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N-TERT-BUTYLTRIMETHYLSILYLAMINE

Product Name
N-TERT-BUTYLTRIMETHYLSILYLAMINE
CAS No.
5577-67-3
Chemical Name
N-TERT-BUTYLTRIMETHYLSILYLAMINE
Synonyms
tert-C4H9NHSi(CH3)3;t-Butylamino Trimethylsilane;TERT-BUTYLAMINOTRIMETHYLSILANE;TERT-BUTYL TRIMETHYLSILYLAMINE;N-TERT-BUTYLTRIMETHYLSILYLAMINE;(Trimethylsilyl)(tert-butyl)amine;N-(TRIMETHYLSILYL)-TERT-BUTYLAMINE;N-(tert-Butyl)(trimethyl)silanamine;N-tert-Butyltrimethylsilylamine 98%;N-tert-butyl-1,1,1-trimethylsilanamine
CBNumber
CB4185743
Molecular Formula
C7H19NSi
Formula Weight
145.32
MOL File
5577-67-3.mol
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N-TERT-BUTYLTRIMETHYLSILYLAMINE Property

Boiling point:
118-119 °C(lit.)
Density 
0.762 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.406(lit.)
Flash point:
80 °F
form 
liquid
pka
13.25±0.70(Predicted)
color 
Clear, colourless
BRN 
1734528
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Safety

Hazard Codes 
C
Risk Statements 
10-34
Safety Statements 
16-26-36/37/39-45
RIDADR 
UN 2733 3/PG 3
WGK Germany 
3
F 
10-21
HazardClass 
3.2
PackingGroup 
III
HS Code 
2931900090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H226Flammable liquid and vapour

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
369330
Product name
N-tert-Butyltrimethylsilylamine
Purity
98%
Packaging
25g
Price
$148
Updated
2024/03/01
Apolloscientific
Product number
OR939298
Product name
N-tert-Butyltrimethylsilylamine
Purity
97%
Packaging
25g
Price
$203
Updated
2021/12/16
SynQuest Laboratories
Product number
7187-1-00
Product name
N-tert-Butyltrimethylsilylamine
Purity
97%
Packaging
25g
Price
$224
Updated
2021/12/16
Apolloscientific
Product number
OR939298
Product name
N-tert-Butyltrimethylsilylamine
Purity
97%
Packaging
100g
Price
$573
Updated
2021/12/16
SynQuest Laboratories
Product number
7187-1-00
Product name
N-tert-Butyltrimethylsilylamine
Purity
97%
Packaging
100g
Price
$632
Updated
2021/12/16
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N-TERT-BUTYLTRIMETHYLSILYLAMINE Chemical Properties,Usage,Production

Uses

N-tert-Butyltrimethylsilylamine may be used in the preparation of selenium and tellurium chalcogenides and the facile synthesis of N-alkylaminomethylphosphonates.

Preparation

N-tert-Butyltrimethylsilylamine is prepared by the reaction of the parent amines with n-Butyllithium in THF/hexane. The parent amines are prepared by the reaction of lithium t-butylamide and the corresponding chlorosilanes (eq 1).

General Description

N-tert-Butyltrimethylsilylamine (Me3SiNH-t-Bu) reacts with [Cp*Rh(H2O)3](OTf)2 in acetone to yield a hydroxyl-capped half-cubane [Cp*3Rh3(μ-OH)3(μ3-OH)](OTf)3(t-BuNH3).

storage

N-tert-Butyltrimethylsilylamine reacts readily with protic solvents, especially water, and must be maintained in a dry environment. It is thermally stable. Use in a fume hood.

Purification Methods

Best purified by distillation.

N-TERT-BUTYLTRIMETHYLSILYLAMINE Preparation Products And Raw materials

Raw materials

Preparation Products

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N-TERT-BUTYLTRIMETHYLSILYLAMINE Suppliers

China 38 Germany 1 Switzerland 1 United Kingdom 2 United States 4 Global 46
J & K SCIENTIFIC LTD.
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010-82848833 400-666-7788
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86-10-82849933
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021-54306202 13764082696
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Shanghai chuqing Organosilane technology ltd
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021-61530618
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86-21-51714575
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sales@chuqingtech.com
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Hangzhou J&H Chemical Co., Ltd.
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Sigma-Aldrich
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Aikon International Limited
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Anhui Silicon Innovation Materials Technology Co., Ltd.
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Wuhan Ying Yuan Bei Biological Limited
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5577-67-3, N-TERT-BUTYLTRIMETHYLSILYLAMINERelated Search:

tert-butylmethylnitrosamine TRIMETHYLSILYL CHLOROSULFONATE DIMETHYLSILYL (T-BUTYLAMIDO)(CYCLOPENTADIENYL) TITANIUM DICHLORIDE N-TERT-BUTYLTRIMETHYLSILYLAMINE N-TERT-BUTYL-1,1-DIMETHYL-1-(2,3,4,5-TETRAMETHYL-2,4-CYCLOPENTADIEN-1-YL) SILANAMINE DIMETHYLSILYL (T-BUTYLAMIDO) TETRAMETHYLCYCLOPENTADIENYL ZIRCONIUM DICHLORIDE TERT-BUTYLAMINOTRIETHYLSILANE 2,3,4,5-TETRAMETHYLCYCLOPENTADIENEDIMETHYLSILYL-TERT-BUTYLAMIDO TITANIUM DICHLORIDE [(1,1-DIMETHYLETHYL)AMINO]DIMETHYL(3-METHYLCYCLOPENTADIEN-1-YL)SILANE AURORA KA-1699 AURORA KA-1824 DIMETHYLSILYL (T-BUTYLAMIDO)CYCLOPENTADIENYL ZIRCONIUM DICHLORIDE

  • TERT-BUTYL TRIMETHYLSILYLAMINE
  • N-TERT-BUTYLTRIMETHYLSILYLAMINE
  • N-(TRIMETHYLSILYL)-TERT-BUTYLAMINE
  • Silanamine,N-(1,1-dimethylethyl)-1,1,1-trimethyl-
  • TERT-BUTYLAMINOTRIMETHYLSILANE
  • N-tert-Butyltrimethylsilylamine 98%
  • N-(tert-Butyl)(trimethyl)silanamine
  • tert-C4H9NHSi(CH3)3
  • (Trimethylsilyl)(tert-butyl)amine
  • N-(Trimethylsilyl)-2-methyl-2-propanamine
  • 2-methyl-N-trimethylsilylpropan-2-amine
  • N-(1,1-Dimethylethyl)-1,1,1-trimethylsilanamine
  • t-Butylamino Trimethylsilane
  • N-tert-butyl-1,1,1-trimethylsilanamine
  • 5577-67-3
  • CH33SiNHCCH33
  • Protected Amines
  • Organic Building Blocks
  • Nitrogen Compounds
  • Building Blocks
  • Building Blocks
  • Chemical Synthesis
  • Nitrogen Compounds
  • Organic Building Blocks
  • Protected Amines