METHYLMAGNESIUM IODIDE
- Product Name
- METHYLMAGNESIUM IODIDE
- CAS No.
- 917-64-6
- Chemical Name
- METHYLMAGNESIUM IODIDE
- Synonyms
- CHLOROMETHYLMAGNESIUM;Methylmagnesium iodide solution;nesium iodide;iodomethylmagnesium;iodomethyl-magnesiu;Methyliodomagnesium;METHYLMAGNESIUM IODIDE;Methylmagnesium iodine;MagnesiuM, iodoMethyl-;3.0 M in diethyl ether
- CBNumber
- CB4248837
- Molecular Formula
- CH3IMg
- Formula Weight
- 166.24
- MOL File
- 917-64-6.mol
METHYLMAGNESIUM IODIDE Property
- Density
- 1.26 g/mL at 20 °C
- Flash point:
- -40 °C
- BRN
- 1209226
- InChIKey
- AUPXBVDHVRZMIB-UHFFFAOYSA-M
- EPA Substance Registry System
- Magnesium, iodomethyl- (917-64-6)
Safety
- Hazard Codes
- F+,C,F
- Risk Statements
- 12-14/15-22-34-66-67-19-11
- Safety Statements
- 16-26-36/37/39-43-45-7/8
- RIDADR
- UN 3399 4.3/PG 1
- WGK Germany
- 1
- F
- 1-3-10
- HazardClass
- 4.2
- PackingGroup
- I
- HS Code
- 29319090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H225Highly Flammable liquid and vapour
H260In contact with water releases flammable gases which may ignite spontaneously
H314Causes severe skin burns and eye damage
H336May cause drowsiness or dizziness
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P223Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P231+P232Handle under inert gas. Protect from moisture.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P370+P378In case of fire: Use … for extinction.
P422Store contents under …
N-Bromosuccinimide Price
- Product number
- 254363
- Product name
- Methylmagnesium iodide solution
- Purity
- 3.0M in diethyl ether
- Packaging
- 100ml
- Price
- $89.2
- Updated
- 2024/03/01
- Product number
- 254363
- Product name
- Methylmagnesium iodide solution
- Purity
- 3.0M in diethyl ether
- Packaging
- 800ml
- Price
- $349.6
- Updated
- 2024/03/01
- Product number
- M0364
- Product name
- Methylmagnesium Iodide (33% in Ethyl Ether, ca. 2mol/L)
- Packaging
- 100G
- Price
- $62
- Updated
- 2024/03/01
- Product number
- 257109
- Product name
- Methylmagnesium iodide solution
- Purity
- 3.0M in diethyl ether
- Packaging
- 200ml
- Price
- $227
- Updated
- 2021/12/16
- Product number
- M316653
- Product name
- MethylmagnesiumIodide(3.0MinDiethylether)
- Packaging
- 10ml
- Price
- $45
- Updated
- 2021/12/16
METHYLMAGNESIUM IODIDE Chemical Properties,Usage,Production
Chemical Properties
Dark grey liquid
Uses
Alkylating agent in organic synthesis, Grignardreagent.
Uses
Methylmagnesium iodide solution can be used:
- To prepare cis-1,2-dialkylcyclopropanols by treating with titanium(IV) alkoxide and carboxylic esters.
- In stereospecific Ni catalyzed Kumada cross-coupling reactions of benzylic ethers.
- To prepare 2,4-disubstituted selenochromenes by reacting with 1-benzoselenopyrylium salts.
- In one of the key synthetic steps for the preparation of 7β-methyl-substituted 5-androstene derivatives from 3β-acetoxyandrost-5-en-17-one stereoselectively.
Definition
Available as solution inether.
Hazard
Flammable, dangerous fire and explosionrisk.
METHYLMAGNESIUM IODIDE Preparation Products And Raw materials
Raw materials
Preparation Products
METHYLMAGNESIUM IODIDE Suppliers
View Lastest Price from METHYLMAGNESIUM IODIDE manufacturers
- Product
- METHYLMAGNESIUM IODIDE 917-64-6
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100KG
- Release date
- 2020-01-11