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3-methylcyclobutane-1-carboxylic acid

Product Name
3-methylcyclobutane-1-carboxylic acid
CAS No.
57252-83-2
Chemical Name
3-methylcyclobutane-1-carboxylic acid
Synonyms
3-Methylcyclobutanecarboxylic acid;3-Methylcyclobutylcarboxylic acid;3-methylcyclobutane-1-carboxylic acid;Cyclobutanecarboxylic acid, 3-methyl-;3-Methylcyclobutanecarboxylic acid - [M14949]
CBNumber
CB41458202
Molecular Formula
C6H10O2
Formula Weight
114.14
MOL File
57252-83-2.mol
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3-methylcyclobutane-1-carboxylic acid Property

Boiling point:
194℃
Density 
1.105
Flash point:
88℃
storage temp. 
Sealed in dry,Room Temperature
pka
4.81±0.40(Predicted)
Appearance
Colorless to light yellow Liquid
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Safety

Hazard Codes 
Xn
Risk Statements 
22-36-52
Safety Statements 
26
RIDADR 
3265
HazardClass 
8
PackingGroup 
HS Code 
2916200090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

AK Scientific
Product number
W7069
Product name
3-Methylcyclobutanecarboxylicacid
Packaging
1g
Price
$157
Updated
2021/12/16
Apolloscientific
Product number
OR926901
Product name
3-Methylcyclobutane-1-carboxylicacid
Packaging
1g
Price
$209
Updated
2021/12/16
Matrix Scientific
Product number
124399
Product name
3-Methylcyclobutanecarboxylicacid
Purity
95+%
Packaging
1g
Price
$364
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0313087
Product name
3-METHYLCYCLOBUTYLCARBOXYLIC ACID
Purity
95.00%
Packaging
5MG
Price
$501.06
Updated
2021/12/16
Apolloscientific
Product number
OR926901
Product name
3-Methylcyclobutane-1-carboxylicacid
Packaging
5g
Price
$543
Updated
2021/12/16
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3-methylcyclobutane-1-carboxylic acid Chemical Properties,Usage,Production

Uses

3-Methylcyclobutanecarboxylic acid is a reactant used in the preparation of alternating copolymers via. ring-opening metathesis polymerization (ROMP) of methylcyclobutene and dimethylcyclobutene.

Synthesis

15760-36-8

57252-83-2

General procedure for the synthesis of 3-methylenecyclobutanecarboxylic acid from 3-methylenecyclobutanecarboxylic acid: 3-methylenecyclobutanecarboxylic acid (1 g) was mixed with Pd/C catalyst (0.19 g) in methanol (20 mL) and the reaction was stirred overnight at room temperature in a hydrogen atmosphere (H2 balloon). Upon completion of the reaction, the mixture was filtered to remove the catalyst and the filtrate was concentrated under vacuum to give the target product 3-methylcyclobutyric acid (760 mg). Mass spectrometry analysis (ESI): calculated mass of C6H10O2 was 114; no corresponding mass was detected.

References

[1] Patent: WO2015/180613, 2015, A1. Location in patent: Page/Page column 20

3-methylcyclobutane-1-carboxylic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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3-methylcyclobutane-1-carboxylic acid Suppliers

PharmaBlock Sciences (Nanjing),Inc.
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China
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Chengdu AstaTech Trading Co., Ltd./AstaTech (Chengdu) Pharma. Co., Ltd.
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Modachem Shanghai Co., Ltd
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Shanghai HuanChuan Industry Co.,Ltd.
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China
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View Lastest Price from 3-methylcyclobutane-1-carboxylic acid manufacturers

Career Henan Chemica Co
Product
3-methylcyclobutane-1-carboxylic acid 57252-83-2
Price
US $1.00/g
Min. Order
1g
Purity
85.0-99.8%
Supply Ability
20ton
Release date
2020-10-28