Ethyl (6-aminopyridin-2-yl)acetate
- Product Name
- Ethyl (6-aminopyridin-2-yl)acetate
- CAS No.
- 71469-82-4
- Chemical Name
- Ethyl (6-aminopyridin-2-yl)acetate
- Synonyms
- Ethyl 2-(6-aminopyridin-2-yl);Ethyl 6-Aminopyridine-2-acetate;2-(6-aMinopyridin-2-yl)butanoate;Ethyl (6-aminopyridin-2-yl)acetate;N-(2-AMinopyriMidin-4-yl)acetaMide;ethyl2-(6-aminopyridin-2-yl)acetate;6-AMINO-2-PYRIDINEACETIC ACID ETHYL ESTER;2-Pyridineacetic acid, 6-amino-, ethyl ester;2-(6-amino-2-pyridinyl)acetic acid ethyl ester;Ethyl (6-aminopyridin-2-yl)acetate ISO 9001:2015 REACH
- CBNumber
- CB41501601
- Molecular Formula
- C9H12N2O2
- Formula Weight
- 180.2
- MOL File
- 71469-82-4.mol
Ethyl (6-aminopyridin-2-yl)acetate Property
- Boiling point:
- 298.7±25.0 °C(Predicted)
- Density
- 1.168±0.06 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2–8 °C
- pka
- 5.84±0.24(Predicted)
- Appearance
- Off-white to light yellow Solid
- InChI
- InChI=1S/C9H12N2O2/c1-2-13-9(12)6-7-4-3-5-8(10)11-7/h3-5H,2,6H2,1H3,(H2,10,11)
- InChIKey
- AJIPGVQKXQFJNX-UHFFFAOYSA-N
- SMILES
- C1(CC(OCC)=O)=NC(N)=CC=C1
Safety
- HS Code
- 2933399990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P312Call a POISON CENTER or doctor/physician if you feel unwell.
P321Specific treatment (see … on this label).
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P337+P313IF eye irritation persists: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
P403+P233Store in a well-ventilated place. Keep container tightly closed.
P405Store locked up.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- E900173
- Product name
- Ethyl2-(6-Aminopyridin-2-yl)acetate
- Packaging
- 1g
- Price
- $330
- Updated
- 2021/12/16
- Product number
- 4H58-1-609
- Product name
- Ethyl (6-aminopyridin-2-yl)acetate
- Packaging
- 1g
- Price
- $400
- Updated
- 2021/12/16
- Product number
- W8039
- Product name
- Ethyl2-(6-aminopyridin-2-yl)acetate
- Packaging
- 250mg
- Price
- $123
- Updated
- 2021/12/16
- Product number
- W8039
- Product name
- Ethyl2-(6-aminopyridin-2-yl)acetate
- Packaging
- 5g
- Price
- $610
- Updated
- 2021/12/16
- Product number
- 113965
- Product name
- Ethyl(6-aminopyridin-2-yl)acetate
- Purity
- 97%
- Packaging
- 1g
- Price
- $403
- Updated
- 2021/12/16
Ethyl (6-aminopyridin-2-yl)acetate Chemical Properties,Usage,Production
Synthesis
408365-87-7
71469-82-4
General procedure for the synthesis of ethyl (6-aminopyridin-2-yl)acetate from ethyl [6-[(tert-butoxycarbonyl)amino]-2-pyridinyl]acetate: to a solution of ethyl [6-[(tert-butoxycarbonyl)amino]-2-pyridinyl]acetate (1.38 g, 4.92 mmol) in methylene chloride (20 ml), was added a solution of dioxane in 4 M HCl (4 equiv. 19.7 mmol) and the reaction mixture was stirred at room temperature for 4 hours. Subsequently, 4 equivalents of dioxane solution of 4M HCl was added additionally and stirring was continued for 16 hours. Upon completion of the reaction, the mixture was concentrated in vacuum to afford the crude product ethyl (6-aminopyridin-2-yl)acetate (1.20 g, yield >100%, containing about 14% of the feedstock). Analysis by LC/MS showed a product purity of about 75% (MH+, m/z 181, retention time Rt=0.68 min). The resulting product does not require further purification and can be used directly in subsequent reactions.
References
[1] Patent: WO2006/50908, 2006, A1. Location in patent: Page/Page column 32; 39-40
Ethyl (6-aminopyridin-2-yl)acetate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Ethyl (6-aminopyridin-2-yl)acetate manufacturers
- Product
- Ethyl (6-aminopyridin-2-yl)acetate 71469-82-4
- Price
- US $1.10/g
- Min. Order
- 1g
- Purity
- 99.0% min
- Supply Ability
- 100 tons min
- Release date
- 2021-05-12
- Product
- Ethyl (6-aminopyridin-2-yl)acetate 71469-82-4
- Price
- US $1.00/g
- Min. Order
- 1g
- Purity
- 95-99%
- Supply Ability
- 1ton
- Release date
- 2020-01-10
- Product
- Ethyl (6-aminopyridin-2-yl)acetate 71469-82-4
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 95-99%
- Supply Ability
- 1ton
- Release date
- 2020-01-08