ChemicalBook > CAS DataBase List > 6-CHLORO-5-(TRIFLUOROMETHYL)PYRIDIN-3-AMINE

6-CHLORO-5-(TRIFLUOROMETHYL)PYRIDIN-3-AMINE

Product Name
6-CHLORO-5-(TRIFLUOROMETHYL)PYRIDIN-3-AMINE
CAS No.
99368-68-0
Chemical Name
6-CHLORO-5-(TRIFLUOROMETHYL)PYRIDIN-3-AMINE
Synonyms
6-Chloro-5-(trifluoromethyl);6-CHLORO-5-(TRIFLUOROMETHYL)PYRIDIN-3-AMINE;6-chloro-5-(trifluoromethyl)-3-Pyridinamine;6-Chloro-5-trifluoroMethyl-pyridin-3-ylaMine;3-Amino-6-chloro-5-(trifluoromethyl)pyridine;3-Pyridinamine, 6-chloro-5-(trifluoromethyl)-;6-chloro-5-(trifluoromethyl)pyridin-3-amine - [C27002]
CBNumber
CB42455918
Molecular Formula
C6H4ClF3N2
Formula Weight
196.56
MOL File
99368-68-0.mol
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6-CHLORO-5-(TRIFLUOROMETHYL)PYRIDIN-3-AMINE Property

Boiling point:
292℃
Density 
1.507
Flash point:
130℃
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
Appearance
Light yellow to light brown Solid
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Safety

HS Code 
2933599590
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

TRC
Product number
C351485
Product name
6-Chloro-5-(trifluoromethyl)pyridin-3-amine
Packaging
50mg
Price
$55
Updated
2021/12/16
TRC
Product number
C351485
Product name
6-Chloro-5-(trifluoromethyl)pyridin-3-amine
Packaging
100mg
Price
$65
Updated
2021/12/16
Apolloscientific
Product number
PC201388
Product name
6-Chloro-5-(trifluoromethyl)pyridin-3-amine
Purity
95+%
Packaging
100mg
Price
$68
Updated
2021/12/16
SynQuest Laboratories
Product number
3H30-7-1D
Product name
6-Chloro-5-(trifluoromethyl)pyridin-3-amine
Purity
95.0%
Packaging
100mg
Price
$109
Updated
2021/12/16
Matrix Scientific
Product number
119596
Product name
6-Chloro-5-(trifluoromethyl)pyridin-3-amine
Purity
95+%
Packaging
250mg
Price
$224
Updated
2021/12/16
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6-CHLORO-5-(TRIFLUOROMETHYL)PYRIDIN-3-AMINE Chemical Properties,Usage,Production

Synthesis

99368-67-9

99368-68-0

A solution of 5% Pt/C (1.58 mmol, 0.31 g) in ethyl acetate (50 mL) was added to 2-chloro-5-nitro-3-(trifluoromethyl)pyridine (5.25 mmol, 1.19 g) mixed with ZnBr2 (1.05 mmol, 0.200 g) and the reaction was stirred for 20 hrs under hydrogen atmosphere. Upon completion of the reaction, the catalyst was removed by filtration and the solid was washed with warm ethanol. The solvent was evaporated to afford the target product 6-chloro-5-(trifluoromethyl)pyridin-3-amine (0.95 g, 92% yield). The product was characterized by 1H NMR (300 MHz, DMSO-d6): δ 5.59 (bs, 1H), 7.37 (s, 1H), 7.92 (s, 1H).

References

[1] Patent: WO2018/20474, 2018, A1. Location in patent: Page/Page column 309-310
[2] Patent: WO2009/21696, 2009, A1. Location in patent: Page/Page column 38; 69-70
[3] Patent: US2007/60623, 2007, A1. Location in patent: Page/Page column 39
[4] Patent: US2014/275111, 2014, A1. Location in patent: Paragraph 0280; 0281
[5] Patent: WO2014/141187, 2014, A1. Location in patent: Page/Page column 60

6-CHLORO-5-(TRIFLUOROMETHYL)PYRIDIN-3-AMINE Preparation Products And Raw materials

Raw materials

Preparation Products

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6-CHLORO-5-(TRIFLUOROMETHYL)PYRIDIN-3-AMINE Suppliers

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View Lastest Price from 6-CHLORO-5-(TRIFLUOROMETHYL)PYRIDIN-3-AMINE manufacturers

Career Henan Chemical Co
Product
6-CHLORO-5-(TRIFLUOROMETHYL)PYRIDIN-3-AMINE 99368-68-0
Price
US $1.00/KG
Min. Order
1G
Purity
99%
Supply Ability
100KG
Release date
2018-08-13

99368-68-0, 6-CHLORO-5-(TRIFLUOROMETHYL)PYRIDIN-3-AMINERelated Search:

Methyl 6-chloro-5-Methylpicolinate 1-(6-Chloro-5-bromo-3-pyridyl)piperazine 6-chloro-5-(trifluoroMethyl)pyridin-3-yl)Methanol 6-chloro-5-iodonicotinic acid 6-Chloro-5-Methylpyridine-2-carboxylic acid Methyl 6-chloro-5-(trifluoroMethyl)nicotinate 6-CHLORO-5-FLUOROBENZIMIDAZOLE Methyl-6-chloro-5-nitronicotinate 2-Pyridinamine, 6-chloro-5-methyl METHYL 6-CHLORO-5-IODONICOTINATE 2-Pyridinecarboxylic acid, 6-chloro-5-hydroxy- 2-CHLORO-5-NITRO-3-(TRIFLUOROMETHYL)PYRIDINE N1-[6-CHLORO-5-(TRIFLUOROMETHYL)-3-PYRIDYL]CYCLOPROPANE-1-CARBOXAMIDE PROP-2-YNYL N-[6-CHLORO-5-(TRIFLUOROMETHYL)PYRIDIN-3-YL]CARBAMATE 6-CHLORO-5-(TRIFLUOROMETHYL)PYRIDIN-3-AMINE

  • 6-CHLORO-5-(TRIFLUOROMETHYL)PYRIDIN-3-AMINE
  • 6-Chloro-5-trifluoroMethyl-pyridin-3-ylaMine
  • 6-chloro-5-(trifluoromethyl)-3-Pyridinamine
  • 6-Chloro-5-(trifluoromethyl)
  • 3-Pyridinamine, 6-chloro-5-(trifluoromethyl)-
  • 3-Amino-6-chloro-5-(trifluoromethyl)pyridine
  • 6-chloro-5-(trifluoromethyl)pyridin-3-amine - [C27002]
  • 99368-68-0