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ChemicalBook > CAS DataBase List > Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)

Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)

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Product Name
Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
CAS No.
325146-81-4
Chemical Name
Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
Synonyms
Ru-BINAP;Diacetato[(R;-binaphthalene ≥diacetoxyruthenium;Ru(OAc)2[(R)-binap];(R)-Ru(OAc)?(BINAP);RU[(R)-BINAP](OCOH3)2;Ru[(R)-BINAP](OCOCH3)2;-binaphthyl]ruthenium(II);Diacetato[(R)-(+)-2,2'-bis(diphenyL
CBNumber
CB42130440
Molecular Formula
C48H40O4P2Ru
Formula Weight
843.86
MOL File
325146-81-4.mol
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Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Property

Melting point:
>100°C
storage temp. 
2-8°C
form 
Powder
color 
ocher to green
Sensitive 
air sensitive
InChI
InChI=1S/C44H32P2.2C2H4O2.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;2*1-2(3)4;/h1-32H;2*1H3,(H,3,4);
InChIKey
XANQJWCSQJDBEA-UHFFFAOYSA-N
SMILES
CC1=O[Ru+2]23(O=C(C)[O-]2)(P(C2C=CC=CC=2)(C2C=CC=CC=2)C2=CC=C4C=CC=CC4=C2C2=C4C=CC=CC4=CC=C2P3(C2C=CC=CC=2)C2C=CC=CC=2)[O-]1
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Safety

WGK Germany 
3
HS Code 
28439000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
692220
Product name
(R)-Ru(OAc)2(BINAP)
Packaging
100mg
Price
$19.74
Updated
2024/03/01
Sigma-Aldrich
Product number
692220
Product name
(R)-Ru(OAc)2(BINAP)
Packaging
500mg
Price
$83.4
Updated
2024/03/01
TCI Chemical
Product number
R0166
Product name
Ru(OAc)2[(R)-binap]
Packaging
200mg
Price
$43
Updated
2024/03/01
TCI Chemical
Product number
R0166
Product name
Ru(OAc)2[(R)-binap]
Packaging
1g
Price
$148
Updated
2024/03/01
Strem Chemicals
Product number
44-0152
Product name
Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(R)-binap]
Packaging
250mg
Price
$53
Updated
2024/03/01
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Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Chemical Properties,Usage,Production

Reaction

  1. Catalyst system that exhibits very high catalytic activity and enantioselectivity in the hydrogenation of a wide range of substrates.
  2. Catalyst used in the synthesis of β-amino acids by hydrogenation.

Chemical Properties

Light yellow powder

Uses

(R)-Ru(OAc)2(BINAP) is a catalyst.

Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Preparation Products And Raw materials

Raw materials

Preparation Products

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Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Suppliers

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View Lastest Price from Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
Diacetato[(R)-(+)-2,2"-bis(diphenylphosphino)-1,1"-binaphthyl]ruthenium(II) 325146-81-4
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27
Wuhan LPBchem Technology Co.,Ltd
Product
Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) / (R)-Ru(OAc)2(BINAP) 325146-81-4
Price
US $10.00-10.00/g
Min. Order
1g
Purity
0.98
Supply Ability
50kg
Release date
2020-09-28
Longyan Tianhua Biological Technology Co., Ltd
Product
Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) 325146-81-4
Price
US $20.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000KG
Release date
2020-11-11

325146-81-4, Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)Related Search:


  • Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
  • (R)-Ru(OAc)2(BINAP),Diacetato[(R)-(+)-2,2′-bis(diphenylphosphino)-1,1′binaphthyl]ruthenium(II)
  • Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(R)-binap]
  • Ru-BINAP
  • RU(OAC)<SUB>2</SUB>[(<I>R</I>)-BINAP]
  • Ru(OAc)2[(R)-binap]
  • -binaphthyl]ruthenium(II),Ru(OAc)2[(R)-binap].
  • (OC-6-22)-Bis(acetato-κO,κO')[(1R)-[1,1'-binaphthalene]-2,2'-diylbis[diphenylphosphine-κP]]ruthenium
  • (R)-Ru(OAc)2(BINAP),Diacetato[(R)-(+)-2,2bis(diphenylphosphino)-1,1inaphthyl]ruthenium(II)
  • Diacetato[(R
  • Ru(OCOCH3)2((S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)
  • -binaphthyl]ruthenium(II)
  • -((((5-Chloropyridine-2,3-diyl)bis(oxy))bis(4,1-phenylene))bis(oxy))dipropanoic Acid
  • -binaphthyl]ruthenium(II) Dichloride
  • -diyl)bis(4-benzyl-4,5-dihydrooxazole)
  • -binaphthalene &ge
  • -(Ethane-1,2-diylbis(azanediyl))disuccinic Acid
  • Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) / (R)-Ru(OAc)2(BINAP)
  • Diacetato[(R)-(+)-2,2'-bis(diphenyL
  • Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) ISO 9001:2015 REACH
  • Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2
  • Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthy...
  • (R)-Ru(OAc)?(BINAP)
  • RU[(R)-BINAP](OCOH3)2
  • Ru[(R)-BINAP](OCOCH3)2
  • Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
  • diacetoxyruthenium
  • (OC-6-22)-Bis(acetato-κo,κo')[(1R)-[1,1'-binaphthalene]-2,2'-diylbis[diphenylphosphine-κp]]ruthenium
  • 325146-81-4
  • C44H32P2C4H6O4Ru
  • Ru