N-TERT-BUTYLTRIMETHYLSILYLAMINE

Product Name: N-TERT-BUTYLTRIMETHYLSILYLAMINE
CAS No.: 5577-67-3
Chemical Name: N-TERT-BUTYLTRIMETHYLSILYLAMINE
Synonyms: tert-C4H9NHSi(CH3)3;t-Butylamino Trimethylsilane;TERT-BUTYLAMINOTRIMETHYLSILANE;TERT-BUTYL TRIMETHYLSILYLAMINE;N-TERT-BUTYLTRIMETHYLSILYLAMINE;(Trimethylsilyl)(tert-butyl)amine;N-(TRIMETHYLSILYL)-TERT-BUTYLAMINE;N-(tert-Butyl)(trimethyl)silanamine;N-tert-Butyltrimethylsilylamine 98%;N-tert-butyl-1,1,1-trimethylsilanamine
CBNumber: CB4185743
Molecular Formula: C7H19NSi
Formula Weight: 145.32
MOL File: 5577-67-3.mol

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N-TERT-BUTYLTRIMETHYLSILYLAMINE Property

Boiling point:: 118-119 °C(lit.)
Density: 0.762 g/mL at 25 °C(lit.)
refractive index: n20/D 1.406(lit.)
Flash point:: 80 °F
form: liquid
pka: 13.25±0.70(Predicted)
color: Clear, colourless
BRN: 1734528

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Safety

Hazard Codes: C
Risk Statements: 10-34
Safety Statements: 16-26-36/37/39-45
RIDADR: UN 2733 3/PG 3
WGK Germany: 3
F: 10-21
HazardClass: 3.2
PackingGroup: III
HS Code: 2931900090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H226Flammable liquid and vapour

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 369330
Product name: N-tert-Butyltrimethylsilylamine
Purity: 98%
Packaging: 25g
Price: $148
Updated: 2024/03/01

Apolloscientific

Product number: OR939298
Product name: N-tert-Butyltrimethylsilylamine
Purity: 97%
Packaging: 25g
Price: $203
Updated: 2021/12/16

SynQuest Laboratories

Product number: 7187-1-00
Product name: N-tert-Butyltrimethylsilylamine
Purity: 97%
Packaging: 25g
Price: $224
Updated: 2021/12/16

Apolloscientific

Product number: OR939298
Product name: N-tert-Butyltrimethylsilylamine
Purity: 97%
Packaging: 100g
Price: $573
Updated: 2021/12/16

SynQuest Laboratories

Product number: 7187-1-00
Product name: N-tert-Butyltrimethylsilylamine
Purity: 97%
Packaging: 100g
Price: $632
Updated: 2021/12/16

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N-TERT-BUTYLTRIMETHYLSILYLAMINE Chemical Properties,Usage,Production

Uses

N-tert-Butyltrimethylsilylamine may be used in the preparation of selenium and tellurium chalcogenides and the facile synthesis of N-alkylaminomethylphosphonates.

Preparation

N-tert-Butyltrimethylsilylamine is prepared by the reaction of the parent amines with n-Butyllithium in THF/hexane. The parent amines are prepared by the reaction of lithium t-butylamide and the corresponding chlorosilanes (eq 1).

General Description

N-tert-Butyltrimethylsilylamine (Me₃SiNH-t-Bu) reacts with [Cp*Rh(H₂O)₃](OTf)₂ in acetone to yield a hydroxyl-capped half-cubane [Cp*3Rh₃(μ-OH)3(μ₃-OH)](OTf)₃(t-BuNH₃).

storage

N-tert-Butyltrimethylsilylamine reacts readily with protic solvents, especially water, and must be maintained in a dry environment. It is thermally stable. Use in a fume hood.

Purification Methods

Best purified by distillation.

N-TERT-BUTYLTRIMETHYLSILYLAMINE Preparation Products And Raw materials

Raw materials

Preparation Products

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N-TERT-BUTYLTRIMETHYLSILYLAMINE Suppliers

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5577-67-3, N-TERT-BUTYLTRIMETHYLSILYLAMINERelated Search:

tert-butylmethylnitrosamine TRIMETHYLSILYL CHLOROSULFONATE DIMETHYLSILYL (T-BUTYLAMIDO)(CYCLOPENTADIENYL) TITANIUM DICHLORIDE N-TERT-BUTYLTRIMETHYLSILYLAMINE N-TERT-BUTYL-1,1-DIMETHYL-1-(2,3,4,5-TETRAMETHYL-2,4-CYCLOPENTADIEN-1-YL) SILANAMINE DIMETHYLSILYL (T-BUTYLAMIDO) TETRAMETHYLCYCLOPENTADIENYL ZIRCONIUM DICHLORIDE TERT-BUTYLAMINOTRIETHYLSILANE 2,3,4,5-TETRAMETHYLCYCLOPENTADIENEDIMETHYLSILYL-TERT-BUTYLAMIDO TITANIUM DICHLORIDE [(1,1-DIMETHYLETHYL)AMINO]DIMETHYL(3-METHYLCYCLOPENTADIEN-1-YL)SILANE AURORA KA-1699 AURORA KA-1824 DIMETHYLSILYL (T-BUTYLAMIDO)CYCLOPENTADIENYL ZIRCONIUM DICHLORIDE

TERT-BUTYL TRIMETHYLSILYLAMINE

N-TERT-BUTYLTRIMETHYLSILYLAMINE

N-(TRIMETHYLSILYL)-TERT-BUTYLAMINE

Silanamine,N-(1,1-dimethylethyl)-1,1,1-trimethyl-

TERT-BUTYLAMINOTRIMETHYLSILANE

N-tert-Butyltrimethylsilylamine 98%

N-(tert-Butyl)(trimethyl)silanamine

tert-C4H9NHSi(CH3)3

(Trimethylsilyl)(tert-butyl)amine

N-(Trimethylsilyl)-2-methyl-2-propanamine

2-methyl-N-trimethylsilylpropan-2-amine

N-(1,1-Dimethylethyl)-1,1,1-trimethylsilanamine

t-Butylamino Trimethylsilane

N-tert-butyl-1,1,1-trimethylsilanamine

5577-67-3

CH33SiNHCCH33

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