ChemicalBook > CAS DataBase List > METHYLMAGNESIUM IODIDE

METHYLMAGNESIUM IODIDE

Product Name
METHYLMAGNESIUM IODIDE
CAS No.
917-64-6
Chemical Name
METHYLMAGNESIUM IODIDE
Synonyms
CHLOROMETHYLMAGNESIUM;Methylmagnesium iodide solution;nesium iodide;iodomethylmagnesium;iodomethyl-magnesiu;Methyliodomagnesium;METHYLMAGNESIUM IODIDE;Methylmagnesium iodine;MagnesiuM, iodoMethyl-;3.0 M in diethyl ether
CBNumber
CB4248837
Molecular Formula
CH3IMg
Formula Weight
166.24
MOL File
917-64-6.mol
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METHYLMAGNESIUM IODIDE Property

Density 
1.26 g/mL at 20 °C
Flash point:
-40 °C
BRN 
1209226
InChIKey
AUPXBVDHVRZMIB-UHFFFAOYSA-M
EPA Substance Registry System
Magnesium, iodomethyl- (917-64-6)
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Safety

Hazard Codes 
F+,C,F
Risk Statements 
12-14/15-22-34-66-67-19-11
Safety Statements 
16-26-36/37/39-43-45-7/8
RIDADR 
UN 3399 4.3/PG 1
WGK Germany 
1
F 
1-3-10
HazardClass 
4.2
PackingGroup 
I
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H260In contact with water releases flammable gases which may ignite spontaneously

H314Causes severe skin burns and eye damage

H336May cause drowsiness or dizziness

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P223Keep away from any possible contact with water, because of violent reaction and possible flash fire.

P231+P232Handle under inert gas. Protect from moisture.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P370+P378In case of fire: Use … for extinction.

P422Store contents under …

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
254363
Product name
Methylmagnesium iodide solution
Purity
3.0M in diethyl ether
Packaging
100ml
Price
$89.2
Updated
2024/03/01
Sigma-Aldrich
Product number
254363
Product name
Methylmagnesium iodide solution
Purity
3.0M in diethyl ether
Packaging
800ml
Price
$349.6
Updated
2024/03/01
TCI Chemical
Product number
M0364
Product name
Methylmagnesium Iodide (33% in Ethyl Ether, ca. 2mol/L)
Packaging
100G
Price
$62
Updated
2024/03/01
Sigma-Aldrich
Product number
257109
Product name
Methylmagnesium iodide solution
Purity
3.0M in diethyl ether
Packaging
200ml
Price
$227
Updated
2021/12/16
TRC
Product number
M316653
Product name
MethylmagnesiumIodide(3.0MinDiethylether)
Packaging
10ml
Price
$45
Updated
2021/12/16
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METHYLMAGNESIUM IODIDE Chemical Properties,Usage,Production

Chemical Properties

Dark grey liquid

Uses

Alkylating agent in organic synthesis, Grignardreagent.

Uses

Methylmagnesium iodide solution can be used:

  • To prepare cis-1,2-dialkylcyclopropanols by treating with titanium(IV) alkoxide and carboxylic esters.
  • In stereospecific Ni catalyzed Kumada cross-coupling reactions of benzylic ethers.
  • To prepare 2,4-disubstituted selenochromenes by reacting with 1-benzoselenopyrylium salts.
  • In one of the key synthetic steps for the preparation of 7β-methyl-substituted 5-androstene derivatives from 3β-acetoxyandrost-5-en-17-one stereoselectively.

Definition

Available as solution inether.

Hazard

Flammable, dangerous fire and explosionrisk.

METHYLMAGNESIUM IODIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from METHYLMAGNESIUM IODIDE manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
METHYLMAGNESIUM IODIDE 917-64-6
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99.0%
Supply Ability
1000KG
Release date
2024-08-25
Career Henan Chemical Co
Product
METHYLMAGNESIUM IODIDE 917-64-6
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2020-01-11

917-64-6, METHYLMAGNESIUM IODIDERelated Search:

PHENYLMAGNESIUM IODIDE ethylmagnesium iodide ISOPROPYLMAGNESIUM BROMIDE Vinylmagnesium chloride TERT-BUTYLMAGNESIUM CHLORIDE Methylmagnesium Bromide ISOBUTYLMAGNESIUM CHLORIDE ISOBUTYLMAGNESIUM BROMIDE N-BUTYLMAGNESIUM BROMIDE Butylmagnesium chloride PHENYLMAGNESIUM BROMIDE ALLYLMAGNESIUM BROMIDE Deuterated methyl magnesium iodide Magnesium METHYLMAGNESIUM IODIDE trideutero-methylmagnesium iodide 3-THIENYLMAGNESIUM IODIDE 3-CHLORO-4-METHYLPHENYLMAGNESIUM IODIDE

  • METHYLMAGNESIUM IODIDE
  • MAGNESIUM METHYL IODIDE
  • iodomethyl-magnesiu
  • methylmagnesiumiodidesol.
  • Methylmagnesium Iodide (33% in Ethyl Ether, ca. 2mol/L)
  • Methylmagnesium iodide solution
  • iodomethylmagnesium
  • METHYLMAGNESIUM IODIDE SOL., ~3 M IN DIE THYL ETHER
  • METHYLMAGNESIUM IODIDE, 3.0M SOLUTION IN DIETHYL ETHER
  • nesium iodide
  • Methylmagnesium bromide [solution in THF]
  • Methylmagnesium iodide, 2-3M in diethyl ether
  • Methylmagnesium iodide solution 3.0 M in diethyl ether
  • Methylmagnesium iodide, 3M solution in diethyl ether, AcroSeal
  • Methyliodomagnesium
  • Methylmagnesium iodide,3M solution in diethylether
  • magnesium carbanide iodide
  • CHLOROMETHYLMAGNESIUM
  • Methylmagnesium iodine
  • Methylmagnesium iodide 3M solution in DEE
  • MethylMagnesiuM iodide, 3.0M solution in diethyl ether, J&KSeal
  • MagnesiuM, iodoMethyl-
  • MethylMagnesiuM iodide, 3.0 M in diethyl ether, SpcSeal
  • Methyl magnesium iodide 3M ether solution
  • methylmagnesium iodide 2M in THF
  • Methylmagnesium Iodide, Diethyl Ether Solution (abt. 1mol/l)
  • Methylmagnesium Iodide (3.0 M in Diethyl ether)
  • 3.0 M in diethyl ether
  • Methylmagnesium iodide (6CI)
  • Methylmagnesium iodide, 3M in diethyl ether
  • Methyl magnesium iodide 1M in THF
  • METHYL MAGNESIUM IODIDE IN ETHER
  • Methyl Magnesium Iodide 3 Molar Solution in Diethyl Ether
  • Methylmagnesium iodide, 3M in diethyl
  • Methyl Magnesium Iodide (2.0 M in Diethyl Ether)
  • 917-64-6
  • CH3IMg
  • CH3MgI
  • Alkyl
  • Organometallic Reagents
  • Mg (Magnesium) Compounds
  • Grignard Reagents & Alkyl Metals
  • Typical Metal Compounds
  • Grignard Reagents
  • Classes of Metal Compounds
  • Grignard Reagent
  • Alkyl
  • Chemical Synthesis
  • Organic Bases
  • Organometallic Reagents
  • Synthetic Reagents
  • AlkylChemical Synthesis
  • Grignard Reagents
  • Organic Bases
  • Organometallic Reagents
  • Synthetic Reagents
  • Classes of Metal Compounds
  • Grignard Reagents