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ChemicalBook > CAS DataBase List > Chloro(1,5-cyclooctadiene)iridium(I) dimer

Chloro(1,5-cyclooctadiene)iridium(I) dimer

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Product Name
Chloro(1,5-cyclooctadiene)iridium(I) dimer
CAS No.
12112-67-3
Chemical Name
Chloro(1,5-cyclooctadiene)iridium(I) dimer
Synonyms
BIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) DICHLORIDE;[Ir(1,5-cod)Cl]2;IRIDIUM(I) CHLORIDE 1,5-CYCLOOCTADIENE COMPLEX DIMER;Bis(1,5-cyclooctadiene)diiridium(I) Dichloride ([Ir(cod)Cl]2);Chloro(1;IRIDIUM COD CHLORIDE;Palladium pivalate(l);Chloro(1,5-cyclooctadiene;ooctadiene)diiridium(I) dichL;IRIDIUM CHLORO-1,5-CYCLOOCTADIENE
CBNumber
CB4212508
Molecular Formula
C16H24Cl2Ir2
Formula Weight
671.7
MOL File
12112-67-3.mol
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Chloro(1,5-cyclooctadiene)iridium(I) dimer Property

Melting point:
205 °C (dec.)(lit.)
storage temp. 
Keep in dark place,Inert atmosphere,2-8°C
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Powder
color 
red to orange
Water Solubility 
insoluble
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
InChIKey
XHOSESNLNGITPM-XRGHXPOKSA-L
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
F 
10
TSCA 
No
HS Code 
28439000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
683094
Product name
Bis(1,5-cyclooctadiene)diiridium(I) dichloride
Purity
97%
Packaging
500mg
Price
$164
Updated
2024/03/01
Sigma-Aldrich
Product number
683094
Product name
Bis(1,5-cyclooctadiene)diiridium(I) dichloride
Purity
97%
Packaging
2g
Price
$417
Updated
2024/03/01
TCI Chemical
Product number
C1807
Product name
Chloro(1,5-cyclooctadiene)iridium(I) Dimer
Purity
>93.0%(T)
Packaging
1g
Price
$581
Updated
2024/03/01
TCI Chemical
Product number
C1807
Product name
Chloro(1,5-cyclooctadiene)iridium(I) Dimer
Purity
>93.0%(T)
Packaging
250mg
Price
$224
Updated
2024/03/01
Alfa Aesar
Product number
012749
Product name
Chloro(1,5-cyclooctadiene)iridium(I) dimer, Ir 57.2%
Packaging
0.25g
Price
$105
Updated
2023/06/20
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Chloro(1,5-cyclooctadiene)iridium(I) dimer Chemical Properties,Usage,Production

Reactions

1. Precursor to catalysts for the asymmetric hydrogenation of tri- and tetrasubstituted olefins.
2. Precursor to catalyst for enantioselective reduction of imines.
3. Precursor to catalyst for allylic alkylation.
4. Precursor to catalyst for allylic amination and etherification.
5. Precursor to catalyst for the reaction of aroyl chlorides with internal alkynes to produce substituted naphthalenes and anthracenes.
6. Ir-catalyzed addition of acid chlorides to terminal alkynes.
7. Intramolecular hydroamination of unactivated alkenes with secondary alkyl- and arylamines.
8. Enantioselective [2+2] cycloaddition.
9. Silyl-directed, Ir-catalyzed ortho-borylation of arenes.
10. Ir-catalyzed cross-coupling of styrene derivatives with allylic carbonates.
11. Transfer hydrogenative C-C coupling

Chemical Properties

red-orange solid

Uses

Chloro(1,5-cyclooctadiene)iridium(I) dimer is widely used as a precursor to other iridium complexes, which finds application in homogeneous catalysis like carbonylation, hydrosilylation, hydrofomylation, asymmetric allylic substitutions, metathesis and chiral catalysis reactions. It is involved in the preparation of Crabtree's catalyst, which is used for hydrogenation and hydrogen-transfer reactions.

Chloro(1,5-cyclooctadiene)iridium(I) dimer Preparation Products And Raw materials

Raw materials

Hydrazinium hydroxide solution Hydroquinone Tetrahydrofuran Iridium(III) chloride hydrate 1,5-Cyclooctadiene Isopropyl alcohol

Preparation Products

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Chloro(1,5-cyclooctadiene)iridium(I) dimer Suppliers

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View Lastest Price from Chloro(1,5-cyclooctadiene)iridium(I) dimer manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
Chloro(1,5-cyclooctadiene)iridium(I) dimer 12112-67-3
Price
US $0.00/G
Min. Order
10G
Purity
98%min
Supply Ability
30kg/month
Release date
2023-02-07
henan kanbei chemical co.,ltd
Product
Chloro(1,5-cyclooctadiene)iridium(I) dimer 12112-67-3
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
1000kg
Release date
2022-09-23
Zhuozhou Wenxi import and Export Co., Ltd
Product
Chloro(1,5-cyclooctadiene)iridium(I) dimer 12112-67-3
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-11

12112-67-3, Chloro(1,5-cyclooctadiene)iridium(I) dimerRelated Search:

