Reaction
ChemicalBook > CAS DataBase List > 2-Di-t-butylphosphino-2'-(N,N-dimethylamino)biphenyl

2-Di-t-butylphosphino-2'-(N,N-dimethylamino)biphenyl

Reaction
Product Name
2-Di-t-butylphosphino-2'-(N,N-dimethylamino)biphenyl
CAS No.
224311-49-3
Chemical Name
2-Di-t-butylphosphino-2'-(N,N-dimethylamino)biphenyl
Synonyms
tBuDavePhos;t-Butyl DavePhos;98% tBuDav;98% tBuDavePhos;t-BuDavePhos 97%;2-(Di-tert-butylphosphino)-2'-;2-(Di-tert-butylphosphino)-2'-(N,N-dimethylamino)b;2-DI-T-BUTYLPHOSPHINO-2'-(N,N-DIMETHYLAMINO)BIPHENYL;2-DI-T-BUTYLPHOSHINO-2''-(N,N-DIMETHYLAMINO)BIPHENYL;2-DI-T-BUTYLPHOSPHINO-2'-(N,N-DIMETHYLAMINO)BIPHENYL
CBNumber
CB4192659
Molecular Formula
C22H32NP
Formula Weight
341.47
MOL File
224311-49-3.mol
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2-Di-t-butylphosphino-2'-(N,N-dimethylamino)biphenyl Property

Melting point:
115-117 °C
Boiling point:
451.6±38.0 °C(Predicted)
storage temp. 
Inert atmosphere,Room Temperature
pka
5.07±0.18(Predicted)
form 
crystal
color 
white
Sensitive 
Air Sensitive
InChI
InChI=1S/C22H32NP/c1-21(2,3)24(22(4,5)6)20-16-12-10-14-18(20)17-13-9-11-15-19(17)23(7)8/h9-16H,1-8H3
InChIKey
PHLPNEHPCYZBNZ-UHFFFAOYSA-N
SMILES
C1(C2=CC=CC=C2P(C(C)(C)C)C(C)(C)C)=CC=CC=C1N(C)C
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
37/39-26
WGK Germany 
3
TSCA 
No
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

H413May cause long lasting harmful effects to aquatic life

Precautionary statements

P273Avoid release to the environment.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
695874
Product name
t-BuDavePhos
Purity
97%
Packaging
5g
Price
$175.2
Updated
2024/03/01
Sigma-Aldrich
Product number
695874
Product name
t-BuDavePhos
Purity
97%
Packaging
1g
Price
$186
Updated
2024/03/01
Strem Chemicals
Product number
15-1048
Product name
2-Di-t-butylphosphino-2'-(N,N-dimethylamino))-1,1'-biphenyl, 98% tBuDavePhos
Packaging
500mg
Price
$54
Updated
2024/03/01
Strem Chemicals
Product number
15-1048
Product name
2-Di-t-butylphosphino-2'-(N,N-dimethylamino))-1,1'-biphenyl, 98% tBuDavePhos
Packaging
2g
Price
$156
Updated
2024/03/01
Sigma-Aldrich
Product number
695874
Product name
t-BuDavePhos
Purity
97%
Packaging
250mg
Price
$49.1
Updated
2024/03/01
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2-Di-t-butylphosphino-2'-(N,N-dimethylamino)biphenyl Chemical Properties,Usage,Production

Reaction

  1. Useful ligand for Pd-catalyzed carbon-oxygen bond forming reactions.
  2. Ligand used selective Pd-catalyzed arylation of ammonia. Application to the synthesis of dibenzodiazepines.
  3. Ligand used for selective Pd-catalyzed silylation of aryl chlorides.
  4. Ligand used for Pd(0)-catalyzed direct dehydrative coupling of terminal alkynes with allylic alcohols to access 1,4-enynes. 

Chemical Properties

White crystals or crystalline powder

Uses

suzuki reaction

2-Di-t-butylphosphino-2'-(N,N-dimethylamino)biphenyl Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Di-t-butylphosphino-2'-(N,N-dimethylamino)biphenyl Suppliers

Accela ChemBio Inc.
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(+1)-858-876-1948
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United States
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View Lastest Price from 2-Di-t-butylphosphino-2'-(N,N-dimethylamino)biphenyl manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
2-Di-tert-butylphosphino-2'-(N,N-dimethylamino)biphenyl 224311-49-3
Price
US $0.00/G
Min. Order
50G
Purity
98%min
Supply Ability
30KG/month
Release date
2023-01-31
XINXIANG RUNYU MATERIAL CO., LTD.
Product
2-DI-T-BUTYLPHOSPHINO-2'-(N,N-DIMETHYLAMINO)BIPHENYL 224311-49-3
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
0.99
Supply Ability
500kg
Release date
2021-11-29
Hebei Weibang Biotechnology Co., Ltd
Product
2-DI-T-BUTYLPHOSPHINO-2'-(N,N-DIMETHYLAMINO)BIPHENYL 224311-49-3
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2024-10-24

224311-49-3, 2-Di-t-butylphosphino-2'-(N,N-dimethylamino)biphenylRelated Search:


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  • 2-Di-t-butylphosphino-2'-(N,N-dimethylamino))-1,1'-biphenyl
  • 2'-(Di-tert-butylphosphino)-N,N-dimethyl-[1,1'-biphenyl]-2-amine
  • 2-(Di-tert-butylphosphino)-2'-(N,N-dimethylamino)biphenyl
  • 2'-(Di-tert-butylphosphino)-N,N-dimethylbiphenyl-2-amine
  • 2'-[Bis(1,1-dimethylethyl)phosphino]-N,N-dimethyl[1,1'-biphenyl]-2-amine
  • 2-Di-t-butylphosphino-2'-(N,N-diMethylaMino)biphenyl (tBuDavePhos)
  • 224311-49-3
  • 224311-43-3
  • C22H32NP
  • CH32NC6H4C6H4PC4H92
  • Phosphines
  • Achiral Phosphine
  • Aryl Phosphine
  • Buchwald Ligands Series
  • Buchwald Ligands&Precatalysts