1,2,4,5-TETRAKIS(BROMOMETHYL)BENZENE

Product Name: 1,2,4,5-TETRAKIS(BROMOMETHYL)BENZENE
CAS No.: 15442-91-8
Chemical Name: 1,2,4,5-TETRAKIS(BROMOMETHYL)BENZENE
Synonyms: TETRABROMODURENE;1,2,4,5-Tetrakis(bromomethyL;5-TETRAKIS(BROMOMETHYL)BENZENE;1,2,4,5-TETRA[BROMOMETHYL]BENZENE;1,2,4,5-TETRAKIS(BROMOMETHYL)BENZENE;Benzene,1,2,4,5-tetrakis(broMoMethyl)-;1,2,4,5-Tetrakis(bromomethyl)benzene 95%;1,2,4,5-Tetrakis(bromomethyl)benzene,98%;1,2,4,5-TETRAKIS(BROMOMETHYL)BENZENE, 95 %;1,2,4,5-Tetrakis(broMoMethyl)benzene, 95% 25GR
CBNumber: CB7452862
Molecular Formula: C10H10Br4
Formula Weight: 449.8
MOL File: 15442-91-8.mol

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1,2,4,5-TETRAKIS(BROMOMETHYL)BENZENE Property

Melting point:: 159-161 °C(lit.)
Boiling point:: 326.93°C (rough estimate)
Density: 2.168
refractive index: 1.7040 (estimate)
storage temp.: Refrigerator, under inert atmosphere
solubility: Chloroform (Slightly), Dichloromethane (Slightly), Methanol (Slightly)
form: Crystalline Powder
color: Off-white to light yellow
InChI: 1S/C10H10Br4/c11-3-7-1-8(4-12)10(6-14)2-9(7)5-13/h1-2H,3-6H2
InChIKey: UTXIKCCNBUIWPT-UHFFFAOYSA-N
SMILES: BrCc1cc(CBr)c(CBr)cc1CBr
CAS DataBase Reference: 15442-91-8(CAS DataBase Reference)

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Safety

Hazard Codes: C
Risk Statements: 34-36/37
Safety Statements: 26-27-28-36/37/39-45
RIDADR: UN 3261 8/PG 2
WGK Germany: 3
HazardClass: 8
PackingGroup: III
HS Code: 29039990
Storage Class: 8A - Combustible corrosive hazardous materials
Hazard Classifications: Eye Dam. 1
Skin Corr. 1B
STOT SE 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

H335May cause respiratory irritation

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 236616
Product name: 1,2,4,5-Tetrakis(bromomethyl)benzene
Purity: 95%
Packaging: 5g
Price: $204.16
Updated: 2025/07/31

TCI Chemical

Product number: T3901
Product name: 1,2,4,5-Tetrakis(bromomethyl)benzene
Purity: min. 95.0 %
Packaging: 1G
Price: $60
Updated: 2025/07/31

TCI Chemical

Product number: T3901
Product name: 1,2,4,5-Tetrakis(bromomethyl)benzene
Purity: min. 95.0 %
Packaging: 5G
Price: $183
Updated: 2025/07/31

TRC

Product number: T298568
Product name: 1,2,4,5-Tetrakis(Bromomethyl)Benzene
Packaging: 500mg
Price: $125
Updated: 2021/12/16

Frontier Specialty Chemicals

Product number: JK560213
Product name: 1,2,4,5-Tetrakis(bromomethyl)benzene
Purity: 95%
Packaging: 5g
Price: $159
Updated: 2021/12/16

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1,2,4,5-TETRAKIS(BROMOMETHYL)BENZENE Chemical Properties,Usage,Production

Chemical Properties

off-white to light yellow crystalline powder

Uses

1,2,4,5-Tetrakis(bromomethyl)benzene has been used in the synthesis of:

tetrapodal imidazolium ligands as their PF₆ salts
6,7-bis(bromomethyl)-2,11,18,21,24-pentaoxatetracyclo[23.4. 0.0^4,9.0¹²,¹⁷]nonacosa-1(25),4(9),5,7,12 (17),13,15,26,28-nonaene
conformationally constrained cyclic α-amino acid derivatives
thiacyclophanes
dendrimeric organoplatinum complexes

