1,2-Bis(bromomethyl)benzene

Product Name: 1,2-Bis(bromomethyl)benzene
CAS No.: 91-13-4
Chemical Name: 1,2-Bis(bromomethyl)benzene
Synonyms: O-XYLENE DIBROMIDE;O-XYLYLENE DIBROMIDE;α,α’-dibromo-o-xylene;O-XYLYLENE BROMIDE;O-Xylyene dibromide;O-XYLIDENE DIBROMIDE;a,a'-Dibromo-o-xylol;1,2-dibenzyl bromide;1,2-Bis(bromomethyl);à,à'-dibromo-o-xylene
CBNumber: CB4129349
Molecular Formula: C8H8Br2
Formula Weight: 263.96
MOL File: 91-13-4.mol

More

Less

1,2-Bis(bromomethyl)benzene Property

Melting point:: 91-94 °C(lit.)
Boiling point:: 140 °C / 20mmHg
Density: 1.96 g/mL at 25 °C(lit.)
refractive index: 1.6113 (estimate)
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
solubility: sol ethanol, ether, chloroform; slightly sol petroleum ether.
form: Crystals or Crystalline Powder
color: White to light cream
Water Solubility: soluble, hydrolyses
BRN: 637159
InChIKey: KGKAYWMGPDWLQZ-UHFFFAOYSA-N
CAS DataBase Reference: 91-13-4(CAS DataBase Reference)
NIST Chemistry Reference: Benzene, 1,2-bis(bromomethyl)-(91-13-4)
EPA Substance Registry System: Benzene, 1,2-bis(bromomethyl)- (91-13-4)

More

Less

Safety

Hazard Codes: C
Risk Statements: 22-34
Safety Statements: 26-36/37/39-45
RIDADR: UN 3448 6.1/PG 2
WGK Germany: 2
F: 8-19-21
TSCA: Yes
HazardClass: 8
PackingGroup: III
HS Code: 29036990

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: D44405
Product name: α,α′-Dibromo-o-xylene
Purity: 97%
Packaging: 25g
Price: $127
Updated: 2024/03/01

Sigma-Aldrich

Product number: D44405
Product name: α,α′-Dibromo-o-xylene
Purity: 97%
Packaging: 100g
Price: $177
Updated: 2024/03/01

TCI Chemical

Product number: D0214
Product name: α,α'-Dibromo-o-xylene
Packaging: 25G
Price: $69
Updated: 2024/03/01

TCI Chemical

Product number: D0214
Product name: α,α'-Dibromo-o-xylene
Packaging: 100G
Price: $216
Updated: 2024/03/01

Alfa Aesar

Product number: A17241
Product name: o-Xylylene dibromide, 97%
Packaging: 5g
Price: $21.65
Updated: 2024/03/01

More

Less

1,2-Bis(bromomethyl)benzene Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powde

Uses

1,2-Bis(bromomethyl)benzene is used in the synthesis of isothioureas involved in the inhibition of human nitric oxide synthases. Also used in the synthesis of tridentate carbene ligands.

Application

1,2-Bis(bromomethyl)benzene (α,α′-Dibromo-o-xylene) is a source of o-quinodimethane, a highly reactive diene useful in Diels-Alder reactions; an electrophile for the synthesis of carbo- and heterocyclic compounds including macrocycles (cyclophanes, crown ethers, hemispherands, spherands), cryptands, hemicarcerands, vaulted cappedophanes, bicyclic compounds, spirocyclic compounds; a protective group reagent for diols.

storage

1,2-Bis(bromomethyl)benzene should be avoided moisture; corrosive (forms HBr on hydrolysis); lachrymator; not mutagenic in Ames test; decontaminate by soaking apparatus, etc. in alcoholic alkali for 24 h or longer.

Purification Methods

Crystallise it from CHCl3 or pet ether, and/or distil it under vacuum. [Wenner Org Chem 17 527 1952, Beilstein 5 H 366, 5 I 180, 5 II 285, 5 III 819, 5 IV 929.]

1,2-Bis(bromomethyl)benzene Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

1,2-Bis(bromomethyl)benzene Suppliers

Americas 1 Belgium 3 China 186 Europe 3 France 2 Germany 7 India 7 Japan 5 Slovakia 1 South Korea 1 Switzerland 4 Ukraine 2 United Kingdom 17 United States 39 Global 278

Creasyn Finechem(Tianjin) Co., Ltd.

Tel: 022-83946278 13820503911
Fax: 022-83945176
Email: sales@creasyn.com
Country: China
ProdList: 997
Advantage: 68

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

TAIYUAN RHF CO.,LTD.

