ChemicalBook > CAS DataBase List > O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide

O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide

Product Name
O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide
CAS No.
200132-54-3
Chemical Name
O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide
Synonyms
A16450;O-ALLYL-N-(9-ANTHRACENYLMETHYL)CINCHONIDINIUM BROMIDE;O-Allyl-N-[(9-anthracenyl)methyl]cinchonidium bromide;O-Allyl-1-(anthracen-9-ylmethyl)cinchonidinium bromide;O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide 90%;(-)-O-(9)-Allyl-N-(9-anthracenylmethyl) cinchonidiniumbromide;(-)-O-(9)-ALLYL-N-(9-ANTHRACENYLMETHYL) CINCHONIDINIUM BROMIDE;O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide (PTC catalys);Cinchonanium, 1-(9-anthracenylmethyl)-9-(2-propenyloxy)-, bromide, (8α,9R)-;4-((1R)-((1-(Anthracen-9-yl)but-3-en-2-yl)oxy)((2S)-5-vinylquinuclidin-2-yl)methyl)quinolin-1-ium bromide
CBNumber
CB4174541
Molecular Formula
C37H37BrN2O
Formula Weight
605.61
MOL File
200132-54-3.mol
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O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide Property

Melting point:
170 °C (dec.)(lit.)
alpha 
-340 º (C=0.45 IN CHLOROFORM)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
optical activity
[α]20/D 345±30°, c = 0.45 in chloroform
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
499617
Product name
O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide
Purity
90%
Packaging
1g
Price
$75
Updated
2024/03/01
Sigma-Aldrich
Product number
499617
Product name
O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide
Purity
90%
Packaging
5g
Price
$196
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
CCH0037407
Product name
(-)-O-(9)-ALLYL-N-(9-ANTHRACENYLMETHYL) CINCHONIDINIUM BROMIDE
Purity
95.00%
Packaging
1G
Price
$232.05
Updated
2021/12/16
ChemScene
Product number
CS-M3023
Product name
O-Allyl-N-[(9-anthracenyl)methyl]cinchonidiumbromide
Purity
≥97.0%
Packaging
1g
Price
$50
Updated
2021/12/16
Biosynth Carbosynth
Product number
FA152006
Product name
(-)-O-(9)-Allyl-N-(9-anthracenylmethyl) cinchonidiniumbromide
Packaging
500mg
Price
$110
Updated
2021/12/16
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O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide Chemical Properties,Usage,Production

Uses

O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide can catalyze the asymmetric alkylation of tert-butyl glycinate-benzophenone Schiff base with different arylmethyl bromides in a micellar medium.

General Description

O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide is a cinchona-based chiral phase-transfer catalyst (PTC) that can be used in asymmetric synthesis. It can be prepared from N-(9-anthracenylmethyl)cinchonindinium chloride.

O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide Preparation Products And Raw materials

Raw materials

Preparation Products

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O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide Suppliers

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200132-54-3, O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromideRelated Search:

Diallylamine Allyl hexanoate Tetrapropylammonium bromide Sodium bromate Ethidium bromide Allyl chloride Allyl bromide Allyl glycidyl ether Sodium allylsulfonate Rocuronium bromide Benzyl bromide Methyl bromide Benzyltriethylammonium bromide Benzyl tripropyl ammonium bromide C-ANTHRACEN-9-YL-METHYLAMINE 9-(METHYLAMINOMETHYL)ANTHRACENE (1-BENZYL-2-PIPERIDINYL)METHANOL N-BENZYLCINCHONIDINIUM BROMIDE

  • O-ALLYL-N-(9-ANTHRACENYLMETHYL)CINCHONIDINIUM BROMIDE
  • (-)-O-(9)-ALLYL-N-(9-ANTHRACENYLMETHYL) CINCHONIDINIUM BROMIDE
  • A16450
  • 4-((1R)-((1-(Anthracen-9-yl)but-3-en-2-yl)oxy)((2S)-5-vinylquinuclidin-2-yl)methyl)quinolin-1-ium bromide
  • O-Allyl-N-[(9-anthracenyl)methyl]cinchonidium bromide
  • O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide 90%
  • O-Allyl-1-(anthracen-9-ylmethyl)cinchonidinium bromide
  • (1S,2S,4S,5R)-2-((R)-(allyloxy)(quinolin-4-yl)methyl)-1-(anthracen-9-ylmethyl)-5-vinylquinuclidin-1-ium bromide
  • 4-[[1-(anthracen-9-ylmethyl)-5-ethenyl-1-azoniabicyclo[2.2.2]octan-2-yl]-prop-2-enoxymethyl]quinoline,bromide
  • (-)-O-(9)-Allyl-N-(9-anthracenylmethyl) cinchonidiniumbromide
  • 4-[(R)-[(2S,4S,5R)-1-(anthracen-9-ylmethyl)-5-ethenyl-1-azoniabicyclo[2.2.2]octan-2-yl]-prop-2-enoxymethyl]quinoline
  • Cinchonanium, 1-(9-anthracenylmethyl)-9-(2-propenyloxy)-, bromide, (8α,9R)-
  • O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide (PTC catalys)
  • 200132-54-3
  • BrC37H37N2O
  • C37H37N2OBr
  • Phase Transfer Reaction
  • Asymmetric Synthesis
  • Chiral Catalysts, Ligands, and Reagents
  • pharmacetical
  • Asymmetric Synthesis
  • Chiral Catalysts, Ligands, and Reagents
  • Phase Transfer Reaction