture was concentrated under reduced pressure. Water was added to the residue, and the mixture was extracted using EtOAc. The extract was washed with brine, dried over Na2SO4, and concentrated under reduced pressure. The residue was purified by silica gel column chromatography (hexane-EtOAc = 9/1-1/1) to give Methyl 5-bromo-1H-pyrrole-3-carboxylate (3.59 g, 49percent) as a pale-yellow solid.

Research

Pyrrole and Methyl 1H-Pyrrole-3-Carboxylate could be used to prepare the Soft Actuators by Electrochemical Copolymerization. In specific, a counter electrode (Ti), a reference electrode (Ag/AgCl), and a working electrode (Ti) were immersed into methyl benzoate solutions of 0.25 M of pyrrole and methyl 1-H pyrrole-3-carboxylate with 100:0, 98:2, 95:5, 80:20 mol ratios and 0.2 M N, N-diethyl-N-methyl-N-(2-methoxyethyl)ammonium bis(trifluoromethanesulfonyl) imide. The thickness of the prepared films was measured to be approximately 100 μm using a micrometer. The PPy actuator was used as the working electrode in the 1 M LiTFSI aqueous electrolyte solutions. The Py copolymer film, fabricated from pyrrole solution containing 2 and 5 mol% of methyl 1-H pyrrole-3-carboxylate, showed a reduced actuating strain of approximately 2%, but the creep strain was reduced to less than 1%[1].

References

[1] Yamasaki, Jun et al. “Soft Actuators Prepared by Electrochemical Copolymerization of Pyrrole and Methyl 1H-Pyrrole-3-Carboxylate.” 2013. 0.

Methyl 1H-pyrrole-3-carboxylate Preparation Products And Raw materials

Raw materials

Preparation Products

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Methyl 1H-pyrrole-3-carboxylate Suppliers

China 131 Europe 1 India 2 Switzerland 2 United Kingdom 2 United States 15 Global 153

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View Lastest Price from Methyl 1H-pyrrole-3-carboxylate manufacturers

Career Henan Chemical Co

Product: 1H-Pyrrole-3-carboxylic acid, methyl ester (9CI) 2703-17-5
Price: US $8.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10tons
Release date: 2018-12-25

2703-17-5, Methyl 1H-pyrrole-3-carboxylateRelated Search:

Pyrrole-2-carboxaldehyde PYRROLIDINE-3-CARBOXYLIC ACID TERT-BUTYL ESTER 4-(Ethoxycarbonyl)-3,5-dimethyl-1H-pyrrole-2-carboxylic acid ETHYL 4-METHYLPYRROLE-3-CARBOXYLATE 2-METHYL-1H-PYRROLE-3-CARBOXYLIC ACID ETHYL ESTER AKOS B006681 Diethyl 2,4-dimethylpyrrole-3,5-dicarboxylate Ethyl 5-formyl-2,4-dimethyl-1H-pyrrole-3-carboxylate Ethyl2,5-dimethylpyrrole-3-carboxylate 4-ETHOXYCARBONYL-3-METHYL PYRROL-2-CARBOXYLIC ACID 4-BENZYL 2-ETHYL 3-(2-ETHOXY-2-OXOETHYL)-5-METHYL-1H-PYRROLE-2,4-DICARBOXYLATE 5-FORMYL-3-METHYL-1H-PYRROLE-2,4-DICARBOXYLIC ACID DIETHYL ESTER ETHYL-1-BENZYL-2,4-DIMETHYLPYRROLE-3-CARBOXYLATE ETHYL 5-HYDROXY-2-METHYLINDOLE-3-CARBOXYLATE DIMETHYL INDOLE-2,3-DICARBOXYLATE 3-METHYL-1H-PYRROLE 2,4-DICARBOXYLIC ACID DIETHYL ESTER RARECHEM AL BI 0942 5-BROMOMETHYL-3-METHYL-1H-PYRROLE-2,4-DICARBOXYLIC ACID DIETHYL ESTER

1H-Pyrrole-3-carboxylic acid, methyl ester (9CI)

Methyl 1H-pyrrole-3-carboxylate

Methyl1H-pyrrole-3-carboxylat

Methyl 1H-pyrrole-3-carboxylate, 95+%

1H-Pyrrole-3-carboxylic acid methyl ester

Methyl Pyrrole-3-carboxylate

3-(Methoxycarbonyl)-1H-pyrrole

Methyl 3-pyrrolecarboxylate

Pyrrole-3-carboxylic acid methyl ester

EOS-61577

1,1-dibromo-2-(chloromethyl)cyclopropane

methyl 1H-pyrrole-3-carboxylate 1kg 3kg 5kg

2703-17-5

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Heterocyclic Building Blocks

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ACIDHALIDE