ChemicalBook > CAS DataBase List > Octyltrichlorosilane

Octyltrichlorosilane

Product Name
Octyltrichlorosilane
CAS No.
5283-66-9
Chemical Name
Octyltrichlorosilane
Synonyms
OTCS;DK322;DK321;DK805;CO9830;LS 2190;P 09830;TRICHLOROOCTYLSILANE;trichlorooctyl-silan;OCTYLTRICHLOROSILANE
CBNumber
CB4230621
Molecular Formula
C8H17Cl3Si
Formula Weight
247.66
MOL File
5283-66-9.mol
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Octyltrichlorosilane Property

Boiling point:
233 °C731 mm Hg(lit.)
Density 
1.07 g/mL at 25 °C(lit.)
vapor density 
>1 (vs air)
vapor pressure 
0-3.5Pa at 25℃
refractive index 
n20/D 1.447(lit.)
Flash point:
206 °F
form 
clear liquid
color 
Fuming liquid
Specific Gravity
1.074
Water Solubility 
59g/L at 20℃
Hydrolytic Sensitivity
8: reacts rapidly with moisture, water, protic solvents
Sensitive 
Moisture Sensitive
BRN 
1744230
InChIKey
RCHUVCPBWWSUMC-UHFFFAOYSA-N
LogP
1.1 at 20℃
CAS DataBase Reference
5283-66-9(CAS DataBase Reference)
EPA Substance Registry System
Silane, trichlorooctyl- (5283-66-9)
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Safety

Hazard Codes 
C
Risk Statements 
34-37
Safety Statements 
26-36/37/39-45
RIDADR 
UN 1801 8/PG 2
WGK Germany 
1
RTECS 
VV4700000
10-21
TSCA 
Yes
HazardClass 
8
PackingGroup 
II
HS Code 
29319090
Hazardous Substances Data
5283-66-9(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

H331Toxic if inhaled

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
235725
Product name
Trichloro(octyl)silane
Purity
97%
Packaging
100g
Price
$106
Updated
2024/03/01
TCI Chemical
Product number
O0168
Product name
n-Octyltrichlorosilane
Purity
>98.0%(GC)(T)
Packaging
25g
Price
$151
Updated
2024/03/01
TCI Chemical
Product number
O0168
Product name
n-Octyltrichlorosilane
Purity
>98.0%(GC)(T)
Packaging
250g
Price
$404
Updated
2023/01/07
Alfa Aesar
Product number
B23753
Product name
n-Octyltrichlorosilane, 97%
Packaging
25g
Price
$29.65
Updated
2024/03/01
Alfa Aesar
Product number
B23753
Product name
n-Octyltrichlorosilane, 97%
Packaging
100g
Price
$57.65
Updated
2024/03/01
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Octyltrichlorosilane Chemical Properties,Usage,Production

Chemical Properties

CLEAR COLOURLESS TO LIGHT YELLOW LIQUID

Uses

OTS functionalized magnesium oxide (MnO2)/aluminium oxide (Al2O3) surface can be used as a catalyst in the decomposition of ozone (O3) and nitrogen dioxide (NO2). OTS can also be used for the surface modification of silicon oxide (SiO2), used in the fabrication of pentacene organic field effect transistors (OFETs). OTS functionalized wafers can be coated on enhanced green fluorescent protein (GFP) and anchor peptides based films to determine the thickness of the films.

General Description

N-Octyltrichlorosilane is a colorless liquid with a pungent odor. It is decomposed by water to hydrochloric acid with evolution of heat. Octyltrichlorosilane is corrosive to metals and tissue and used as an intermediate for silicones.

Reactivity Profile

Chlorosilanes, such as N-OCTYLTRICHLOROSILANE, are compounds in which silicon is bonded to from one to four chlorine atoms with other bonds to hydrogen and/or alkyl groups. Chlorosilanes react with water, moist air, or steam to produce heat and toxic, corrosive fumes of hydrogen chloride. They may also produce flammable gaseous H2. They can serve as chlorination agents. Chlorosilanes react vigorously with both organic and inorganic acids and with bases to generate toxic or flammable gases.

Health Hazard

TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Contact with molten substance may cause severe burns to skin and eyes. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Fire Hazard

Combustible material: may burn but does not ignite readily. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapors may travel to source of ignition and flash back. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.

Flammability and Explosibility

Not classified

Safety Profile

A corrosive irritant to skin, eyes, and mucous membranes. Will react with water or steam to produce toxic and corrosive fumes. When heated to decomposition it emits toxic fumes of Cl-. See also CHLOROSILANES.

Synthesis

 In a 25 ml oven dried stainless steel tube, 0.22 g (0.67 mmol) of benzyltributylphosphonium chloride, 1.00 g (6.73 mmol) of 1-chlorooctane, and 2.71 g (20.0 mmol) of trichlorosilane were added under a dry nitrogen atmosphere. After sealing the cylinder with a cap, the reactor was maintained at 170°C. for 2 hrs. The resulting mixture was distilled to yield 1.45 g of n-octyltrichlorosilane (yield; 87%). n-Octyltrichlorosilane, 1.45 g, 87% yield MS (70eV EI) m/z (relative intensity): 250(1), 248(3), 246(4), 179(12), 177(35), 175 (34), 135(53), 133(54), 85(100), 71(57), 57(98).

Purification Methods

Purify the silane by repeated fractionation using a 15-20 theoretical plate glass column packed with glass helices. This can be done more efficiently using a spinning band column. The purity can be checked by analysing for Cl (ca 0.5-1g of sample is dissolved in 25mL of MeOH, diluted with H2O and titrated with standard alkali). It is moisture sensitive. [Whitmore J Am Chem Soc 68 475 1946, El-Abbady & Anderson J Am Chem Soc 80 1737 1958, Beilstein 4 III 1907.]

Octyltrichlorosilane Preparation Products And Raw materials

Raw materials

Preparation Products

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Octyltrichlorosilane Suppliers

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View Lastest Price from Octyltrichlorosilane manufacturers

Hubei Changfu Chemical Co., Ltd.
Product
n-Octyltrichlorosilane 5283-66-9
Price
US $0.00/kg
Min. Order
1kg
Purity
96%
Supply Ability
20t
Release date
2024-04-26
Hebei Weibang Biotechnology Co., Ltd
Product
N-OCTYLTRICHLOROSILANE 5283-66-9
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2022-10-24
Career Henan Chemical Co
Product
N-OCTYLTRICHLOROSILANE 5283-66-9
Price
US $7.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2020-01-03

5283-66-9, OctyltrichlorosilaneRelated Search:


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