Synthesis

95-93-2

15442-91-8

General procedure for the synthesis of tetrabromotoluene from 1,2,4,5-tetramethylbenzene: 1,2,4,5-tetrakis(bromomethyl)benzene (2.8 g, 20 mmol) was prepared by reacting 1,2,4,5-tetramethylbenzene (2.8 g, 20 mmol) with N-bromosuccinimide (NBS, 14.4 g, 80 mmol) and benzoyl peroxide in 50 mL of tetrachloromethane (1c, 1 g, 5.9 mmol). The reaction mixture was heated at 77 °C for 50 min. After completion of the reaction, the precipitate was collected by filtration under reduced pressure and washed with hot tetrachloromethane. The filtrate was concentrated to a small volume and cooled to 4 °C. The crude product was filtered and purified by recrystallization from methanol. The reaction time was less than 1 hour to give a white solid product in 15% yield with a melting point of 159-160°C. The structure of the product was determined by 1H-NMR (CDCl3, δ: 7.37 ppm, 2H, a; 4.60 ppm, 8H, b), 13C-NMR (CDCl3, δ: 137.6 ppm, a; 133.6 ppm, h; 28.7 ppm, b), and FT-IR (KBr, νmax: 3026, 2980, 2933. 1504, 1456, 1210, 911, 797, 678, 598 cm-1) were characterized.

References

[1] Journal of the Chinese Chemical Society, 2002, vol. 49, # 1, p. 77 - 82
[2] Angewandte Chemie - International Edition, 2006, vol. 45, # 26, p. 4281 - 4286
[3] Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, 1994, vol. 247, p. 23 - 30
[4] Heterocycles, 2015, vol. 90, # 1, p. 645 - 658
[5] Tetrahedron Letters, 2015, vol. 56, # 26, p. 3992 - 3995

1,2,4,5-TETRAKIS(BROMOMETHYL)BENZENE Preparation Products And Raw materials

Raw materials

Preparation Products

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1,2,4,5-TETRAKIS(BROMOMETHYL)BENZENE Suppliers

Belgium 1 China 95 Czech 1 France 1 Germany 3 India 3 Japan 1 Switzerland 1 Ukraine 1 United Kingdom 2 United States 15 Global 124

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Thermo Fisher Scientific

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View Lastest Price from 1,2,4,5-TETRAKIS(BROMOMETHYL)BENZENE manufacturers

Henan Fengda Chemical Co., Ltd

Product: 1,2,4,5-TETRAKIS(BROMOMETHYL)BENZENE 15442-91-8
Price: US $100.00-1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2023-12-26

15442-91-8, 1,2,4,5-TETRAKIS(BROMOMETHYL)BENZENERelated Search:

Biphenyl-3,3',5,5'-tetracarboxylic acid 1,2,3,4-Tetrahydronaphthalene 1,2,4-Trimethylbenzene 1,3-Bis(bromomethyl)benzene 1,3,5-Tris(bromomethyl)benzene 1,2-Bis(bromomethyl)benzene 3,7-dibromo-10H-phenothiazine alpha,alpha'-Dibromo-p-xylene 1,2,4,5-TETRAKIS(BROMOMETHYL)BENZENE 2,4-DIMETHYLBENZYL BROMIDE 1,4-BIS(BROMOMETHYL)-2,5-DIMETHYLBENZENE 2,5-DIMETHYLBENZYL BROMIDE 4-Fluorobenzyl bromide HEXAKIS(BROMOMETHYL)BENZENE 3-Methylbenzyl bromide 4-Methylbenzyl bromide 3,4-Dimethylbenzylbromide Benzyl bromide

ALPHA,ALPHA',ALPHA'',ALPHA'''-TETRABROMODURENE

1,2,4,5-TETRAKIS(BROMOMETHYL)BENZENE

1,2,4,5-TETRA[BROMOMETHYL]BENZENE

TETRABROMODURENE

1,2,4,5-TETRAKIS(BROMOMETHYL)BENZENE, 95 %

1,2,4,5-Tetrakis(bromomethyl)benzene,98%

1,2,4,5-Tetrakis(broMoMethyl)benzene, 95% 25GR

Benzene,1,2,4,5-tetrakis(broMoMethyl)-

1,2,4,5-Tetrakis(bromomethyl)benzene 95%

1,2,4,5-Tetrakis(bromomethyL

1,2,4,5-Tetrakis(bromomethyl)benzene, 95%, for synthesis

1,2,4,5-TETRAKIS(BROMOMETHYL)BENZENE ISO 9001：2015 REACH

5-TETRAKIS(BROMOMETHYL)BENZENE

15442-91-8

C10H10Br4

C6H2CH2Br4

Organic Building Blocks

Halogenated Hydrocarbons

Aryl

C9 to C12

Building Blocks

Morpholines/Thiomorpholines ,Indazoles