ChemicalBook > CAS DataBase List > UV-320

UV-320

Product Name
UV-320
CAS No.
3846-71-7
Chemical Name
UV-320
Synonyms
2-benzotriazol-2-yl-4,6-di-tert-butylphenol;4,6-Di-tert-butyl-2-(2H-benzotriazole-2-yl)phenol;HDBB;Ultraviolet absorbent UV-320;2-(2H-Benzo[d][1,2,3]triazol-2-yl)-4,6-di-tert-butylphenol;2-(2H-benzotriazol-2-yl)-4,6-bis(1,1-dimethylethyl)-Phenol;Phenol, 2-(2H-benzotriazol-2-yl)-4,6-bis(1,1-dimethylethyl)-;UV-320;TINUVIN 320;JADEADD UV320
CBNumber
CB4154994
Molecular Formula
C20H25N3O
Formula Weight
323.43
MOL File
3846-71-7.mol
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UV-320 Property

Melting point:
152-154°C
Boiling point:
444.0±55.0 °C(Predicted)
Density 
1.10±0.1 g/cm3(Predicted)
Flash point:
215°C
storage temp. 
2-8°C
solubility 
Chloroform (Slightly), Methanol (Slightly)
pka
9.41±0.48(Predicted)
form 
Solid
color 
White to Off-White
InChI
InChI=1S/C20H25N3O/c1-19(2,3)13-11-14(20(4,5)6)18(24)17(12-13)23-21-15-9-7-8-10-16(15)22-23/h7-12,24H,1-6H3
InChIKey
LHPPDQUVECZQSW-UHFFFAOYSA-N
SMILES
C1(O)=C(C(C)(C)C)C=C(C(C)(C)C)C=C1N1N=C2C=CC=CC2=N1
CAS DataBase Reference
3846-71-7(CAS DataBase Reference)
EPA Substance Registry System
Phenol, 2-(2H-benzotriazol-2-yl)-4,6-bis(1,1-dimethylethyl)- (3846-71-7)
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Safety

Risk Statements 
48/22-52/53
Safety Statements 
26-36/37/39
RIDADR 
3077
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H351Suspected of causing cancer

H373May cause damage to organs through prolonged or repeated exposure

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P201Obtain special instructions before use.

P202Do not handle until all safety precautions have been read and understood.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P281Use personal protective equipment as required.

P308+P313IF exposed or concerned: Get medical advice/attention.

P314Get medical advice/attention if you feel unwell.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
U850210
Product name
UV-320
Packaging
25g
Price
$105
Updated
2021/12/16
TRC
Product number
U850210
Product name
UV-320
Packaging
50g
Price
$185
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB140259
Product name
2-(2H-Benzo[d][1,2,3]triazol-2-yl)-4,6-di-tert-butylphenol
Packaging
50g
Price
$200
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0007185
Product name
2-(2'-HYDROXY-3',5'-DI-TERT-BUTYLPHENYL)BENZOTRIAZOLE
Purity
95.00%
Packaging
100G
Price
$2465.53
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB140259
Product name
2-(2H-Benzo[d][1,2,3]triazol-2-yl)-4,6-di-tert-butylphenol
Packaging
25g
Price
$150
Updated
2021/12/16
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UV-320 Chemical Properties,Usage,Production

Uses

UV-320 is a benzotriazole UV stabilizer, which is used to increase product stability and to prevent discolouration in various consumer and industrial goods such as plastics. Benzotriazole UV stabilizers are a pollutant for the aquatic environment and have been implicated as a potential stable and toxic ligands for aryl hydrocarbon receptor in human.

Synthesis

84755-44-2

3846-71-7

The general procedure for the synthesis of 2-(2H-3,5-di-tert-butyl-2-hydroxyphenyl)benzotriazole from 2-(2'-hydroxy-3',5'-di-tert-butylphenyl)benzotriazole N-oxide is as follows: Example 3: 10 g (0.03 mol) of 2-(2'-hydroxy-3',5'-di-tert-butylphenyl)benzotriazole-N-oxide, 100 mg of palladium-carbon catalyst, 100 ml of solvent mixture of toluene and water (4:1 ratio by volume), and 3 g of 50% dimethylamine solution were added to a 500 ml autoclave equipped with a stirrer. After replacing the air in the autoclave with hydrogen, the hydrogen pressure was set to 10 kg/cm2. The temperature was raised to 50 °C with stirring, and the reaction was maintained at this temperature until no more hydrogen was absorbed by the mixture. After completion of the reaction, the autoclave was cooled and the catalyst was removed by filtration. A portion of the filtrate was quantitatively analyzed by GC and the yield of 2-(2'-hydroxy-3',5'-di-tert-butylphenyl)benzotriazole was measured to be 85.6%. After removing the solvent from the filtrate by distillation, the residual solid was crystallized with ethanol and subsequently washed with ethanol to give 7.1 g of 2-(2'-hydroxy-3',5'-di-tert-butylphenyl)benzotriazole (71% yield; melting point 152-155 °C).

References

[1] Tetrahedron Letters, 1997, vol. 38, # 48, p. 8303 - 8306
[2] Tetrahedron Letters, 1997, vol. 38, # 5, p. 845 - 848
[3] Journal of Organic Chemistry, 1995, vol. 60, p. 5683 - 5685
[4] Australian Journal of Chemistry, 1982, vol. 35, # 10, p. 2089 - 2093
[5] Patent: US5104992, 1992, A

UV-320 Preparation Products And Raw materials

Raw materials

Preparation Products

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UV-320 Suppliers

Guangdong Wengjiang Chemical Reagent Co., Ltd.
Tel
0751-2886766 13927870850
Fax
0751-2886756
Email
3001267247@qq.com
Country
China
ProdList
9941
Advantage
58
Tianjin Zhongxin Chemtech Co., Ltd.
Tel
022-66880623
Fax
86(0)22-66880086
Email
sales@tjzxchem.com
Country
China
ProdList
613
Advantage
60
J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
TAIYUAN RHF CO.,LTD.
Tel
+86 351 7031519
Fax
+86 351 7031519
Email
sales@RHFChem.com
Country
China
ProdList
2338
Advantage
56
Beijing Ouhe Technology Co., Ltd
Tel
010-010-82967028 13522913783
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12000
Advantage
60
Pure Chemistry Scientific Inc.
Tel
001-857-928-2050 or 1-888-588-9418
Fax
001-617-206-9595
Email
sales@chemreagents.com
Country
United States
ProdList
10186
Advantage
62
Nanjing Chemlin Chemical Co., Ltd
Tel
025-83697070
Fax
+86-25-83453306
Email
info@chemlin.com.cn
Country
China
ProdList
16075
Advantage
64
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42934
Advantage
64
Tianjin heowns Biochemical Technology Co., Ltd.
Tel
400 638 7771
Email
sales@heowns.com
Country
China
ProdList
14435
Advantage
57
UHN Shanghai Research & Development Co., Ltd.
Tel
021-58958002 18930822973
Fax
+86 (21) 5895-8628
Email
sales@uhnshanghai.com
Country
China
ProdList
998
Advantage
58
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View Lastest Price from UV-320 manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd
Product
UV Absorber UV-320 3846-71-7
Price
US $79.00-38.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-12-04
Hebei Chuanghai Biotechnology Co., Ltd
Product
UV-320 3846-71-7
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-11-01
Changyi Longchang Bio-Chemical Co., LTD
Product
CHLUMIUV? UV-320 3846-71-7
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20 tons
Release date
2025-04-09

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