Iridium(III) chloride hydrate DILINOLEIC ACID Iridium 1,5-Cyclooctadiene POLYALUMINUM CHLORIDE POLYETHYLENE, CHLORINATED 1,3-CYCLOOCTADIENE Cobalt chloride Chloro(1,5-cyclooctadiene)rhodium(I) dimer BIS(1,5-CYCLOOCTADIENE)IRIDIUM (I) TETRAFLUOROBORATE Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) SPhos Pd G1, Methyl t-Butyl Ether Adduct RuPhos Pd G2 XPhos Pd G1 BIS(1 5-CYCLOOCTADIENE)RHODIUM(I) Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate

  • BIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) DICHLORIDE
  • DI-MU-CHLOROBIS[(ETA-CYCLOOCTA-1,5-DIENE)IRIDIUM (I)]
  • DI-MU-CHLORO-BIS[(1,2,5,6-ETA)-1,5-CYCLOOCTADIENE]DIIRIDIUM
  • CHLORO(1,5-CYCLOOCTADIENE)IRIDATE (I) DIMER
  • CHLORO(1,5-CYCLOOCTADIENE)IRIDIUM(I) DIMER
  • IRIDIUM(I) CHLORIDE 1,5-CYCLOOCTADIENE COMPLEX DIMER
  • IRIDIUM I CYCLOOCTADIENE CHLORIDE
  • IRIDIUM CHLORO-1,5-CYCLOOCTADIENE
  • IRIDIUM COD CHLORIDE
  • 1,5-CYCLOOCTADIENE-IRIDIUM(I) CHLORIDE DIMER
  • chloro(1,5-cyclooctadiene)iridium(i)
  • BIS(1,5-CYCLOOCTADIEN)DIIRIDIUM(I)-DICHL ORIDE
  • BIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) DIC&
  • Chloro(1,5-cyclooctadiene)iridium(I), dimer,99.9%
  • Chloro(1,5-cyclooctadiene)iridium(I)dimere
  • di-mu-chlorobis[(1,2,5,6-eta)cycloocta-1,5-diene]diiridium
  • Chloro-1,5-cyclooctadieneiridium(I)dimer,99%
  • CHLORO(1,5-CYCLOOCTADIENE)IRIDIUM(I) DIMER (57%IR)
  • Chloro-(1,5-cyclooctadiene)-iridium dimer
  • Chloro(1,5-cyclooctadiene)iridium(I) dimer, Ir 57.2%
  • Chloro(1,5-cyclooctadiene)iridium(I)dimer dec. 190
  • Chloro(1,5-cyclooctadiene)iridium(I) dimer ,98%
  • "Di-chloro bis(cycloocta-1,5-dienyl)iridium(I)"
  • Bis(1,5-cyclooctadiene)diiridium(I) dichloride,1,5-Cyclooctadiene-iridium(I) chloride dimer, Chloro(1,5-cyclooctadiene)iridium(I) dimer, Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]diiridium, Iridiu
  • Chloro(1,5-cyclooctadiene)iridiuM(I) diMer 250MG
  • IridiuM, di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]di-
  • Chloro(1,5-cyclooctadiene)iridiuM(I) diMer,98% [Ir(COD)Cl]2
  • IRIDIUM(I) CYCLOOCTADIENE CHLORIDE, diMer
  • Chloro(1,5-cyclooctadiene)iridium(Ⅰ) dimer
  • Chloro(1,5-cyclooctadiene)iridiuM(I) diMer,[Ir(COD)Cl]2
  • Bis(1,5-cyclooctadiene)diiridiuM(I) dichloride 97%
  • 1,5-octadiene iridiuM chloride diMer
  • Dichloro(1,5-cyclooctadien)iridium(I) dimer
  • Bis(1,5-cyclooctadiene)diiridium(I) Dichloride ([Ir(cod)Cl]2)
  • Chloroiridium - cycloocta-1,5-diene (1:1)
  • [Ir(1,5-cod)Cl]2
  • 5-cyclooctadiene)iridium(I) dimer
  • Chloro(1
  • Chloro(1,5-cyclooctadiene)iridium(I) Dimer &gt
  • ooctadiene)diiridium(I) dichL
  • Chloro(1,5-cyclooctadiene)iridium(I) dimer ISO 9001：2015 REACH
  • TIANFU CHEM Chloro(1,5-cyclooctadiene)iridium(I) dimer
  • Di( μ -chloro)bis(1,5-cyclooctadiene)diiridium(I)
  • Chloro-1,5-cyclooctadiene iridium(I) dimmer
  • Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]diiridium
  • Chloroiridium-cycloocta-1,5-diene
  • CHLORO(1,5-CYCLOOTADIENE)IRIDIUM(I) DIMER
  • Chloro(1,5-cyclooctadiene
  • Palladium pivalate(l)
  • 12112-67-3
  • 12112-67-2
  • C16H24Ir2Cl2
  • 2C8H12IrCl2
  • IrClC8H122
  • C8H12IrCl2
  • IrCODCl2
  • C16H24Cl2Ir2
  • Iridium