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Ethyl (6-aminopyridin-2-yl)acetate

Product Name
Ethyl (6-aminopyridin-2-yl)acetate
CAS No.
71469-82-4
Chemical Name
Ethyl (6-aminopyridin-2-yl)acetate
Synonyms
Ethyl 2-(6-aminopyridin-2-yl);Ethyl 6-Aminopyridine-2-acetate;2-(6-aMinopyridin-2-yl)butanoate;Ethyl (6-aminopyridin-2-yl)acetate;N-(2-AMinopyriMidin-4-yl)acetaMide;ethyl2-(6-aminopyridin-2-yl)acetate;6-AMINO-2-PYRIDINEACETIC ACID ETHYL ESTER;2-Pyridineacetic acid, 6-amino-, ethyl ester;2-(6-amino-2-pyridinyl)acetic acid ethyl ester;Ethyl (6-aminopyridin-2-yl)acetate ISO 9001：2015 REACH
CBNumber
CB41501601
Molecular Formula
C9H12N2O2
Formula Weight
180.2
MOL File
71469-82-4.mol
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Ethyl (6-aminopyridin-2-yl)acetate Property

Boiling point:
298.7±25.0 °C(Predicted)
Density 
1.168±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
pka
5.84±0.24(Predicted)
Appearance
Off-white to light yellow Solid
InChI
InChI=1S/C9H12N2O2/c1-2-13-9(12)6-7-4-3-5-8(10)11-7/h3-5H,2,6H2,1H3,(H2,10,11)
InChIKey
AJIPGVQKXQFJNX-UHFFFAOYSA-N
SMILES
C1(CC(OCC)=O)=NC(N)=CC=C1
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Safety

HS Code 
2933399990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
E900173
Product name
Ethyl2-(6-Aminopyridin-2-yl)acetate
Packaging
1g
Price
$330
Updated
2021/12/16
AK Scientific
Product number
W8039
Product name
Ethyl2-(6-aminopyridin-2-yl)acetate
Packaging
250mg
Price
$123
Updated
2021/12/16
AK Scientific
Product number
W8039
Product name
Ethyl2-(6-aminopyridin-2-yl)acetate
Packaging
1g
Price
$236
Updated
2021/12/16
SynQuest Laboratories
Product number
4H58-1-609
Product name
Ethyl (6-aminopyridin-2-yl)acetate
Packaging
1g
Price
$400
Updated
2021/12/16
Matrix Scientific
Product number
113965
Product name
Ethyl(6-aminopyridin-2-yl)acetate
Purity
97%
Packaging
1g
Price
$403
Updated
2021/12/16
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Ethyl (6-aminopyridin-2-yl)acetate Chemical Properties,Usage,Production

Synthesis

408365-87-7

71469-82-4

General procedure for the synthesis of ethyl (6-aminopyridin-2-yl)acetate from ethyl [6-[(tert-butoxycarbonyl)amino]-2-pyridinyl]acetate: to a solution of ethyl [6-[(tert-butoxycarbonyl)amino]-2-pyridinyl]acetate (1.38 g, 4.92 mmol) in methylene chloride (20 ml), was added a solution of dioxane in 4 M HCl (4 equiv. 19.7 mmol) and the reaction mixture was stirred at room temperature for 4 hours. Subsequently, 4 equivalents of dioxane solution of 4M HCl was added additionally and stirring was continued for 16 hours. Upon completion of the reaction, the mixture was concentrated in vacuum to afford the crude product ethyl (6-aminopyridin-2-yl)acetate (1.20 g, yield >100%, containing about 14% of the feedstock). Analysis by LC/MS showed a product purity of about 75% (MH+, m/z 181, retention time Rt=0.68 min). The resulting product does not require further purification and can be used directly in subsequent reactions.

References

[1] Patent: WO2006/50908, 2006, A1. Location in patent: Page/Page column 32; 39-40

Ethyl (6-aminopyridin-2-yl)acetate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Ethyl (6-aminopyridin-2-yl)acetate manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
Ethyl (6-aminopyridin-2-yl)acetate 71469-82-4
Price
US $1.10/g
Min. Order
1g
Purity
99.0% min
Supply Ability
100 tons min
Release date
2021-05-12
Career Henan Chemical Co
Product
Ethyl (6-aminopyridin-2-yl)acetate 71469-82-4
Price
US $1.00/g
Min. Order
1g
Purity
95-99%
Supply Ability
1ton
Release date
2020-01-10
Career Henan Chemical Co
Product
Ethyl (6-aminopyridin-2-yl)acetate 71469-82-4
Price
US $1.00/KG
Min. Order
1KG
Purity
95-99%
Supply Ability
1ton
Release date
2020-01-08

71469-82-4, Ethyl (6-aminopyridin-2-yl)acetateRelated Search:

(6-TERT-BUTOXYCARBONYLAMINO-PYRIDIN-2-YL)-ACETIC ACID ETHYL ESTER Ethyl (6-aminopyridin-2-yl)acetate ETHYL 2-(4,6-DIAMINO-3,5-DICYANO-2-PYRIDINYL)-2-[(Z)-2-(4-FLUOROPHENYL)HYDRAZONO]ACETATE ETHYL 2-[6-(METHYLAMINO)-2-PYRIDYL]ACETATE

  • Ethyl (6-aminopyridin-2-yl)acetate
  • 2-(6-aMinopyridin-2-yl)butanoate
  • N-(2-AMinopyriMidin-4-yl)acetaMide
  • 6-AMINO-2-PYRIDINEACETIC ACID ETHYL ESTER
  • Ethyl 2-(6-aminopyridin-2-yl)
  • ethyl2-(6-aminopyridin-2-yl)acetate
  • 2-(6-amino-2-pyridinyl)acetic acid ethyl ester
  • 2-Pyridineacetic acid, 6-amino-, ethyl ester
  • Ethyl (6-aminopyridin-2-yl)acetate ISO 9001：2015 REACH
  • Ethyl 6-Aminopyridine-2-acetate
  • 71469-82-4
  • pharmacetical