Tel: +86 351 7031519
Fax: +86 351 7031519
Email: sales@RHFChem.com
Country: China
ProdList: 2338
Advantage: 56

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24529
Advantage: 81

ChangShu Haitian Fine Chemicals Co.,Ltd

Tel: 13913622609
Fax: 86-512-52893680
Email: sales@haitianchem.cn
Country: China
ProdList: 192
Advantage: 61

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44689
Advantage: 61

Capot Chemical Co., Ltd

Tel: +86 (0) 571 85 58 67 18
Fax: 0086-571-85864795
Email: sales@capotchem.com
Country: China
ProdList: 18207
Advantage: 66

Beijing Ouhe Technology Co., Ltd

Tel: 010-82967028 13552068683
Fax: +86-10-82967029
Email: 2355560935@qq.com
Country: China
ProdList: 12390
Advantage: 60

JinYan Chemicals(ShangHai) Co.,Ltd.

Tel: 13817811078
Fax: 86-021-50426522,50426273
Email: sales@jingyan-chemical.com
Country: China
ProdList: 9976
Advantage: 60

More

Less

View Lastest Price from 1,2-Bis(bromomethyl)benzene manufacturers

Henan Fengda Chemical Co., Ltd

Product: 1,2-Bis(bromomethyl)benzene 91-13-4
Price: US $32.00-1.30/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2024-04-15

Honest Joy Holdings Limited

Product: O-Xylylene dibromide 91-13-4
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98.5%
Supply Ability: 100 tons
Release date: 2022-02-18

Career Henan Chemical Co

Product: 1,2-Bis(bromomethyl)benzene 91-13-4
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 25kg
Release date: 2019-07-12

91-13-4, 1,2-Bis(bromomethyl)benzeneRelated Search:

1,2-Dibromoethane Musk xylene Ethylbenzene Allylbenzene Diethylstilbestrol BROMOPENTAMETHYLBENZENE Decabromodiphenyl Ethane Benzyl bromide XYLENE CYANOL FF Benzene Bromodiphenylmethane 4-BROMO-2,2-DIPHENYLBUTYRONITRILE Methyl 4-(bromomethyl)benzoate Xylene ALPHA,ALPHA,ALPHA',ALPHA'-TETRABROMO-O-XYLENE HEXAKIS(BROMOMETHYL)BENZENE 2-Methoxy-5-(2-ethylhexyloxy)-1,4-bis(bromomethyl)benzene 1,2,4,5-TETRAKIS(BROMOMETHYL)BENZENE

O-XYLENE DIBROMIDE

O-XYLYLENE DIBROMIDE

O-XYLIDENE DIBROMIDE

O-XYLYLENE DIBROMIDE 97%

o-Xylylenedibromide,97%

à,à'-dibromo-o-xylene

1,2-dibenzyl bromide

1,2-Bis(bromomethyl)benzene, o-Xylylene dibromide

-(Bromomethyl)benzyl bromide

2-(Bromomethyl)benzyl bromide

a,a'-Dibromo-o-xylol

1,2-Bis(bromomethyl)benzene 1,2-Bis(bromomethyl)benzene ,97%

1,2-Phenylenebis(bromomethane)

alpha,alpha'-Dibromo-o-xylene,96%

1,2-Bis(bromomethyl)benzene ,97%

1,2-Bis(bromomethyl)

alpha'-DibroMo-o-xylene

o-Xylylene Bromide o-Xylylene Dibromide 1,2-Bis(bromomethyl)benzene

alpha,alpha'-DibroMo-o-xylene 97%

<i>α</i>,<i>α</i>'-Dibromo-o-xylene

O-Xylyene dibromide

1,2-Bis(bromomethyl)-benzene for synthesis

O-XYLYLENE BROMIDE

A,A'-DIBROMO-O-XYLENE

ALPHA,ALPHA'-DIBROMO-2-XYLENE

ALPHA,ALPHA'-DIBROMO-O-XYLENE

ALPHA,ALPHA-DIBROMO-O-XYLENE

1,2-BIS(BROMOMETHYL)BENZENE

1,2-bis(bromomethyl)-benzen

alpha,alpha '-Dibromo-ortho-xylene

alpha,alpha'-Dibromo-o-xylol

benzene,1,2-bis(bromomethyl)-

o-(Bromomethyl)benzyl bromide

o-Bis(bromomethyl)benzene

o-Xylene, alpha,alpha'-dibromo-

α,α’-dibromo-o-xylene

1,2-Bis(bromomethyl)benzene~alpha,alpha-Dibromo-o-xylene

α,α'-Dibromo-o-xylene &gt

α，α'-Dibromo-o-xylene

1,2-Bis(bromomethyl)benzene USP/EP/BP

Alpha,Alpha'-Dibromo-o-xylene

α,α'-Dibromo-o-xylene

91-13-4

HALOGEN

Aryl

C8

Building Blocks

Organic Building Blocks

Halogenated Hydrocarbons

Aryl

Building Blocks

C8

Chemical Synthesis

Halogenated Hydrocarbons

Organic Building Blocks

Aromatic Halides (substituted)